Pollutants, Volume 3, Issue 4 (December 2023) – 10 articles

We performed a thorough systematic review of published literature to determine potential links between human health impacts and naled, a registered adult mosquito control product (adulticide), and its major degradate, dichlorvos (DDVP). A search query was performed on 8 September 2023, capturing all articles published up to that date on the Scopus and PubMed databases. Inclusion criteria were the presence of either pesticide and a measured or modeled human health outcome or risk. The search string resulted in 382 articles; however, 354 articles were excluded, resulting in only 28 articles that met the inclusion criteria. The studies that directly relate to aerosolized ultra-low volume (ULV) mosquito control applications did not report any associated deleterious human health outcomes. Results from the reviewed papers displayed no negative health effects or led to inconclusive results. No studies showed adverse health effects from aerial ULV applications for mosquito management. Our findings are congruent with the United States Environmental Protection Agency and Centers for Disease Control and Prevention recommendations that aerial applications of naled, following label parameters, do not pose an adverse risk exposure to humans, wildlife, and the environment. Full article

Background: Autism Spectrum Disorder (ASD) is a complex neurodevelopmental condition with increasing prevalence. This review aims to systematically investigate the relationship between the levels of toxic and trace elements in hair and the occurrence of ASD. Methods: Original articles reporting trace element levels in hair were included. A comprehensive search was conducted in databases such as Medline (via PubMed), Scopus, Web of Science, and Google Scholar, covering publications from 1 January 2000, to 2 January 2023. Keywords including “hair element analysis”, “trace elements”, and “autism”, were utilized in the search. Results: A direct comparison of the data was not possible due to the variety of methodologies observed in the available studies, including variations in sample sizes and analytical procedures. Conclusions: Exposure to toxic elements, notably Mercury (Hg) and Lead (Pb), which act as neurotoxicants, was found to be associated with the pathogenesis of ASD. Furthermore, a significant correlation was identified between the Zinc (Zn) to Copper (Cu) ratio and ASD. Full article

Contaminants of concern (CoCs) pose significant threats to Uganda’s ecosystems and public health, particularly in the face of rapid urbanization, industrial expansion, and intensified agriculture. This systematic review comprehensively analyzed Uganda’s CoC landscape, addressing imminent challenges that endanger the country’s ecosystems and public health. CoCs, originating from urban, industrial, and agricultural activities, encompass a wide range of substances, including pharmaceuticals, personal care products, pesticides, industrial chemicals, heavy metals, radionuclides, biotoxins, disinfection byproducts, hydrocarbons, and microplastics. This review identified the major drivers of CoC dispersion, particularly wastewater and improper waste disposal practices. From an initial pool of 887 articles collected from reputable databases such as PubMed, African Journal Online (AJOL), Web of Science, Science Direct, and Google Scholar, 177 pertinent studies were extracted. The literature review pointed to the presence of 57 pharmaceutical residues and personal care products, along with 38 pesticide residues and 12 heavy metals, across various environmental matrices, such as wastewater, groundwater, seawater, rainwater, surface water, drinking water, and pharmaceutical effluents. CoC concentrations displayed significant levels exceeding established regulations, varying based on the specific locations, compounds, and matrices. This review underscores potential ecological and health consequences associated with CoCs, including antibiotic resistance, endocrine disruption, and carcinogenicity. Inefficiencies in traditional wastewater treatment methods, coupled with inadequate sanitation practices in certain areas, exacerbate the contamination of Uganda’s aquatic environments, intensifying environmental and health concerns. To address these challenges, advanced oxidation processes (AOPs) emerge as promising and efficient alternatives for CoC degradation and the prevention of environmental pollution. Notably, no prior studies have explored the management and mitigation of these contaminants through AOP application within various aqueous matrices in Uganda. This review emphasizes the necessity of specific regulations, improved data collection, and public awareness campaigns, offering recommendations for advanced wastewater treatment implementation, the adoption of sustainable agricultural practices, and the enforcement of source control measures. Furthermore, it highlights the significance of further research to bridge knowledge gaps and devise effective policies and interventions. Ultimately, this comprehensive analysis equips readers, policymakers, and regulators with vital knowledge for informed decision-making, policy development, and the protection of public health and the environment. Full article

