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12 pages, 236 KiB

Open AccessEditorial

Advances in Mineral Processing and Hydrometallurgy

by Corby G. Anderson and Hao Cui

Metals 2021, 11(9), 1393; https://doi.org/10.3390/met11091393 - 01 Sep 2021

Cited by 1 | Viewed by 2042

Abstract

A Special Issue of Metals was commissioned that was devoted to aspects of Mineral Processing and Hydrometallurgy [...] Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

Research

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12 pages, 2897 KiB

Open AccessArticle

Application of Multistage Concentration (MSC) Electrodialysis to Concentrate Lithium from Lithium-Containing Waste Solution

by Yeonchul Cho, Kihun Kim, Jaewoo Ahn and Jaeheon Lee

Metals 2020, 10(7), 851; https://doi.org/10.3390/met10070851 - 28 Jun 2020

Cited by 8 | Viewed by 2766

Abstract

In order to manufacture lithium carbonate to be used as a raw material for a secondary lithium battery, lithium sulfate solution is used as a precursor, and the concentration of lithium is required to be 10 g/L or more. Electrodialysis (ED) was used [...] Read more.

In order to manufacture lithium carbonate to be used as a raw material for a secondary lithium battery, lithium sulfate solution is used as a precursor, and the concentration of lithium is required to be 10 g/L or more. Electrodialysis (ED) was used as a method of concentrating lithium in a low-concentration lithium sulfate solution, and multistage concentration (MSC) electrodialysis was used to increase the concentration ratio (%). When MSC was performed using a raw material solution containing a large amount of sodium sulfate, the process lead time was increased by 60 min. And the concentration ratio (%) of lithium decreased as the number of concentration stages increased. In order to remove sodium sulfate, methanol was added to the raw material solution to precipitate sodium sulfate, and when it was added in a volume ratio of 0.4, lithium was not lost. Using a solution in which sodium sulfate was partially removed, fourth-stage concentration ED was performed to obtain a lithium sulfate solution with a lithium concentration of 10 g/L. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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18 pages, 3363 KiB

Open AccessArticle

Mechanism and Kinetics of Malachite Dissolution in an NH₄OH System

by Alvaro Aracena, Javiera Pino and Oscar Jerez

Metals 2020, 10(6), 833; https://doi.org/10.3390/met10060833 - 24 Jun 2020

Cited by 5 | Viewed by 2926

Abstract

Copper oxide minerals composed of carbonates consume high quantities of leaching reagent. The present research proposes an alternative procedure for malachite leaching (Cu₂CO₃(OH)₂) through the use of only compound, ammonium hydroxide (NH₄OH). Preliminary studies were [...] Read more.

Copper oxide minerals composed of carbonates consume high quantities of leaching reagent. The present research proposes an alternative procedure for malachite leaching (Cu₂CO₃(OH)₂) through the use of only compound, ammonium hydroxide (NH₄OH). Preliminary studies were also carried out for the dissolution of malachite in an acid system. The variables evaluated were solution pH, stirring rate, temperature, NH₄OH concentration, particle size, solid/liquid ratio and different ammonium reagents. The experiments were carried out in a stirred batch system with controlled temperatures and stirring rates. For the acid dissolution system, sulfuric acid consumption reached excessive values (986 kg H₂SO₄/ton of malachite), invalidating the dissolution in these common systems. On the other hand, for the ammoniacal system, there was no acid consumption and the results show that copper recovery was very high, reaching values of 84.1% for a concentration of 0.2 mol/dm³ of NH₄OH and an experiment time of 7200 s. The theoretical/thermodynamic calculations indicate that the solution pH was a significant factor in maintaining the copper soluble as Cu(NH₃)₄²⁺. This was validated by the experimental results and solid analysis by X-ray diffraction (XRD), from which the reaction mechanisms were obtained. A heterogeneous kinetic model was obtained from the diffusion model in a porous layer for particles that begin the reaction as nonporous but which become porous during the reaction as the original solid splits and cracks to form a highly porous structure. The reaction order for the NH₄OH concentration was 3.2 and was inversely proportional to the square of the initial radius of the particle. The activation energy was calculated at 36.1 kJ/mol in the temperature range of 278 to 313 K. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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17 pages, 11337 KiB

Open AccessArticle

Effect of Preliminary Alkali Desilication on Ammonia Pressure Leaching of Low-Grade Copper–Silver Concentrate

by Kirill Karimov, Andrei Shoppert, Denis Rogozhnikov, Evgeniy Kuzas, Semen Zakhar’yan and Stanislav Naboichenko

Metals 2020, 10(6), 812; https://doi.org/10.3390/met10060812 - 18 Jun 2020

Cited by 7 | Viewed by 2574

Abstract

Ammonia leaching is a promising method for processing low-grade copper ores, especially those containing large amounts of oxidized copper. In this paper, we study the effect of Si-containing minerals on the kinetics of Cu and Ag leaching from low-grade copper concentrates. The results [...] Read more.

