Journal Description
Polymers
Polymers
is an international, peer-reviewed, open access journal of polymer science published semimonthly online by MDPI. Belgian Polymer Group (BPG), European Colloid & Interface Society (ECIS), National Interuniversity Consortium of Materials Science and Technology (INSTM) and North American Thermal Analysis Society (NATAS) are affiliated with Polymers and their members receive a discount on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), Ei Compendex, PubMed, PMC, FSTA, CAPlus / SciFinder, Inspec, and other databases.
- Journal Rank: JCR - Q1 (Polymer Science) / CiteScore - Q1 (Polymers and Plastics)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.7 days after submission; acceptance to publication is undertaken in 2.9 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in MDPI journals, in appreciation of the work.
- Testimonials: See what our authors and editors say about Polymers.
Impact Factor:
5.0 (2022);
5-Year Impact Factor:
5.0 (2022)
Latest Articles
Fiber Bragg Gratings Sensor Strain–Optic Behavior with Different Polymeric Coatings Subjected to Transverse Strain
Polymers 2024, 16(9), 1223; https://doi.org/10.3390/polym16091223 (registering DOI) - 27 Apr 2024
Abstract
This research work is based on a previous study by the authors that characterized the behavior of FBG sensors with a polyimide coating in a structural monitoring system. Sensors applied to structural health monitoring are affected by the presence of simultaneous multidirectional strains.
[...] Read more.
This research work is based on a previous study by the authors that characterized the behavior of FBG sensors with a polyimide coating in a structural monitoring system. Sensors applied to structural health monitoring are affected by the presence of simultaneous multidirectional strains. The previous study observed the influence of the transverse strain ( ) while keeping the longitudinal strain constant ( ), where the x direction is the direction of the optical fiber. The present study develops an experimental methodology consisting of a biaxial test plan on cruciform specimens with three embedded FBG sensors coated with polyimide, acrylate, and ORMOCER®. Applying the Strain–Optic Theory as a reference, a comparison of the experimental values obtained with the different coatings was studied. This experimental work made it possible to study the influence of the transverse strain ( ) on the longitudinal measurements of each FBGS and the influence of the coating material. Finally, the calibration procedure was defined as well as (strain sensitivity factor) for each sensor.
Full article
(This article belongs to the Section Polymer Membranes and Films)
►
Show Figures
Open AccessCommunication
Synthesis and Oxidative Degradation of Leucine-Based Poly(diacylhydrazine)
by
Kanda Wongwailikhit, Ratha Suwannakeeree and Nobuhiro Kihara
Polymers 2024, 16(9), 1222; https://doi.org/10.3390/polym16091222 (registering DOI) - 27 Apr 2024
Abstract
Diacylhydrazine is thermally and chemically stable, and it remains inert to oxygen even at high temperatures. However, it is rapidly oxidized by sodium hypochlorite, leading to its decomposition into carboxylic acid and nitrogen gas. In the synthesis of a novel poly(diacylhydrazine) as an
[...] Read more.
Diacylhydrazine is thermally and chemically stable, and it remains inert to oxygen even at high temperatures. However, it is rapidly oxidized by sodium hypochlorite, leading to its decomposition into carboxylic acid and nitrogen gas. In the synthesis of a novel poly(diacylhydrazine) as an oxidatively degradable polymer, L-leucine methyl ester is acylated by terephthaloyl chloride. Subsequent hydrazination yields a bishydrazide monomer. The oxidative coupling polymerization of this monomer produces poly(diacylhydrazine). The molecular structures of the products are confirmed by an 1H NMR analysis. A polymodal molecular weight distribution and a large polydispersity index are observed by GPC in all cases. A 10% weight loss temperature is noted at 286 °C in air by TGA. The obtained polymer is not oxidized by oxygen. No glass transition is observed below the decomposition temperature. Upon the treatment of the poly(diacylhydrazine) with sodium hypochlorite solution, decomposition occurs rapidly, resulting in monomeric carboxylic acid and nitrogen gas. The L-leucine-based poly(diacylhydrazine) serves as a novel on-demand degradable polymer with high levels of thermal and chemical stability during usage.
Full article
(This article belongs to the Collection Design and Synthesis of Polymers)
►▼
Show Figures
Figure 1
Open AccessArticle
Injectable Thermo-Responsive Peptide Hydrogels and Its Enzyme Triggered Dynamic Self-Assembly
by
Bowen Yin, Ruoxue Wang, Yu Guo, Liuxuan Li and Xiuli Hu
Polymers 2024, 16(9), 1221; https://doi.org/10.3390/polym16091221 - 26 Apr 2024
Abstract
Endogenous stimuli-responsive injectable hydrogels hold significant promise for practical applications due to their spatio-temporal controllable drug delivery. Herein, we report a facile strategy to construct a series of in situ formation polypeptide hydrogels with thermal responsiveness and enzyme-triggered dynamic self-assembly. The thermo-responsive hydrogels
[...] Read more.
Endogenous stimuli-responsive injectable hydrogels hold significant promise for practical applications due to their spatio-temporal controllable drug delivery. Herein, we report a facile strategy to construct a series of in situ formation polypeptide hydrogels with thermal responsiveness and enzyme-triggered dynamic self-assembly. The thermo-responsive hydrogels are from the diblock random copolymer mPEG-b-P(Glu-co-Tyr). The L-glutamic acid (Glu) segments with different γ-alkyl groups, including methyl, ethyl, and n-butyl, offer specific secondary structure, facilitating the formation of hydrogel. The L-tyrosine (Tyr) residues not only provide hydrogen-bond interactions and thus adjust the sol–gel transition temperatures, but also endow polypeptide enzyme-responsive properties. The PTyr segments could be phosphorylated, and the phosphotyrosine copolymers were amphiphilies, which could readily self-assemble into spherical aggregates and transform into sheet-like structures upon dephosphorylation by alkaline phosphatase (ALP). P(MGlu-co-Tyr/P) and P(MGlu-co-Tyr) copolymers showed good compatibility with both MC3T3-E1 and Hela cells, with cell viability above 80% at concentrations up to 1000 μg/mL. The prepared injectable polypeptide hydrogel and its enzyme-triggered self-assemblies show particular potential for biomedical applications.