Various studies have been conducted in the fields of sustainable operations management (SOM), optimization, and wastewater treatment, yielding unsubstantiated recovery. In the context of Europe’s climate neutrality vision, this paper reviews effective decarbonization strategies and proposes sustainable approaches to mitigate carbonization in various sectors such as buildings, energy, industry, and transportation and how these interlink with wastewater management. The study also explores the role of digitalization in decarbonization and reviews policies that can direct governments’ actions towards a climate-neutral society. This paper presents a review of optimization approaches applied in the fields of science and technology, incorporating modern optimization techniques based on various peer-reviewed published research papers. It emphasizes non-conventional energy and distributed power-generating systems along with the deregulated and regulated environment. Additionally, this paper critically reviews the performance and capability of the micellar-enhanced ultrafiltration (MEUF) process in the treatment of dye wastewater. The review presents evidence of the simultaneous removal of co-existing pollutants and explores the feasibility and efficiency of biosurfactants instead of chemical surfactants. Lastly, the paper proposes a novel Firm–Regulator–Consumer-Technology Enablers/Facilitators interaction framework to study operations, decisions and interactive cooperation considering the relationships between the four agents through a comprehensive literature review of SOM. The proposed framework provides support for exploring future research opportunities and holistic sustainability initiatives. Full article

In this article, we investigated the dust deposit on leaves in the vegetation period of urban trees using a simple washing method. The data presented in this paper are preliminary results. Air pollution and the area and population of cities are increasing. The EU directives require the reduction and maintenance of air pollution. Trees have many ecological services, including the dust removal capacity. We investigated four urban tree species (Acer platanoides L., Fraxinus excelsior L., Tilia tomentosa Moench., and Prunus cerasifera L. ‘Woodii’) in many locations in Budapest. After collection, the leaves were washed with distillated water, which was eliminated in a drying chamber, and then the dust was measured back into the beakers. Microscopical photos were taken of each leaf’s surface. We found differences among species and seasons, which confirmed previous studies. Examining the data by location, we found no difference in dust deposition, unlike previous results. The dust deposition for Tilia tomentosa Moench. is between 48 and 295 mg/m²; for Fraxinus excelsior L., between 47 and 205 mg/m²; and for Acer platanoides L., between 110 and 500 mg/m². No relevant data were found for Prunus cerasifera ‘Woodii’ (between 426 and 492 mg/m²) due to its exposed location. New data were obtained in Budapest for the dust deposition of the ‘Woodii’ variety. We partially confirmed or provided new results by examining the dust deposition capacities of urban trees. The leaf surface structure of the examined trees is supposedly a typical cause of dust deposit differences. Full article

Anthropogenic chemicals are fundamental for maintaining our standard of living in modern society. Unfortunately, some chemicals are persistent and can enter waste streams and, ultimately, the environment. Commonly used household products, including pharmaceuticals and personal care products, are notable sources of contaminants. The aim of this study was to develop an ‘Up-the-Pipe Solutions’ framework to raise awareness within the wider community about the presence and potential risks of the chemicals found in household products. There is potential to reduce the levels of contaminants in waste streams or substitute them with less harmful alternatives by raising awareness. This framework is based on ‘The Natural Step’ and the concept of essentiality; it recognises the importance of engaging with communities to raise awareness of each individual’s contribution to the problem. Our daily activities and behavioural patterns can have adverse consequences, including the release of persistent contaminants in main waste streams from our kitchens, bathrooms, and green wastes. The ‘Up-the-Pipe Solutions’ framework was successfully used in a small community to engage with school children, local authorities, and Māori leaders to raise awareness of chemical pollution. Full article