Ammonia leaching is a promising method for processing low-grade copper ores, especially those containing large amounts of oxidized copper. In this paper, we study the effect of Si-containing minerals on the kinetics of Cu and Ag leaching from low-grade copper concentrates. The results of experiments on the pressure leaching of the initial copper concentrate in an ammonium/ammonium-carbonate solution with oxygen as an oxidizing agent are in good agreement with the shrinking core model in the intra-diffusion mode: in this case, the activation energies were 53.50 kJ/mol for Cu and 90.35 kJ/mol for Ag. Energy-dispersive X-ray spectroscopy analysis (EDX) analysis showed that reagent diffusion to Cu-bearing minerals can be limited by aluminosilicate minerals of the gangue. The recovery rate for copper and silver increases significantly after a preliminary alkaline desilication of the concentrate, and the new shrinking core model is the most adequate, showing that the process is limited by diffusion through the product layer and interfacial diffusion. The activation energy of the process increases to 86.76 kJ/mol for Cu and 92.15 kJ/mol for Ag. Using the time-to-a-given-fraction method, it has been shown that a high activation energy is required in the later stages of the process, when the most resistant sulfide minerals of copper and silver apparently remain. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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14 pages, 5599 KiB

Open AccessFeature PaperArticle

Monosodium Glutamate as Selective Lixiviant for Alkaline Leaching of Zinc and Copper from Electric Arc Furnace Dust

by Erik Prasetyo, Corby Anderson, Fajar Nurjaman, Muhammad Al Muttaqii, Anton Sapto Handoko, Fathan Bahfie and Fika Rofiek Mufakhir

Metals 2020, 10(5), 644; https://doi.org/10.3390/met10050644 - 15 May 2020

Cited by 15 | Viewed by 4357

Abstract

The efficacy of monosodium glutamate (MSG) as a lixiviant for the selective and sustainable leaching of zinc and copper from electric arc furnace dust was tested. Batch leaching studies and XRD, XRF and SEM-EDS characterization confirmed the high leaching efficiency of zinc (reaching [...] Read more.

The efficacy of monosodium glutamate (MSG) as a lixiviant for the selective and sustainable leaching of zinc and copper from electric arc furnace dust was tested. Batch leaching studies and XRD, XRF and SEM-EDS characterization confirmed the high leaching efficiency of zinc (reaching 99%) and copper (reaching 86%) leaving behind Fe, Al, Ca and Mg in the leaching residue. The separation factor (concentration ratio in pregnant leach solution) between zinc vs. other elements, and copper vs. other elements in the optimum condition could reach 11,700 and 250 times, respectively. The optimum conditions for the leaching scheme were pH 9, MSG concentration 1 M and pulp density 50 g/L. Kinetic studies (leaching time and temperature) revealed that the saturation value of leaching efficiency was attained within 2 h for zinc and 4 h for copper. Modeling of the kinetic experimental data indicated that the role of temperature on the leaching process was minor. The study also demonstrated the possibility of MSG recycling from pregnant leach solutions by precipitation as glutamic acid (>90% recovery). Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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18 pages, 5502 KiB

Open AccessArticle

Acid and Acid-Alkali Treatment Methods of Al-Chloride Solution Obtained by the Leaching of Coal Fly Ash to Produce Sandy Grade Alumina

by Dmitry Valeev, Andrei Shoppert, Alexandra Mikhailova and Alex Kondratiev

Metals 2020, 10(5), 585; https://doi.org/10.3390/met10050585 - 29 Apr 2020

Cited by 22 | Viewed by 4989

Abstract

Sandy grade alumina is a valuable intermediate material that is mainly produced by the Bayer process and used for manufacturing primary metallic aluminum. Coal fly ash is generated in coal-fired power plants as a by-product of coal combustion that consists of submicron ash [...] Read more.

Sandy grade alumina is a valuable intermediate material that is mainly produced by the Bayer process and used for manufacturing primary metallic aluminum. Coal fly ash is generated in coal-fired power plants as a by-product of coal combustion that consists of submicron ash particles and is considered to be a potentially hazardous technogenic waste. The present paper demonstrates that the Al-chloride solution obtained by leaching coal fly ash can be further processed to obtain sandy grade alumina, which is essentially suitable for metallic aluminum production. The novel process developed in the present study involves the production of amorphous alumina via the calcination of aluminium chloride hexahydrate obtained by salting-out from acid Al-Cl liquor. Following this, alkaline treatment with further Al₂O₃ dissolution and recrystallization as Al(OH)₃ particles is applied, and a final calcination step is employed to obtain sandy grade alumina with minimum impurities. The process does not require high-pressure equipment and reutilizes the alkaline liquor and gibbsite particles from the Bayer process, which allows the sandy grade alumina production costs to be to significantly reduced. The present article also discusses the main technological parameters of the acid treatment and the amounts of major impurities in the sandy grade alumina obtained by the different (acid and acid-alkali) methods. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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17 pages, 7545 KiB

Open AccessFeature PaperArticle

Recovery of Gold from the Refractory Gold Concentrate Using Microwave Assisted Leaching

by Kanghee Cho, Hyunsoo Kim, Eunji Myung, Oyunbileg Purev, Nagchoul Choi and Cheonyoung Park

Metals 2020, 10(5), 571; https://doi.org/10.3390/met10050571 - 28 Apr 2020

Cited by 21 | Viewed by 5041

Abstract

Microwave technology has been confirmed to be suitable for use in a wide range of mineral leaching processes. Compared to conventional leaching, microwave-assisted leaching has significant advantages. It is a proven process, because of its short processing time and reduced energy. The purpose [...] Read more.