Full article
(This article belongs to the Special Issue Biocompatible Polymers for Tissue Engineering and Drug Delivery)
►▼
Show Figures
Graphical abstract
Open AccessArticle
Predicting Mechanical Properties of Polymer Materials Using Rate-Dependent Material Models: Finite Element Analysis of Bespoke Upper Limb Orthoses
by
Syed Hammad Mian, Usama Umer, Khaja Moiduddin and Hisham Alkhalefah
Polymers 2024, 16(9), 1220; https://doi.org/10.3390/polym16091220 - 26 Apr 2024
Abstract
Three-dimensional printing—especially with fused deposition modeling (FDM)—is widely used in the medical field as it enables customization. FDM is versatile owing to the availability of various materials, but selecting the appropriate material for a certain application can be challenging. Understanding materials’ mechanical behaviors,
[...] Read more.
Three-dimensional printing—especially with fused deposition modeling (FDM)—is widely used in the medical field as it enables customization. FDM is versatile owing to the availability of various materials, but selecting the appropriate material for a certain application can be challenging. Understanding materials’ mechanical behaviors, particularly those of polymeric materials, is vital to determining their suitability for a given application. Physical testing with universal testing machines is the most used method for determining the mechanical behaviors of polymers. This method is resource-intensive and requires cylinders for compression testing and unique dumbbell-shaped specimens for tensile testing. Thus, a specialized fixture must be designed to conduct mechanical testing for the customized orthosis, which is costly and time-consuming. Finite element (FE) analysis using an appropriate material model must be performed to identify the mechanical behaviors of a customized shape (e.g., an orthosis). This study analyzed three material models, namely the Bergström–Boyce (BB), three-network (TN), and three-network viscoplastic (TNV) models, to determine the mechanical behaviors of polymer materials for personalized upper limb orthoses and examined three polymer materials: PLA, ABS, and PETG. The models were first calibrated for each material using experimental data. Once the models were calibrated and found to fit the data appropriately, they were employed to examine the customized orthosis’s mechanical behaviors through FE analysis. This approach is innovative in that it predicts the mechanical characteristics of a personalized orthosis by combining theoretical and experimental investigations.
Full article
(This article belongs to the Special Issue Theoretical and Computational Polymers Science: Physics, Chemistry and Biology)
►▼
Show Figures
Figure 1
Open AccessArticle
Effect of Simulated Dental Pulpal Pressure Using Fetal Bovine Serum for the Bonding Performance of Contemporary Adhesive to Dentin
by
Yitong Li, Masahiko Maeno, Carolina Cecilia Cifuentes-Jimenez, Mei Komoto, Yunqing Liu, Yoichiro Nara, Hidehiko Sano, Pedro Alvarez-Lloret, Monica Yamauti and Atsushi Tomokiyo
Polymers 2024, 16(9), 1219; https://doi.org/10.3390/polym16091219 - 26 Apr 2024
Abstract
This study evaluated the effect of simulated pulpal pressure (SPP) conditions and storage time on contemporary adhesive systems’ microtensile bond strength (µTBS) to dentin. Extracted human molars were prepared and randomly divided into four groups according to the adhesives: Clearfil Megabond 2 (CSE),
[...] Read more.
This study evaluated the effect of simulated pulpal pressure (SPP) conditions and storage time on contemporary adhesive systems’ microtensile bond strength (µTBS) to dentin. Extracted human molars were prepared and randomly divided into four groups according to the adhesives: Clearfil Megabond 2 (CSE), Beautibond Xtreme Universal (BXU), G2-Bond (G2B), and Scotchbond Universal Plus (SBP). Each adhesive group was further divided following the SPP conditions: control with no simulation (SPP-CTR), SPP with distilled water (SPP-DTW), and SPP with fetal bovine serum (SPP-FBS). Resin composite build-ups were prepared, and teeth were stored in water (37 °C) for 24 h (24 h) and 3 months (3 m). Then, teeth were sectioned to obtain resin–dentin bonded beams and tested to determine the µTBS. Data were analyzed using three-way ANOVA, Tukey post hoc tests (=0.05), and Weibull failure analysis. Failure mode was observed using scanning electron microscopy. The µTBS response was affected by adhesive systems, simulated pulpal pressure conditions, and storage time. SPP-CTR groups presented a higher overall bond strength than SPP-DTW and SPP-FBS, which were not significantly different from each other. Only for SBP, the SPP-FBS group showed higher µTBS than the SPP-DTW group. The Weibull analysis showed that the bonding reliability and durability under SPP-DTW and SPP-FBS were inferior to SPP-CTR, and the 24 h bonding quality of adhesives to dentin was superior to that of 3 m. SPP drastically reduced the µTBS of all adhesives to dentin regardless of solution (distilled water or fetal bovine serum). Storage after 3 m also decreased µTBS despite the SPP condition.
