Nuclear Magnetic Resonance in Characterization and Oxidation Evaluation of Edible Oils

A special issue of Foods (ISSN 2304-8158). This special issue belongs to the section "Food Engineering and Technology".

Deadline for manuscript submissions: closed (15 November 2021) | Viewed by 3322

Special Issue Editors


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Guest Editor
Food Technology, Faculty of Pharmacy, Lascaray Research Center, University of the Basque Country (UPV-EHU), Paseo de la Universidad n° 7, 01006 Vitoria-Gasteiz, Spain
Interests: food; lipids; oxidation; antioxidants; in vitro digestion; proton nuclear magnetic resonance; solid phase microextraction; gas chromatography/mass spectrometry
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Food Technology, Faculty of Pharmacy, Lascaray Research Center, University of the Basque Country (UPV-EHU), Paseo de la Universidad n° 7, 01006 Vitoria-Gasteiz, Spain
Interests: food; lipids; oxidation; antioxidants; in vitro digestion; solid phase microextraction; gas chromatography/mass spectrometry; proton nuclear magnetic resonance; fourier transform infrared spectroscopy
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Edible oils, either of vegetable or animal origin, are widely consumed all over the world and they are important sources of essential lipid nutrients for humans. However, their composition in main and minor bioactive components can be affected by many factors, among which, botanical and geographical origin or production process can be mentioned. In addition, this composition will rule to a large extent oil behaviour during storage and processing. This constitutes a crucial issue, since the oxidative and thermal degradative reactions that can take place under these conditions, which frequently involve the use of high temperatures, can entail nutritional losses and the generation of a wide variety of toxic compounds that could be further ingested and adversely affect human health. Therefore, the study of the composition of edible oils and of the factors that can influence it not only could help to improve their nutritional and technological quality and to optimize their use for different purposes, but also could provide very valuable information for oils authentication purposes. Moreover, the advance in the knowledge of edible oils oxidation and thermodegradation processes, including the nature and concentrations of the compounds generated, and of the factors influencing these processes, also constitutes a relevant topic with potential health implications. In this context, Nuclear Magnetic Resonance (NMR) spectroscopy has proved to be a very powerful tool due to the great deal of information it is able to provide.

This Special Issue aims to go deeper into the application of NMR spectroscopy for the study of edible oils composition and of the impact that different variables can have on their main and minor component profiles, as well as on their behaviour under oxidative conditions. Besides, the evaluation by NMR of edible oils oxidation: either as bulk oils or taking part in more complex systems like emulsions, in presence or absence of other added compounds that could act as antioxidants or prooxidants, and under various conditions (storage, thermal treatment…), is also the subject of this Special Issue. These research fields fit perfectly with various of the topics included in the scope of “Foods” journal, such as food sciences and technology, food chemistry, food safety and quality, food analysis or food and health.

We are pleased to invite researchers to contribute research articles and reviews on the above mentioned areas and other related ones.

We look forward to receiving your contributions.

Dr. Patricia Sopelana
Dr. María Luisa Ibargoitia
Guest Editors

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Keywords

  • edible oils
  • composition
  • authentication
  • oxidation
  • thermal processing
  • storage
  • toxic oxidation products
  • NMR Spectroscopy
  • antioxidants
  • prooxidants

Published Papers (1 paper)

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Research

28 pages, 4735 KiB  
Article
Comparative 1H NMR-Based Chemometric Evaluations of the Time-Dependent Generation of Aldehydic Lipid Oxidation Products in Culinary Oils Exposed to Laboratory-Simulated Shallow Frying Episodes: Differential Patterns Observed for Omega-3 Fatty Acid-Containing Soybean Oils
by Angela I. Wann, Benita C. Percival, Katy Woodason, Miles Gibson, Siâny Vincent and Martin Grootveld
Foods 2021, 10(10), 2481; https://doi.org/10.3390/foods10102481 - 17 Oct 2021
Cited by 9 | Viewed by 2800
Abstract
Soybean oil is the second most exported oil from the United States and South America, and is widely marketed as a cooking oil product containing numerous health benefits for human consumers. However, culinary oils with high polyunsaturated fatty acid (PUFA) contents, are known [...] Read more.
Soybean oil is the second most exported oil from the United States and South America, and is widely marketed as a cooking oil product containing numerous health benefits for human consumers. However, culinary oils with high polyunsaturated fatty acid (PUFA) contents, are known to produce high quantities of lipid oxidation products (LOPs), including toxic aldehydes upon exposure to high-temperature frying episodes. Previous studies have demonstrated causal links between aldehyde ingestion and inhalation with deleterious health perturbations, including mutagenic and carcinogenic effects, along with cardiovascular and teratogenic actions. In this study, aldehydic LOPs were detected and quantified in commercially available samples of soybean, avocado, corn and extra-virgin olive oil products before and after their exposure to laboratory-simulated laboratory frying episodes (LSSFEs) using high-resolution 1H nuclear magnetic resonance (NMR) analysis. Results acquired demonstrated that PUFA-rich soybean and corn oils gave rise to the highest concentrations of oil aldehydes from the thermo-oxidation of unsaturated fatty acids, whereas monounsaturated fatty acid (MUFA)-laden avocado and olive oils were much more resistant to this peroxidation process, as expected. Multivariate chemometrics analyses provided evidence that an orthogonal component pattern of aldehydic LOPs featuring low-molecular-mass n-alkanals such as propanal, and 4-oxo-alkanals, arises from thermo-oxidation of the ω-3 fatty acid (FA) linolenic acid (present in soybean oils at levels of ca. 7% (w/w)), was able to at least partially distinguish this oil from corresponding samples of thermally-stressed corn oil. Despite having a similar total PUFA level, corn oil has only a negligible ω-3 FA content, and therefore generated significantly lower levels of these two aldehyde classes. In view of the adverse health effects associated with dietary LOP ingestion, alternative methodologies for the incorporation of soybean oils within high-temperature frying practices are proposed. Full article
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