Microwave technology has been confirmed to be suitable for use in a wide range of mineral leaching processes. Compared to conventional leaching, microwave-assisted leaching has significant advantages. It is a proven process, because of its short processing time and reduced energy. The purpose of this study was to enhance the gold content in a refractory gold concentrate using microwave-assisted leaching. The leaching efficiencies of metal ions (As, Cu, Zn, Fe, and Pb) and recovery of gold from refractory gold concentrate were investigated via nitric acid leaching followed by microwave treatment. As the acid concentration increased, metal ion leaching increased. In the refractory gold concentrate leaching experiments, nitric acid leaching at high temperatures could limit the decomposition of sulfide minerals, because of the passive layer in the refractory gold concentrate. Microwave-assisted leaching experiments for gold recovery were conducted for the refractory gold concentrate. More extreme reaction conditions (nitric acid concentration > 1.0 M) facilitated the decomposition of passivation species derived from metal ion dissolution and the liberation of gangue minerals on the sulfide surface. The recovery rate of gold in the leach residue was improved with microwave-assisted leaching, with a gold recovery of ~132.55 g/t after 20 min of the leaching experiment (2.0 M nitric acid), according to fire assays. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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15 pages, 3767 KiB

Open AccessArticle

An Alternative Process for Leaching Chalcopyrite Concentrate in Nitrate-Acid-Seawater Media with Oxidant Recovery

by César I. Castellón, Pía C. Hernández, Lilian Velásquez-Yévenes and María E. Taboada

Metals 2020, 10(4), 518; https://doi.org/10.3390/met10040518 - 17 Apr 2020

Cited by 15 | Viewed by 3910

Abstract

An alternative copper concentrate leaching process using sodium nitrate and sulfuric acid diluted in seawater followed by gas scrubbing to recover the sodium nitrate has been evaluated. The work involved leaching test carried out under various condition by varying temperature, leaching time, particle [...] Read more.

An alternative copper concentrate leaching process using sodium nitrate and sulfuric acid diluted in seawater followed by gas scrubbing to recover the sodium nitrate has been evaluated. The work involved leaching test carried out under various condition by varying temperature, leaching time, particle size, and concentrations of NaNO₃ and H₂SO₄. The amount of copper extracted from the chalcopyrite concentrate leached with seawater, 0.5 M of H₂SO₄ and 0.5 M of NaNO₃ increased from 78% at room temperature to 91% at 45 °C in 96 h and 46 h of leaching, respectively. Gas scrubbing with the alkaline solution of NaOH was explored to recover part of the sodium nitrate. The dissolved salts were recovered by evaporation as sodium nitrate and sodium nitrite crystals. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 4599 KiB

Open AccessArticle

Platinum Group Elements Recovery from Used Catalytic Converters by Acidic Fusion and Leaching

by Erik Prasetyo and Corby Anderson

Metals 2020, 10(4), 485; https://doi.org/10.3390/met10040485 - 06 Apr 2020

Cited by 13 | Viewed by 4756

Abstract

The recovery of platinum group elements (PGE (platinum group element coating); Pd, Pt, and Rh) from used catalytic converters, using low energy and fewer chemicals, was developed using potassium bisulfate fusion pretreatment, and subsequently leached using hydrochloric acid. In the fusion pre-treatment, potassium [...] Read more.

The recovery of platinum group elements (PGE (platinum group element coating); Pd, Pt, and Rh) from used catalytic converters, using low energy and fewer chemicals, was developed using potassium bisulfate fusion pretreatment, and subsequently leached using hydrochloric acid. In the fusion pre-treatment, potassium bisulfate alone (without the addition of an oxidant) proved to be an effective and selective fusing agent. It altered PGE into a more soluble species and did not react with the cordierite support, based on X-Ray Diffraction (XRD) and metallographic characterization results. The fusion efficacy was due to the transformation of bisulfate into pyrosulfate, which is capable of oxidizing PGE. However, the introduction of potassium through the fusing agent proved to be detrimental, in general, since potassium formed insoluble potassium PGE chloro-complexes during leaching (decreasing the recovery) and required higher HCl concentration and a higher leaching temperature to restore the solubility. Optimization on the fusion and leaching parameter resulted in 106% ± 1.7%, 93.3% ± 0.6%, and 94.3% ± 3.9% recovery for Pd, Pt, and Rh, respectively. These results were achieved at fusion conditions: temperature 550 °C, potassium bisulfate/raw material mass ratio 2.5, and fusion time within 30 min. The leaching conditions were: HCl concentration 5 M, temperature 80 °C, and time within 20 min. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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18 pages, 2478 KiB

Open AccessArticle

Hydrometallurgical Treatment of Waste Printed Circuit Boards: Bromine Leaching

by Hao Cui and Corby Anderson

Metals 2020, 10(4), 462; https://doi.org/10.3390/met10040462 - 02 Apr 2020

Cited by 32 | Viewed by 4159

Abstract

This paper demonstrates the recovery of valuable metals from shredded Waste Printed Circuit Boards (WPCBs) by bromine leaching. Effects of sodium bromide concentration, bromine concentration, leaching time and inorganic acids were investigated. The most critical factors are sodium concentration and bromine concentration. It [...] Read more.