Full article
(This article belongs to the Special Issue Polymers Strategies in Dental Therapy)
►▼
Show Figures
Figure 1
Open AccessArticle
Biodegradation Study of Styrene–Butadiene Composites with Incorporated Arthrospira platensis Biomass
by
Marius Bumbac, Cristina Mihaela Nicolescu, Traian Zaharescu, Ion Valentin Gurgu, Costel Bumbac, Elena Elisabeta Manea, Ioana Alexandra Ionescu, Bogdan-Catalin Serban, Octavian Buiu and Crinela Dumitrescu
Polymers 2024, 16(9), 1218; https://doi.org/10.3390/polym16091218 (registering DOI) - 26 Apr 2024
Abstract
The preparation of polymer composites that incorporate material of a biogenic nature in the polymer matrices may lead to a reduction in fossil polymer consumption and a potentially higher biodegradability. Furthermore, microalgae biomass as biogenic filler has the advantage of fast growth and
[...] Read more.
The preparation of polymer composites that incorporate material of a biogenic nature in the polymer matrices may lead to a reduction in fossil polymer consumption and a potentially higher biodegradability. Furthermore, microalgae biomass as biogenic filler has the advantage of fast growth and high tolerance to different types of culture media with higher production yields than those provided by the biomass of terrestrial crops. On the other hand, algal biomass can be a secondary product in wastewater treatment processes. For the present study, an SBS polymer composite (SBSC) containing 25% (w/w) copolymer SBS1 (linear copolymer: 30% styrene and 70% butadiene), 50% (w/w) copolymer SBS2 (linear copolymer: 40% styrene and 60% butadiene), and 25% (w/w) paraffin oil was prepared. Arthrospira platensis biomass (moisture content 6.0 ± 0.5%) was incorporated into the SBSC in 5, 10, 20, and 30% (w/w) ratios to obtain polymer composites with spirulina biomass. For the biodegradation studies, the ISO 14855-1:2012(E) standard was applied, with slight changes, as per the specificity of our experiments. The degradation of the studied materials was followed by quantitatively monitoring the CO2 resulting from the degradation process and captured by absorption in NaOH solution 0.5 mol/L. The structural and morphological changes induced by the industrial composting test on the materials were followed by physical–mechanical, FTIR, SEM, and DSC analysis. The obtained results were compared to create a picture of the material transformation during the composting period. Thus, the collected data indicate two biodegradation processes, of the polymer and the biomass, which take place at the same time at different rates, which influence each other. On the other hand, it is found that the material becomes less ordered, with a sponge-like morphology; the increase in the percentage of biomass leads to an advanced degree of degradation of the material. The FTIR analysis data suggest the possibility of the formation of peptide bonds between the aromatic nuclei in the styrene block and the molecular residues resulting from biomass biodegradation. It seems that in industrial composting conditions, the area of the polystyrene blocks from the SBS-based composite is preferentially transformed in the process.
Full article
(This article belongs to the Special Issue Biodegradable Polymer Composites: Fabrication and Applications II)
Open AccessArticle
Optimization of Electrospinning Parameters for Lower Molecular Weight Polymers: A Case Study on Polyvinylpyrrolidone
by
Fatima Tuz Zahra, Ying Zhang, Adeolu Oluwaseun Ajayi, Quincy Quick and Richard Mu
Polymers 2024, 16(9), 1217; https://doi.org/10.3390/polym16091217 - 26 Apr 2024
Abstract
Polyvinylpyrrolidone (PVP) is a synthetic polymer that holds significance in various fields such as biomedical, medical, and electronics, due to its biocompatibility and exceptional dielectric properties. Electrospinning is the most commonly used tool to fabricate fibers because of its convenience and the wide
[...] Read more.
Polyvinylpyrrolidone (PVP) is a synthetic polymer that holds significance in various fields such as biomedical, medical, and electronics, due to its biocompatibility and exceptional dielectric properties. Electrospinning is the most commonly used tool to fabricate fibers because of its convenience and the wide choice of parameter optimization. Various parameters, including solution molarity, flow rate, voltage, needle gauge, and needle-to-collector distance, can be optimized to obtain the desired morphology of the fibers. Although PVP is commercially available in various molecular weights, PVP with a molecular weight of 130,000 g/mol is generally considered to be the easiest PVP to fabricate fibers with minimal challenges. However, the fiber diameter in this case is usually in the micron regime, which limits the utilization of PVP fibers in fields that require fiber diameters in the nano regime. Generally, PVP with a lower molecular weight, such as 10,000 g/mol and 55,000 g/mol, is known to present challenges in fiber preparation. In the current study, parameter optimization for PVP possessing molecular weights of 10,000 g/mol and 55,000 g/mol was carried out to obtain nanofibers. The electrospinning technique was utilized for fiber fabrication by optimizing the above-mentioned parameters. SEM analysis was performed to analyze the fiber morphology, and quantitative analysis was performed to correlate the effect of parameters on the fiber morphology. This research study will lead to various applications, such as drug encapsulation for sustained drug release and nanoparticles/nanotubes encapsulation for microwave absorption applications.
Full article
(This article belongs to the Special Issue Fiber and Polymer Composites: Processing, Simulation, Properties and Applications II)
Open AccessArticle
High-Temperature Polylactic Acid Proves Reliable and Safe for Manufacturing 3D-Printed Patient-Specific Instruments in Pediatric Orthopedics—Results from over 80 Personalized Devices Employed in 47 Surgeries
by
Grazia Chiara Menozzi, Alessandro Depaoli, Marco Ramella, Giulia Alessandri, Leonardo Frizziero, Adriano De Rosa, Francesco Soncini, Valeria Sassoli, Gino Rocca and Giovanni Trisolino
Polymers 2024, 16(9), 1216; https://doi.org/10.3390/polym16091216 - 26 Apr 2024
Abstract
(1) Background: Orthopedic surgery has been transformed by 3D-printed personalized instruments (3DP-PSIs), which enhance precision and reduce complications. Hospitals are adopting in-house 3D printing facilities, using cost-effective methods like Fused Deposition Modeling (FDM) with materials like Polylactic acid (PLA) to create 3DP-PSI. PLA’s
[...] Read more.