Regulatory monitoring networks are often too sparse to support community-scale PM_2.5 exposure assessment, while emerging low-cost sensors have the potential to fill in the gaps. Recent advances in air quality monitoring have produced portable, easy-to-use, low-cost, sensor-based monitors which have given a new dimension to air pollutant monitoring and have democratized the air quality monitoring process by making monitors and results directly available at the community level. This study used PurpleAir © sensors for PM_2.5 assessment in California, USA. The evaluation of PM_2.5 from sensors included Quality Assurance and quality control (QA/QC) procedures, assessment concerning reference-monitored PM_2.5 concentrations, and the formulation of a decision support system integrating these observations using geostatistical techniques. The hourly and daily average observed PM_2.5 concentrations from PurpleAir monitors followed the trends of observed PM_2.5 at regulatory monitors. PurpleAir monitors also captured the peak PM_2.5 concentrations due to incidents such as forest fires. In comparison with reference-monitored PM_2.5 levels, it was found that PurpleAir PM_2.5 concentrations were mostly higher. The most important reason for PurpleAir’s higher PM_2.5 concentrations was the inclusion of moisture or water vapor as an aerosol in contrast to measurements of PM_2.5 excluding water content in FEM/FRM and non-FEM/FRM monitors. Long-term assessment (2016–2023) revealed that R² values were between 0.54 and 0.86 for selected collocated PurpleAir sensors and regulatory monitors for hourly PM_2.5 concentrations. Past research studies that were conducted for mostly shorter periods resulted in higher R² values between 0.80 and 0.98. This study aims to provide reasonable estimations of PM_2.5 concentrations with high spatiotemporal resolutions based on statistical models using PurpleAir measurements. The methods of Kriging and IDW, geostatistical interpolation techniques, showed similar spatio-temporal patterns. Overall, this study revealed that low-cost, sensor-based PurpleAir sensors could be effective and reliable tools for episodic and long-term ambient air quality monitoring and developing mitigation strategies. Full article

End-point evaluation of stream health is essential for the quantification of water quality. To this end, many Multi-Metric Indices (MMIs) have been developed to quantify water quality. The most extensive work has occurred in North America and Europe, while other areas of the world are in development. In this study, we compared the use of relevant physical, chemical and biological parameters in MMIs to various other stream health indicators to assess water quality throughout a three-river corridor along the north central Pacific slope of Costa Rica. Analysis of the data suggested MMIs were the best indicators of water quality and, more specifically, insect MMIs were the most predicative. MMIs were also best at pinpointing anthropomorphic impact throughout the corridor. Further, less complex insect MMIs such as compilations of family diversity using Ephemeroptera, Plecoptera and Trichoptera (EPT) orders were equally as predictive as the more complex models. With a need to better understand and use citizen monitors to predict water quality in these tropical environments, less complex insect MMIs show promise as a solution. Full article

Temperature-dependent chemical toxicity has become a crucial issue taking into consideration that lakes, especially shallow waterbodies, are impacted by climate change worldwide. In this study, we are looking for an answer to what extent standard ecotoxicity assays being performed under constant and relatively low temperatures are capable of predicting the chemical risk posed by pesticides. Lemna minor test plants were exposed to glyphosate in concentrations in the range of 25, 50, 100, 200, and 400 μg/L at temperatures 10, 15, 20, 25, 30, and 35 °C. Two peaks appeared when growth inhibition was assessed; lower concentrations elucidated higher inhibition, at 20 °C, while higher concentrations were found at a higher temperature of 30 °C. The toxic effect experienced at 20 °C indicates that reported PNEC values cannot be sufficient to protect non-target aquatic species in certain environmental scenarios. In addition to growth inhibition, phytotoxicity was also assessed based on peroxidase (POD) concentrations. In general, POD showed greater sensitivity, already showing a response at the lowest temperature tested, 10 °C. Decreased POD activity was detected in the temperature range of 10–30 °C, most probably indicating damage to cell and plasma membranes. Full article

Wildfires represent a significant threat to protected areas around the world. This threat has become even more pronounced in recent years due to climate change. These fires can destroy, among other things, natural habitats, cause a loss of biodiversity, and affect air quality. In addition, they can have a significant economic impact on countries that depend on tourism and protected area activities. In this context, Geographic Information Systems (GIS) can provide an important solution for fire management in protected areas. In this case study, the Basilicata region (Southern Italy) was taken as an example where data on protected areas and fire events are freely accessible and constantly updated. By exploiting several interoperable GIS tools, it was possible to perform a complex geospatial analysis that provided important information for sustainable and resilient land use planning. In particular, areas with the highest frequency of fires within or close to protected areas emerged, which can therefore be attended to at different planning levels. In addition, in general, the work has made it possible to implement simple methodologies of relational analysis between fires and protected areas that can be easily employed in administrative settings so as to make the territory more resilient to the expected increase in fires due to climatic changes. Full article