This paper demonstrates the recovery of valuable metals from shredded Waste Printed Circuit Boards (WPCBs) by bromine leaching. Effects of sodium bromide concentration, bromine concentration, leaching time and inorganic acids were investigated. The most critical factors are sodium concentration and bromine concentration. It was found that more than 95% of copper, silver, lead, gold and nickel could be dissolved simultaneously under the optimal conditions: 50 g/L solid/liquid ratio, 1.17 M NaBr, 0.77 M Br₂, 2 M HCl, 400 RPM agitation speed and 23.5 °C for 10 hours. The study shows that the dissolution of gold from waste printed circuit boards in a Br₂-NaBr system is controlled by film diffusion and chemical reaction. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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16 pages, 2846 KiB

Open AccessArticle

Reducing the Magnesium Content from Seawater to Improve Tailing Flocculation: Description by Population Balance Models

by Gonzalo R. Quezada, Matías Jeldres, Norman Toro, Pedro Robles and Ricardo I. Jeldres

Metals 2020, 10(3), 329; https://doi.org/10.3390/met10030329 - 02 Mar 2020

Cited by 4 | Viewed by 2192

Abstract

Experimental assays and mathematical models, through population balance models (PBM), were used to characterize the particle aggregation of mining tailings flocculated in seawater. Three systems were considered for preparation of the slurries: i) Seawater at natural pH (pH 7.4), ii) seawater at pH [...] Read more.

Experimental assays and mathematical models, through population balance models (PBM), were used to characterize the particle aggregation of mining tailings flocculated in seawater. Three systems were considered for preparation of the slurries: i) Seawater at natural pH (pH 7.4), ii) seawater at pH 11, and iii) treated seawater at pH 11. The treated seawater had a reduced magnesium content in order to avoid the formation of solid complexes, which damage the concentration operations. For this, the pH of seawater was raised with lime before being used in the process—generating solid precipitates of magnesium that were removed by vacuum filtration. The mean size of the aggregates were represented by the mean chord length obtained with the Focused beam reflectance measurement (FBRM) technique, and their descriptions, obtained by the PBM, showed an aggregation and a breakage kernel had evolved. The fractal dimension and permeability were included in the model in order to improve the representation of the irregular structure of the aggregates. Then, five parameters were optimized: Three for the aggregation kernel and two for the breakage kernel. The results show that raising the pH from 8 to 11 was severely detrimental to the flocculation performance. Nevertheless, for pH 11, the aggregates slightly exceeded 100 µm, causing undesirable behaviour during the thickening operations. Interestingly, magnesium removal provided a suitable environment to perform the tailings flocculation at alkaline pH, making aggregates with sizes that exceeded 300 µm. Only the fractal dimension changed between pH 8 and treated seawater at pH 11—as reflected in the permeability outcomes. The PBM fitted well with the experimental data, and the parameters showed that the aggregation kernel was dominant at all-polymer dosages. The descriptive capacity of the model might have been utilized as a support in practical decisions regarding the best-operating requirements in the flocculation of copper tailings and water clarification. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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10 pages, 3095 KiB

Open AccessArticle

Selective and Mutual Separation of Palladium (II), Platinum (IV), and Rhodium (III) Using Aliphatic Primary Amines

by Kazuya Matsumoto, Yuto Sezaki, Sumito Yamakawa, Yuki Hata and Mitsutoshi Jikei

Metals 2020, 10(3), 324; https://doi.org/10.3390/met10030324 - 29 Feb 2020

Cited by 9 | Viewed by 3306

Abstract

The selective recovery of platinum-group metals (PGMs) remains a huge challenge. Although solvent extraction processes are generally used for PGM separation, the use of organic solvents is problematic because of their toxicity and environmental concerns. Here, we have developed a new PGM recovery [...] Read more.

The selective recovery of platinum-group metals (PGMs) remains a huge challenge. Although solvent extraction processes are generally used for PGM separation, the use of organic solvents is problematic because of their toxicity and environmental concerns. Here, we have developed a new PGM recovery method by precipitation from hydrochloric acid (HCl) solutions containing Pd(II), Pt(IV), and Rh(III) using aliphatic primary amines as precipitants. Pt(IV) was precipitated using the amines with alkyl chains longer than hexyl independent of HCl concentration. The precipitation of Pd(II) required longer alkyl amines than octyl, regardless of the HCl concentration. Rh(III) was recovered by precipitation at high HCl concentrations using the amines longer than hexyl. The mutual separation of Pt(IV), Rh(III), and Pd(II), in this order, was successfully achieved by changing the HCl concentrations and alkyl chain lengths of the amines. X-ray photoelectron spectroscopy and thermogravimetric analysis evidently showed that the metal-containing precipitates were ion-pair complexes composed of metal chloro-complex anions and ammonium cations. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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15 pages, 1818 KiB

Open AccessArticle

Describing Mining Tailing Flocculation in Seawater by Population Balance Models: Effect of Mixing Intensity

by Gonzalo R. Quezada, Luís Ayala, Williams H. Leiva, Norman Toro, Pedro G. Toledo, Pedro Robles and Ricardo I. Jeldres

Metals 2020, 10(2), 240; https://doi.org/10.3390/met10020240 - 11 Feb 2020

Cited by 7 | Viewed by 2248

Abstract

A population balance model (PBM) is used to describe flocculation of particle tailings in seawater at pH 8 for a range of mixing intensities. The size of the aggregates is represented by the mean chord length, determined by the focused beam reflectance measurement [...] Read more.