(1) Background: Orthopedic surgery has been transformed by 3D-printed personalized instruments (3DP-PSIs), which enhance precision and reduce complications. Hospitals are adopting in-house 3D printing facilities, using cost-effective methods like Fused Deposition Modeling (FDM) with materials like Polylactic acid (PLA) to create 3DP-PSI. PLA’s temperature limitations can be overcome by annealing High-Temperature PLA (ann-HTPLA), enabling steam sterilization without compromising properties. Our study examines the in vivo efficacy of ann-HTPLA 3DP-PSI in pediatric orthopedic surgery. (2) Methods: we investigated safety and efficacy using ann-HTPLA 3DP-PSI produced at an “in-office” 3D-printing Point-of-Care (3DP-PoC) aimed at correcting limb deformities in pediatric patients. Data on 3DP-PSI dimensions and printing parameters were collected, along with usability and complications. (3) Results: Eighty-three ann-HTPLA 3DP-PSIs were utilized in 33 patients (47 bone segments). The smallest guide used measured 3.8 cm3, and the largest measured 58.8 cm3. Seventy-nine PSIs (95.2%; 95% C.I.: 88.1–98.7%) demonstrated effective use without issues. Out of 47 procedures, 11 had complications, including 2 infections (4.3%; 95% CI: 0.5–14.5%). Intraoperative use of 3DP-PSIs did not significantly increase infection rates or other complications. (4) Conclusions: ann-HTPLA has proven satisfactory usability and safety as a suitable material for producing 3DP-PSI in an “in-office” 3DP-PoC.
Full article
(This article belongs to the Special Issue Structure and Properties of Polymeric Materials in Additive Manufacturing II)
►▼
Show Figures
Figure 1
Open AccessArticle
Mechanical Properties Comparison of Isotropic vs. Anisotropic Hybrid Magnetorheological Elastomer-Fluid
by
Hammam M. Ananzeh, Rahizar Ramli, Sabariah Julai and Asan G. A. Muthalif
Polymers 2024, 16(9), 1215; https://doi.org/10.3390/polym16091215 - 26 Apr 2024
Abstract
Magnetorheological (MR) materials are smart materials that can change their rheological characteristics when exposed to a magnetic field. Such rheological properties include viscosity and dynamic modulus. MR materials have emerged as one of the most efficient smart materials that can modify mechanical and
[...] Read more.
Magnetorheological (MR) materials are smart materials that can change their rheological characteristics when exposed to a magnetic field. Such rheological properties include viscosity and dynamic modulus. MR materials have emerged as one of the most efficient smart materials that can modify mechanical and viscoelastic characteristics. Depending on the medium used, MR materials can be classified into two types: magnetorheological fluids (MRFs) and magnetorheological elastomers (MREs). MREs are classified as isotropic or anisotropic based on CIP distribution inside the elastomer matrix. A unique hybrid material incorporating MRE and MRF is constructed in this work to investigate, compare, and the dynamic properties of isotropic, anisotropic, hybrid isotropic, and hybrid anisotropic MREs under various magnetic fields (0, 104, and 160.2 mT). The created samples are subjected to extensive testing, including static and dynamic evaluations. In the static tests, experiments use a compression linear displacement mode with a fixed maximum gap change of 3 mm. The temperature is maintained at a constant level of 24 °C throughout the 40 s test duration for each test, and the magnetic field is incrementally increased by varying the number of magnets, ranging from 0 to 160.2 mT for dynamic qualities using compression oscillations on a dynamic mechanical analyzer (DMA), including frequency and strain-dependent data. These experiments, carried out using sinusoidal shear movements, include an excitation frequency range of 0.1 Hz to 15 Hz while preserving, with a fixed shear strain of 2%.
Full article
(This article belongs to the Section Polymer Physics and Theory)
►▼
Show Figures
Figure 1
Open AccessArticle
Carbon Black Functionalized with Serinol Pyrrole to Replace Silica in Elastomeric Composites
by
Federica Magaletti, Martina Galbusera, Davide Gentile, Ulrich Giese, Vincenzina Barbera and Maurizio Galimberti
Polymers 2024, 16(9), 1214; https://doi.org/10.3390/polym16091214 - 26 Apr 2024
Abstract
Elastomer composites for dynamic mechanical applications with a low dissipation of energy are of great importance in view of their application in tire compounds. In this work, furnace carbon black functionalized with 2-2,5-dimethyl-1H-pyrrol-1-yl-1,3-propanediol (SP) was used in place of silica in
[...] Read more.
Elastomer composites for dynamic mechanical applications with a low dissipation of energy are of great importance in view of their application in tire compounds. In this work, furnace carbon black functionalized with 2-2,5-dimethyl-1H-pyrrol-1-yl-1,3-propanediol (SP) was used in place of silica in an elastomer composite based on poly(styrene-co-butadiene) from solution anionic polymerization and poly(1,4-cis-isoprene) from Hevea Brasiliensis. The traditional coupling agent used for silica was also used for the CB/SP adduct: 3,3′-bis(triethoxysilylpropyl)tetrasulfide (TESPT). The composite with the CB/SP + TESPT system revealed a lower Payne effect, higher dynamic rigidity, and lower hysteresis, compared to the composite with CB + TESPT, although the latter composite had a higher crosslinking density. The properties of the silica and the CB/SP + TESPT-based composites appear similar, though in the presence of slightly higher hysteresis and lower ultimate properties for the CB/SP-based composite. The use of CB in place of silica allows us to prepare lighter compounds and paves the way for the preparation of tire compounds with lower environmental impacts.