A population balance model (PBM) is used to describe flocculation of particle tailings in seawater at pH 8 for a range of mixing intensities. The size of the aggregates is represented by the mean chord length, determined by the focused beam reflectance measurement (FBRM) technique. The PBM follows the dynamics of aggregation and breakage processes underlying flocculation and provides a good approximation to the temporal evolution of aggregate size. The structure of the aggregates during flocculation is described by a constant or time-dependent fractal dimension. The results revealed that the compensations between the aggregation and breakage rates lead to a correct representation of the flocculation kinetics of the tailings of particles in seawater and, in addition, that the representation of the flocculation kinetics in optimal conditions is equally good with a constant or variable fractal dimension. The aggregation and breakage functions and their corresponding parameters are sensitive to the choice of the fractal dimension of the aggregates, whether constant or time dependent, however, under optimal conditions, a constant fractal dimension is sufficient. The model is robust and predictive with a few parameters and can be used to find the optimal flocculation conditions at different mixing intensities, and the optimal flocculation time can be used for a cost-effective evaluation of the quality of the flocculant used. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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15 pages, 5311 KiB

Open AccessArticle

Depression of Pyrite in Seawater Flotation by Guar Gum

by César I. Castellón, Eder C. Piceros, Norman Toro, Pedro Robles, Alejandro López-Valdivieso and Ricardo I. Jeldres

Metals 2020, 10(2), 239; https://doi.org/10.3390/met10020239 - 11 Feb 2020

Cited by 15 | Viewed by 3031

Abstract

The application of guar gum for pyrite depression in seawater flotation was assessed through microflotation tests, Focused Beam Reflectance Measurements (FBRM), and Particle Vision Measurements (PVM). Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as collector and frother, respectively. Chemical [...] Read more.

The application of guar gum for pyrite depression in seawater flotation was assessed through microflotation tests, Focused Beam Reflectance Measurements (FBRM), and Particle Vision Measurements (PVM). Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as collector and frother, respectively. Chemical species on the pyrite surface were characterized by Fourier-transform infrared spectroscopy (FTIR) spectroscopy. The microflotation tests were performed at pH 8, which is the pH at the copper sulfide processing plants that operate with seawater. Pyrite flotation recovery was correlated with FBRM and PVM characterization to delineate the pyrite depression mechanisms by the guar gum. The high flotation recovery of pyrite with PAX was significantly lowered by guar gum, indicating that this polysaccharide could be used as an effective depressant in flotation with sea water. FTIR analysis showed that PAX and guar gum co-adsorbed on the pyrite surface, but the highly hydrophilic nature of the guar gum embedded the hydrophobicity due to the PAX. FBRM and PVM revealed that the guar gum promoted the formation of flocs whose size depended on the addition of guar gum and PAX. It is proposed that the highest pyrite depression occurred not only because of the hydrophilicity induced by the guar gum, but also due to the formation of large flocs, which could not be transported by the bubbles to the froth phase. Furthermore, it is shown that an overdose of guar gum hindered the depression effect due to redispersion of the flocs. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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13 pages, 4575 KiB

Open AccessArticle

Leaching Chalcopyrite with an Imidazolium-Based Ionic Liquid and Bromide

by Marcelo Rodríguez, Luís Ayala, Pedro Robles, Rossana Sepúlveda, David Torres, Francisco Raul Carrillo-Pedroza, Ricardo I. Jeldres and Norman Toro

Metals 2020, 10(2), 183; https://doi.org/10.3390/met10020183 - 27 Jan 2020

Cited by 21 | Viewed by 3489

Abstract

The unique properties of ionic liquids (ILs) drive the growing number of novel applications in different industries. The main features of ILs are high thermal stability, recyclability, low flash point, and low vapor pressure. This study investigated pure chalcopyrite dissolution in the presence [...] Read more.

The unique properties of ionic liquids (ILs) drive the growing number of novel applications in different industries. The main features of ILs are high thermal stability, recyclability, low flash point, and low vapor pressure. This study investigated pure chalcopyrite dissolution in the presence of the ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate, [BMIm]HSO₄, and a bromide-like complexing agent. The proposed system was compared with acid leaching in sulfate media with the addition of chloride and bromide ions. The results demonstrated that the use of ionic liquid and bromide ions improved the chalcopyrite leaching performance. The best operational conditions were at a temperature of 90 °C, with an ionic liquid concentration of 20% and 100 g/L of bromide. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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14 pages, 4607 KiB

Open AccessArticle

Leaching of Silver and Gold Contained in a Sedimentary Ore, Using Sodium Thiosulfate; A Preliminary Kinetic Study

by Edmundo Roldán-Contreras, Eleazar Salinas-Rodríguez, Juan Hernández-Ávila, Eduardo Cerecedo-Sáenz, Ventura Rodríguez-Lugo, Ricardo I. Jeldres and Norman Toro

Metals 2020, 10(2), 159; https://doi.org/10.3390/met10020159 - 21 Jan 2020

Cited by 14 | Viewed by 6862

Abstract

Some sedimentary minerals have attractive contents of gold and silver, like a sedimentary exhalative ore available in the eastern of Hidalgo in Mexico. The gold and silver contained represent an interesting opportunity for processing by non-toxic and aggressive leaching reagents like thiosulfate. The [...] Read more.

Some sedimentary minerals have attractive contents of gold and silver, like a sedimentary exhalative ore available in the eastern of Hidalgo in Mexico. The gold and silver contained represent an interesting opportunity for processing by non-toxic and aggressive leaching reagents like thiosulfate. The preliminary kinetic study indicated that the leaching process was poorly affected by temperature and thiosulfate concentration. The reaction order was −0.61 for Ag, considering a thiosulfate concentration between 200–500 mol·m⁻³, while, for Au, it was −0.09 for a concentration range between 32–320 mol·m^–3. By varying the pH 7–10, it was found that the reaction order was n = 5.03 for Ag, while, for Au, the value was n = 0.94, considering pH 9.5–11. The activation energy obtained during the silver leaching process was 3.15 kJ·mol⁻¹ (298–328 K), which was indicative of a diffusive control of the process. On the other hand, during gold leaching, the activation energy obtained was of 36.44 kJ·mol⁻¹, which was indicative that this process was mixed controlled process, first at low temperatures by diffusive control (298–313 K) and then by chemical control (318–323 K). Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 1667 KiB

Open AccessArticle

Leaching Chalcopyrite with High MnO₂ and Chloride Concentrations

by David Torres, Luís Ayala, Ricardo I. Jeldres, Eduardo Cerecedo-Sáenz, Eleazar Salinas-Rodríguez, Pedro Robles and Norman Toro

Metals 2020, 10(1), 107; https://doi.org/10.3390/met10010107 - 09 Jan 2020

Cited by 15 | Viewed by 3184 | Correction

Abstract

Most copper minerals are found as sulfides, with chalcopyrite being the most abundant. However; this ore is refractory to conventional hydrometallurgical methods, so it has been historically exploited through froth flotation, followed by smelting operations. This implies that the processing involves polluting activities, [...] Read more.

Most copper minerals are found as sulfides, with chalcopyrite being the most abundant. However; this ore is refractory to conventional hydrometallurgical methods, so it has been historically exploited through froth flotation, followed by smelting operations. This implies that the processing involves polluting activities, either by the formation of tailings dams and the emission of large amounts of SO₂ into the atmosphere. Given the increasing environmental restrictions, it is necessary to consider new processing strategies, which are compatible with the environment, and, if feasible, combine the reuse of industrial waste. In the present research, the dissolution of pure chalcopyrite was studied considering the use of MnO₂ and wastewater with a high chloride content. Fine particles (−20 µm) generated an increase in extraction of copper from the mineral. Besides, it was discovered that working at high temperatures (80 °C); the large concentrations of MnO₂ become irrelevant. The biggest copper extractions of this work (71%) were achieved when operating at 80 °C; particle size of −47 + 38 µm, MnO₂/CuFeS₂ ratio of 5/1, and 1 mol/L of H₂SO₄. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 3541 KiB

Open AccessArticle

Assessment of Silica Recovery from Metallurgical Mining Waste, by Means of Column Flotation

by Eleazar Salinas-Rodriguez, Javier Flores-Badillo, Juan Hernandez-Avila, Eduardo Cerecedo-Saenz, Ma. del Pilar Gutierrez-Amador, Ricardo I. Jeldres and Normam Toro

Metals 2020, 10(1), 72; https://doi.org/10.3390/met10010072 - 02 Jan 2020

Cited by 7 | Viewed by 3044

Abstract

The generation of mining waste commonly led to the use of spaces for its disposal. Challenges like mitigating the damage to surrounding communities have promoted the need to reuse, recycle and/or reduce their generation. Besides, these residues may become a source of materials, [...] Read more.

The generation of mining waste commonly led to the use of spaces for its disposal. Challenges like mitigating the damage to surrounding communities have promoted the need to reuse, recycle and/or reduce their generation. Besides, these residues may become a source of materials, which are capable of being recovered and reused in several industries, minimizing the environmental impact. In the mining region of Pachuca, Mexico, waste from the mining industry have been generated for more than 100 years, which have a high SiO₂ content that can be recovered for various industrial applications. This work aims to recover silica from a material of the Dos Carlos dam. A columnar system composed of two-stage of cleaning was used, considering a J_LT (surface liquid rate) value of 0.45 and 0.68 cm/s, respectively; while the J_g (surface gas rate) value was 0.30 cm/s for both stages. Similar bubble sizes in the range of J_g 0.10 to 0.30 cm/s, with values between 0.14 and 0.16 cm in the first stage, and 0.05 to 0.06 cm in the second one. This provided a recovery of 75.10% for all the allotropic phases of silica (quartz, trydimite, and cristobalite) leaving a concentration of 24.90% of a feldspathic phase (orthoclase), as flotation tails. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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18 pages, 6254 KiB

Open AccessArticle

Leaching Kinetics of Arsenic Sulfide-Containing Materials by Copper Sulfate Solution

by Kirill A. Karimov, Denis A. Rogozhnikov, Evgeniy A. Kuzas and Andrei A. Shoppert

Metals 2020, 10(1), 7; https://doi.org/10.3390/met10010007 - 19 Dec 2019

Cited by 12 | Viewed by 3320

Abstract

The overall decrease in the quality of mineral raw materials, combined with the use of arsenic-containing ores, results in large amounts of various intermediate products containing this highly toxic element. The use of hydrometallurgical technologies for these materials is complicated by the formation [...] Read more.