Full article
(This article belongs to the Special Issue Advances in Functional Rubber and Elastomer Composites II)
►▼
Show Figures
Figure 1
Open AccessArticle
Prediction of the Bubble Growth Behavior by Means of the Time-, Temperature-, Pressure- and Blowing Agent Concentration-Dependent Transient Elongational Viscosity Function of Polymers
by
Tobias Schaible and Christian Bonten
Polymers 2024, 16(9), 1213; https://doi.org/10.3390/polym16091213 - 26 Apr 2024
Abstract
Bubble growth processes are highly complex processes, which are not only dependent on the foaming process parameters (temperature, pressure and blowing agent concentration) but also on the type and structure of the polymer used. Since the elongational viscosity at the bubble wall during
[...] Read more.
Bubble growth processes are highly complex processes, which are not only dependent on the foaming process parameters (temperature, pressure and blowing agent concentration) but also on the type and structure of the polymer used. Since the elongational viscosity at the bubble wall during bubble growth also depends on these influencing factors, the so-called transient elongational viscosity plays a key role in describing the gas bubble growth behavior in polymer melts. The model-based description of the transient elongational viscosity function is difficult due to its dependence on time, Hencky strain and strain rate. Therefore, representative viscosities or shear viscosity models are usually used in the literature to predict the bubble growth behavior. In this work, the transient equibiaxial elongational viscosity function at the bubble wall during bubble growth is described holistically for the first time. This is achieved by extending the so-called molecular stress function (MSF) model by superposition principles (temperature, pressure and blowing agent concentration) and by using the elongational deformation behavior (Hencky strain and strain rate) at the bubble wall during the initial, and thus viscosity-driven, bubble growth process. Therefore, transient uniaxial elongational viscosity measurements are performed and the non-linear MSF model parameters of the two investigated polymers PS (linear polymer chains) and PLA (long-chain branched polymer chains) are determined. By applying the superposition principles and by changing the strain mode parameter to the equibiaxial case in the MSF model, the transient equibiaxial viscosity master curve is obtained and used to describe the bubble growth process. The results show that the extended MSF model can fully predict the transient equibiaxial elongational viscosity function at the bubble wall during bubble growth processes. The bubble growth behavior over time can then be realistically described using the defined transient equibiaxial elongational viscosity function at the bubble wall. This is not possible, for example, with a representative viscosity and therefore clearly demonstrates the influence and importance of knowing the transient deformation behavior that prevails at the bubble wall during bubble growth processes.
Full article
(This article belongs to the Section Polymer Physics and Theory)
►▼
Show Figures
Figure 1
Open AccessArticle
Fabrication, Structural Characterization, and Photon Attenuation Efficiency Investigation of Polymer-Based Composites
by
Sitah F. Alanazi, Norah M. Alotaibi, Mohammed Alsuhybani, Nassar Alnassar, Fahad I. Almasoud and Mansour Almurayshid
Polymers 2024, 16(9), 1212; https://doi.org/10.3390/polym16091212 - 26 Apr 2024
Abstract
Experiments have assessed various polymer composites for radiation shielding in diverse applications. These composites are lighter and non-toxic when compared to lead (Pb), making them particularly effective in diagnostic imaging for shielding against low-energy photons. This study demonstrates the fabrication of four composites
[...] Read more.
Experiments have assessed various polymer composites for radiation shielding in diverse applications. These composites are lighter and non-toxic when compared to lead (Pb), making them particularly effective in diagnostic imaging for shielding against low-energy photons. This study demonstrates the fabrication of four composites by combining a base material, specifically a high-density polyethylene (HDPE) polymer, with 10% and 20% silicon (Si) and silicon carbide (SiC), respectively. Additionally, 5% molybdenum (Mo) was incorporated into the composites as a heavy metal element. The composites obtained were fabricated into 20 disks with a uniform thickness of 2 mm each. Discs were exposed to radiation from a low-energy X-ray source (32.5–64.5 keV). The chemical and physical properties of composites were assessed. The shielding ability of samples was evaluated by determining the linear and mass attenuation coefficients (μ and μm), radiation protection efficiency (RPE), half-value layer (HVL), and mean free path (MFP). According to our findings, supplementing HDPE with additives improved the attenuation of beams. The μm values showed that composite X-ray shielding characteristics were enhanced with filler concentration for both Si and SiC. Polymer composites with micro-molecule fillers shelter X-rays better than polymers, especially at low energy. The HVL and MFB values of the filler are lower than those of the pure HDPE sample, indicating that less thickness is needed to shield at the appropriate energy. HC-20 blocked 92% of the incident beam at 32.5 keV. This study found that increasing the composite sample thickness or polymer filler percentage could shield against low-energy radiation.
Full article
(This article belongs to the Special Issue Polymer Materials for Energy, Environment and Radiation Shielding)
►▼
Show Figures
Figure 1
Open AccessArticle
Study of Cellulose Dissolution in ZnO/NaOH/Water Solvent Solution and Its Temperature-Dependent Effect Using Molecular Dynamics Simulation
by
Lamiae Bourassi, Meriem El Mrani, Mohammed Merzouki, Rania Abidi, Haytham Bouammali, Boufelja Bouammali, Larbi Elfarh, Rachid Touzani, Allal Challioui and Mohamed Siaj
Polymers 2024, 16(9), 1211; https://doi.org/10.3390/polym16091211 - 26 Apr 2024
Abstract
Cellulose is a biopolymer with numerous advantages that make it an ecological, economical, and high-performing choice for various applications. To fully exploit the potential of cellulose, it is often necessary to dissolve it, which poses a current challenge. The aqueous zinc oxide/sodium hydroxide
[...] Read more.
Cellulose is a biopolymer with numerous advantages that make it an ecological, economical, and high-performing choice for various applications. To fully exploit the potential of cellulose, it is often necessary to dissolve it, which poses a current challenge. The aqueous zinc oxide/sodium hydroxide (ZnO/NaOH/Water) system is a preferred solvent for its rapid dissolution, non-toxicity, low cost, and environmentally friendly nature. In this context, the behavior of cellulose chains in the aqueous solution of ZnO/NaOH and the impact of temperature on the solubility of this polymer were examined through a molecular dynamics simulation. The analysis of the root means square deviation (RMSD), interaction energy, hydrogen bond curves, and radial distribution function revealed that cellulose is insoluble in the ZnO/NaOH solvent at room temperature (T = 298 K). Decreasing the temperature in the range of 273 K to 268 K led to a geometric deformation of cellulose chains, accompanied by a decrease in the number of interchain hydrogen bonds over the simulation time, thus confirming the solubility of cellulose in this system between T = 273 K and T = 268 K.
Full article
(This article belongs to the Special Issue New Advances in the Structure, Performance and Chemical Functionalization of Cellulose)
►▼
Show Figures
Figure 1
Open AccessArticle
Possibility of Using Wind Turbine Waste in Particleboard Manufacturing
by
Adam Derkowski, Dorota Dziurka, Ryszard Antonowicz, Monika Chuda-Kowalska and Radoslaw Mirski
Polymers 2024, 16(9), 1210; https://doi.org/10.3390/polym16091210 - 26 Apr 2024
Abstract
Recent reports indicate that the development of electricity generation using wind turbines will continue to grow. Despite the long service life of wind turbine blades, their technological life comes to an end at a certain point. Currently, there is no industrial method for
[...] Read more.
Recent reports indicate that the development of electricity generation using wind turbines will continue to grow. Despite the long service life of wind turbine blades, their technological life comes to an end at a certain point. Currently, there is no industrial method for recycling them, and the proposed solutions need to consider a complete and comprehensive approach to this material. In many countries, these blades are stored in special landfills and await proposals for rational recycling. It has been proposed that this recyclable yet still troublesome raw material be used in building sheathing boards. Sheathing boards used in the construction industry have a relatively long lifecycle. Three types of polymer chips and two resins, i.e., PF and MUF, were used in the study. The boards’ quality was assessed per the standards specified for particle boards. The resulting boards were characterized by strengths above 20 N/mm2 and an elastic modulus close to 4000 N/mm2. Slightly better results were obtained with the MUF resin.
Full article
(This article belongs to the Special Issue Eco-Friendly Polymers: Structure, Modification and Processing)
►▼
Show Figures
Figure 1
Open AccessArticle
Multiscale Modeling and Characterization of Graphene Epoxy Nanocomposite
by
Collins Ekeowa and SD Jacob Muthu
Polymers 2024, 16(9), 1209; https://doi.org/10.3390/polym16091209 - 26 Apr 2024
Abstract
This study aims to characterize graphene epoxy nanocomposite properties using multiscale modeling. Molecular dynamics was used to study the nanocomposite at the nanoscale and finite element analysis at the macroscale to complete the multiscale modeling. The coupling of these two scales was carried
[...] Read more.
This study aims to characterize graphene epoxy nanocomposite properties using multiscale modeling. Molecular dynamics was used to study the nanocomposite at the nanoscale and finite element analysis at the macroscale to complete the multiscale modeling. The coupling of these two scales was carried out using the Irving–Kirkwood averaging method. First, the functionalization of graphene was carried and 6% grafted graphene was selected based on Young’s modulus and the tensile strength of the grafted graphene sheet. Functionalized graphene with weight fractions of 1.8, 3.7, and 5.6 wt.% were reinforced with epoxy polymer to form a graphene epoxy nanocomposite. The results showed that the graphene with 3.7 wt.% achieved the highest modulus. Subsequently, a functionalized graphene sheet with an epoxy matrix was developed to obtain the interphase properties using the MD modeling technique. The normal and shear forces at the interphase region of the graphene epoxy nanocomposite were investigated using a traction-separation test to analyze the mechanical properties including Young’s modulus and traction forces. The mean stiffness of numerically tested samples with 1.8, 3.7, and 5.6 wt.% graphene and the stiffness obtained from experimental results from the literature were compared. The experimental results are lower than the multiscale model results because the experiments cannot replicate the molecular-scale behavior. However, a similar trend could be observed for the addition of up to 3.7 wt.% graphene. This demonstrated that the graphene with 3.7 wt.% shows improved interphase properties. The macroscale properties of the graphene epoxy nanocomposite models with 1.8 and 3.7 wt.% were comparatively higher.
Full article
(This article belongs to the Special Issue Advances in Mechanical and Thermal Characterization of Polymer Composites II)
►▼
Show Figures
Figure 1
Open AccessArticle
Transparent and Efficient Wood-Based Triboelectric Nanogenerators for Energy Harvesting and Self-Powered Sensing
by
Ting Cheng, Kunli Cao, Yidan Jing, Hongyan Wang and Yan Wu
Polymers 2024, 16(9), 1208; https://doi.org/10.3390/polym16091208 - 26 Apr 2024
Abstract
Wood possesses several advantageous qualities including innocuity, low cost, aesthetic appeal, and excellent biocompatibility, and its naturally abundant functional groups and diverse structural forms facilitate functionalization modification. As the most sustainable bio-based material, the combination of wood with triboelectric nanogenerators (TENGs) stands poised
[...] Read more.