The overall decrease in the quality of mineral raw materials, combined with the use of arsenic-containing ores, results in large amounts of various intermediate products containing this highly toxic element. The use of hydrometallurgical technologies for these materials is complicated by the formation of multicomponent solutions and the difficulty of separating copper from arsenic. Previously, for the selective separation of As from copper–arsenic intermediates a leaching method in the presence of Cu(II) ions was proposed. This paper describes the investigation of the kinetics of arsenic sulfide-containing materials leaching by copper sulfate solution. The cakes after leaching of arsenic trisulfide with a solution of copper sulfate were described using methods such as X-ray diffraction spectrometry (XRD), X-ray fluorescence spectrometry (XRF), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy analysis (EDS). The effect of temperature (70–90 °C), the initial concentration of CuSO₄ (0.23–0.28 M) and the time on the As recovery into the solution was studied. The process temperature has the greatest effect on the kinetics, while an increase in copper concentration from 0.23 to 0.28 M effects an increase in As transfer into solution from 93.2% to 97.8% for 120 min of leaching. However, the shrinking core model that best fits the kinetic data suggests that the process occurs by the intra-diffusion mode with the average activation energy of 44.9 kJ/mol. Using the time-to-a-given-fraction kinetics analysis, it was determined that the leaching mechanism does not change during the reaction. The semi-empirical expression describing the reaction rate under the studied conditions can be written as follows: 1/3ln(1 − X) + [(1 − X) − 1/3 − 1] = 4560000Cu^3.61e^−44900/RT t. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 1903 KiB

Open AccessArticle

Leaching Manganese Nodules in an Acid Medium and Room Temperature Comparing the Use of Different Fe Reducing Agents

by David Torres, Luís Ayala, Manuel Saldaña, Manuel Cánovas, Ricardo I. Jeldres, Steven Nieto, Jonathan Castillo, Pedro Robles and Norman Toro

Metals 2019, 9(12), 1316; https://doi.org/10.3390/met9121316 - 06 Dec 2019

Cited by 19 | Viewed by 3095 | Correction

Abstract

The deposits of Fe-Mn, in the seabed of the planet, are a good alternative source for the extraction of elements of interest. Among these are marine nodules, which have approximately 24% manganese and may be a solution to the shortage of high-grade ores [...] Read more.

The deposits of Fe-Mn, in the seabed of the planet, are a good alternative source for the extraction of elements of interest. Among these are marine nodules, which have approximately 24% manganese and may be a solution to the shortage of high-grade ores on the surface. In this investigation, an ANOVA analysis was performed to evaluate the time independent variables and MnO₂/reducing agent in the leaching of manganese nodules with the use of different Fe reducing agents (FeS₂, Fe²⁺, Fe⁰ and Fe₂O₃). Tests were also carried out for the different reducing agents evaluating the MnO₂/Fe ratio, in which the Fe⁰ (FeC) proved to be the best reducing agent for the dissolution of Mn from marine nodules, achieving solutions of 97% in 20 min. In addition, it was discovered that at low MnO₂/Fe ratios the acid concentration in the system is not very relevant and the potential and pH were in ranges of −0.4–1.4 V and −2–0.1 favoring the dissolution of Mn from MnO₂. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 3076 KiB

Open AccessArticle

Copper Tailing Flocculation in Seawater: Relating the Yield Stress with Fractal Aggregates at Varied Mixing Conditions

by Matías Jeldres, Eder C. Piceros, Norman Toro, David Torres, Pedro Robles, Williams H. Leiva and Ricardo I. Jeldres

Metals 2019, 9(12), 1295; https://doi.org/10.3390/met9121295 - 01 Dec 2019

Cited by 14 | Viewed by 2808

Abstract

The implications of physical conditions of the feedwell on the rheological properties of synthetic copper tailings, flocculated in seawater, were analysed. The mixing intensity of flocculation was related to the structural characteristics of the aggregates, and the outcomes were linked to the yield [...] Read more.