Wood possesses several advantageous qualities including innocuity, low cost, aesthetic appeal, and excellent biocompatibility, and its naturally abundant functional groups and diverse structural forms facilitate functionalization modification. As the most sustainable bio-based material, the combination of wood with triboelectric nanogenerators (TENGs) stands poised to significantly advance the cause of green sustainable production while mitigating the escalating challenges of energy consumption. However, the inherent weak polarizability of natural wood limits its development for TENGs. Herein, we present the pioneering development of a flexible transparent wood-based triboelectric nanogenerator (TW-TENG) combining excellent triboelectrical properties, optical properties, and wood aesthetics through sodium chlorite delignification and epoxy resin impregnation. Thanks to the strong electron-donating groups in the epoxy resin, the TW-TENG obtained an open-circuit voltage of up to ~127 V, marking a remarkable 530% enhancement compared to the original wood. Furthermore, durability and stability were substantiated through 10,000 working cycles. In addition, the introduction of epoxy resin and lignin removal endowed the TW-TENG with excellent optical characteristics, with optical transmittance of up to 88.8%, while preserving the unique texture and aesthetics of the wood completely. Finally, we show the application prospects of TW-TENGs in the fields of self-power supply, motion sensing, and smart home through the demonstration of a TW-TENG in the charging and discharging of capacitors and the output of electrical signals in different scenarios.
Full article
(This article belongs to the Special Issue High Proformance Wood Coating)
►▼
Show Figures
Figure 1
Open AccessReview
Advances in Organosulfur-Based Polymers for Drug Delivery Systems
by
Fawad Islam and Qingle Zeng
Polymers 2024, 16(9), 1207; https://doi.org/10.3390/polym16091207 - 25 Apr 2024
Abstract
Organosulfur-based polymers have unique properties that make them useful for targeted and managed drug delivery, which can improve therapy while reducing side effects. This work aims to provide a brief review of the synthesis strategies, characterization techniques, and packages of organosulfur-based polymers in
[...] Read more.
Organosulfur-based polymers have unique properties that make them useful for targeted and managed drug delivery, which can improve therapy while reducing side effects. This work aims to provide a brief review of the synthesis strategies, characterization techniques, and packages of organosulfur-based polymers in drug delivery. More importantly, this work discusses the characterization, biocompatibility, controlled release, nanotechnology, and targeted therapeutic aspects of these important structural units. This review provides not only a good comprehension of organosulfur-based polymers but also an insightful discussion of potential future prospectives in research. The discovery of novel organosulfur polymers and innovations is highly expected to be stimulated in order to synthesize polymer prototypes with increased functional accuracy, efficiency, and low cost for many industrial applications.
Full article
(This article belongs to the Special Issue Recent Progress in Sulfur-Containing Polymers)
Open AccessArticle
Pervaporation Membranes Based on Polyelectrolyte Complex of Sodium Alginate/Polyethyleneimine Modified with Graphene Oxide for Ethanol Dehydration
by
Mariia Dmitrenko, Olga Mikhailovskaya, Roman Dubovenko, Anna Kuzminova, Danila Myznikov, Anton Mazur, Konstantin Semenov, Yury Rusalev, Alexander Soldatov, Sergey Ermakov and Anastasia Penkova
Polymers 2024, 16(9), 1206; https://doi.org/10.3390/polym16091206 - 25 Apr 2024
Abstract
Pervaporation is considered the most promising technology for dehydration of bioalcohols, attracting increasing attention as a renewable energy source. In this regard, the development of stable and effective membranes is required. In this study, highly efficient membranes for the enhanced pervaporation dehydration of
[...] Read more.
Pervaporation is considered the most promising technology for dehydration of bioalcohols, attracting increasing attention as a renewable energy source. In this regard, the development of stable and effective membranes is required. In this study, highly efficient membranes for the enhanced pervaporation dehydration of ethanol were developed by modification of sodium alginate (SA) with a polyethylenimine (PEI) forming polyelectrolyte complex (PEC) and graphene oxide (GO). The effect of modifications with GO or/and PEI on the structure, physicochemical, and transport characteristics of dense membranes was studied. The formation of a PEC by ionic cross-linking and its interaction with GO led to changes in membrane structure, confirmed by spectroscopic and microscopic methods. The physicochemical properties of membranes were investigated by a thermogravimetric analysis, a differential scanning calorimetry, and measurements of contact angles. The theoretical consideration using computational methods showed favorable hydrogen bonding interactions between GO, PEI, and water, which caused improved membrane performance. To increase permeability, supported membranes without treatment and cross-linked were developed by the deposition of a thin dense layer from the optimal PEC/GO (2.5%) composite onto a developed porous substrate from polyacrylonitrile. The cross-linked supported membrane demonstrated more than two times increased permeation flux, higher selectivity (above 99.7 wt.% water in the permeate) and stability for separating diluted mixtures compared to the dense pristine SA membrane.
Full article
(This article belongs to the Special Issue Feature Papers in Polymer Membranes and Films III)
Open AccessArticle
Rubber-like PTFE Thin Coatings Deposited by Pulsed Electron Beam Deposition (PED) Method
by
Agata Niemczyk, Roman Jędrzejewski, Joanna Piwowarczyk and Jolanta Baranowska
Polymers 2024, 16(9), 1205; https://doi.org/10.3390/polym16091205 - 25 Apr 2024
Abstract
PTFE coatings were manufactured using the pulsed electron beam deposition (PED) technique and deposited on Si substrates. The deposition was carried out at constant parameters: temperature 24 °C, discharge voltages 12 kV, and 5000 electron pulses with a pulse frequency of 5 Hz.
[...] Read more.
PTFE coatings were manufactured using the pulsed electron beam deposition (PED) technique and deposited on Si substrates. The deposition was carried out at constant parameters: temperature 24 °C, discharge voltages 12 kV, and 5000 electron pulses with a pulse frequency of 5 Hz. Nitrogen was used as the background gas. The gas pressure varied from 3 to 11 mTorr. The coating adhesion was evaluated using micro scratch testing and the residual scratch morphology was characterized by atomic force microscopy. Detailed studies of the chemical and physical structure were conducted using infrared spectroscopy and X-ray diffraction. These analyses were then correlated with the mechanical response of the coatings observed during the scratch tests. Drawing upon a review of the literature concerning energetic beam interactions with PTFE material, hypotheses were posed to explain why only specific conditions of the PED process yielded PTFE coatings with rubber-like properties.
Full article
(This article belongs to the Special Issue Advanced Polymeric Films II)
►▼
Show Figures
Figure 1
Open AccessArticle
Predicting Diffusion Coefficients in Nafion Membranes during the Soaking Process Using a Machine Learning Approach
by
Ivan Malashin, Daniil Daibagya, Vadim Tynchenko, Andrei Gantimurov, Vladimir Nelyub and Aleksei Borodulin
Polymers 2024, 16(9), 1204; https://doi.org/10.3390/polym16091204 - 25 Apr 2024
Abstract
Nafion, a versatile polymer used in electrochemistry and membrane technologies, exhibits complex behaviors in saline environments. This study explores Nafion membrane’s IR spectra during soaking and subsequent drying processes in salt solutions at various concentrations. Utilizing the principles of Fick’s second law, diffusion
[...] Read more.
Nafion, a versatile polymer used in electrochemistry and membrane technologies, exhibits complex behaviors in saline environments. This study explores Nafion membrane’s IR spectra during soaking and subsequent drying processes in salt solutions at various concentrations. Utilizing the principles of Fick’s second law, diffusion coefficients for these processes are derived via exponential approximation. By harnessing machine learning (ML) techniques, including the optimization of neural network hyperparameters via a genetic algorithm (GA) and leveraging various regressors, we effectively pinpointed the optimal model for predicting diffusion coefficients. Notably, for the prediction of soaking coefficients, our model is composed of layers with 64, 64, 32, and 16 neurons, employing ReLU, ELU, sigmoid, and ELU activation functions, respectively. Conversely, for drying coefficients, our model features two hidden layers with 16 and 12 neurons, utilizing sigmoid and ELU activation functions, respectively.
Full article
(This article belongs to the Special Issue Scientific Machine Learning for Polymeric Materials)
►▼
Show Figures
Figure 1
Journal Menu
► ▼ Journal Menu-
- Polymers Home
- Aims & Scope
- Editorial Board
- Reviewer Board
- Topical Advisory Panel
- Instructions for Authors
- Special Issues
- Topics
- Sections & Collections
- Article Processing Charge
- Indexing & Archiving
- Editor’s Choice Articles
- Most Cited & Viewed
- Journal Statistics
- Journal History
- Journal Awards
- Society Collaborations
- Conferences
- Editorial Office
Journal Browser
► ▼ Journal BrowserHighly Accessed Articles
Latest Books
E-Mail Alert
News
Topics
Topic in
Materials, Nanomaterials, Photonics, Polymers, Applied Sciences, Sensors
Optical and Optoelectronic Properties of Materials and Their Applications
Topic Editors: Zhiping Luo, Gibin George, Navadeep ShrivastavaDeadline: 20 May 2024
Topic in
Biomedicines, Cancers, JFB, Nanomaterials, Polymers
Advanced Functional Materials for Regenerative Medicine
Topic Editors: Antonino Morabito, Luca ValentiniDeadline: 6 June 2024
Topic in
Bioengineering, JMMP, Materials, Micromachines, Polymers
Advances in Filament Engineering for Biomaterials
Topic Editors: Ming-Wei Chang, Zeeshan Ahmad, Hui-Min David WangDeadline: 30 June 2024
Topic in
Foods, Materials, Polymers, Sensors, Applied Sciences
Scientific Advances in STEM: Synergies to Achieve Success, 3rd Volume
Topic Editors: Yadir Torres Hernández, Ana María Beltrán Custodio, Manuel Félix ÁngelDeadline: 31 July 2024
Conferences
Special Issues
Special Issue in
Polymers
Polymers, Additives and Reinforcements from Upgraded Wastes from the Food Industry and Agroforestry
Guest Editors: Rafael Antonio Balart Gimeno, Pablo Stefani, Franco Dominici, Marina Patricia Arrieta Dillon, Luís Jesús Quiles CarrilloDeadline: 30 April 2024
Special Issue in
Polymers
Soft Polymeric Materials: Synthesis, Characterizations and Applications
Guest Editors: Kumkum Ahmed, MD Nahin Islam Shiblee, Chanchal Kumar Roy, Hidemitsu FurukawaDeadline: 15 May 2024
Special Issue in
Polymers
Artificial Intelligence Enhanced Design of Polymer Materials and Manufacturing
Guest Editors: Yingtao Liu, Changjie Cai, Blake HerrenDeadline: 31 May 2024
Special Issue in
Polymers
Permanently Porous Polymers
Guest Editors: Magdalena Rogulska, Małgorzata Maciejewska, Marta GrochowiczDeadline: 15 June 2024
Topical Collections
Topical Collection in
Polymers
Progress in Theory of Polymers at Interfaces
Collection Editors: Jens-Uwe Sommer, Martin Kröger
Topical Collection in
Polymers
State-of-the-Art Polymer Science and Technology in Poland (2021,2022)
Collection Editors: Marek M. Kowalczuk, Mirosława El Fray, Łukasz Klapiszewski, Dorota Neugebauer, Michał Cegłowski
Topical Collection in
Polymers
Proteins and Peptides
Collection Editors: Horia Iovu, Vladimir N. Uversky