The implications of physical conditions of the feedwell on the rheological properties of synthetic copper tailings, flocculated in seawater, were analysed. The mixing intensity of flocculation was related to the structural characteristics of the aggregates, and the outcomes were linked to the yield stress of the pulp sediments. Tailings settling assays were conducted by using a 30 mm turbine type stirrer with an in-situ aggregate size characterisation. The structural characteristics of the aggregates were determined by using the focused beam reflectance measurement (FBRM). After a mixing time between the pulp and the flocculant, the sample was allowed to settle for 2.5 h, where the variation of the sediment height was minimal. The sediment was gently removed and subjected to rheological characterisation. The yield stress was measured on an Anton Paar MCR 102 rheometer (ANAMIN Group, Santiago, Chile), with a vane-in-cup configuration. The mixing intensity was related to the characteristics of the aggregates, and the outcomes were linked to the yield stress of the flocculated pulp sediments. More aggressive hydrodynamics deteriorated the structure of the aggregates, promoting the reduction of both its size and the fractal dimension. This brought direct consequences on the rheological properties of the sediments: at higher mixing level, the yield stress was lower. The explanation lies in the structural changes of the aggregates, where at a fixed mixing rate, the yield stress presented a seemingly exponential increase over the fractal dimension. Additionally, correlations were found between the rheological properties with settling rate and aggregate size. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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13 pages, 2242 KiB

Open AccessArticle

Kinetics of Chalcopyrite Leaching by Hydrogen Peroxide in Sulfuric Acid

by Miroslav Sokić, Branislav Marković, Srđan Stanković, Željko Kamberović, Nada Štrbac, Vaso Manojlović and Nela Petronijević

Metals 2019, 9(11), 1173; https://doi.org/10.3390/met9111173 - 30 Oct 2019

Cited by 32 | Viewed by 5345

Abstract

In ores, chalcopyrite is usually associated with other sulfide minerals, such as sphalerite, galena, and pyrite, in a dispersed form, with complex mineralogical structures. Concentrates obtained by flotation of such ores are unsuitable for pyrometallurgical processing owing to their poor quality and low [...] Read more.

In ores, chalcopyrite is usually associated with other sulfide minerals, such as sphalerite, galena, and pyrite, in a dispersed form, with complex mineralogical structures. Concentrates obtained by flotation of such ores are unsuitable for pyrometallurgical processing owing to their poor quality and low metal recovery. This paper presents the leaching of chalcopyrite concentrate from the location “Rudnik, Serbia”. The samples from the flotation plant were treated with hydrogen peroxide in sulfuric acid. The influences of temperature, particle size, stirring speed, as well as the concentrations of hydrogen peroxide and sulfuric acid were followed and discussed. Hence, the main objective was to optimize the relevant conditions and to determine the reaction kinetics. It was remarked that the increase in temperature, hydrogen peroxide content, and sulfuric acid concentration, as well as the decrease in particle size and stirring speed, contribute to the dissolution of chalcopyrite. The dissolution kinetics follow a model controlled by diffusion, and the lixiviant diffusion controls the rate of reaction through the sulfur layer. Finally, the main characterization methods used to corroborate the obtained results were X-ray diffraction (XRD) as well as qualitative and quantitative light microscopy of the chalcopyrite concentrate samples and the leach residue. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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13 pages, 3159 KiB

Open AccessArticle

Viscoelasticity of Quartz and Kaolin Slurries in Seawater: Importance of Magnesium Precipitates

by Matías Jeldres, Eder Piceros, Pedro A. Robles, Norman Toro and Ricardo I. Jeldres

Metals 2019, 9(10), 1120; https://doi.org/10.3390/met9101120 - 19 Oct 2019

Cited by 10 | Viewed by 2638

Abstract

In this study, the viscoelastic properties of quartz and kaolin suspensions in seawater were analysed considering two distinct conditions: pH 8 and 10.7. Creep and oscillatory sweep tests provided the rheological parameters. An Anton Paar MCR 102 rheometer (ANAMIN Group, Santiago, Chile) was [...] Read more.

In this study, the viscoelastic properties of quartz and kaolin suspensions in seawater were analysed considering two distinct conditions: pH 8 and 10.7. Creep and oscillatory sweep tests provided the rheological parameters. An Anton Paar MCR 102 rheometer (ANAMIN Group, Santiago, Chile) was used with a vane-in-cup configuration, and the data were processed with RheoCompass^TM Light software (ANAMIN Group, Santiago, Chile). The outcomes were associated with the formation of solid species principally composed of magnesium precipitates. The magnesium in solution reduced in the presence of quartz (68 wt %), from 1380 to 1280 mg/L. Since the difference was not large regarding the solid-free seawater, the disposition of solid complexes at pH 10.7 was expected to be similar. The jump in pH caused both yield stress and viscoelastic moduli to drop, suggesting that the solid precipitates diminished the strength of the particle networks that made up the suspension. For the kaolin slurries (37 wt %), the yield stress raised when the pH increased, but unlike quartz, there was significant adsorption of magnesium cations. In fact, the concentration of magnesium in solution fell from 1380 to 658 mg/L. Dynamic oscillatory assays revealed structural changes in both pulps; in particular, the phase angle was greater at pH 8 than at pH 10.7, which indicates that at more alkaline conditions, the suspension exhibits a more solid-like character. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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10 pages, 1186 KiB

Open AccessArticle

Extraction of Mn from Black Copper Using Iron Oxides from Tailings and Fe²⁺ as Reducing Agents in Acid Medium

by Kevin Pérez, Norman Toro, Eduardo Campos, Javier González, Ricardo I. Jeldres, Amin Nazer and Mario H. Rodriguez

Metals 2019, 9(10), 1112; https://doi.org/10.3390/met9101112 - 18 Oct 2019

Cited by 17 | Viewed by 2748

Abstract

Exotic type deposits include several species of minerals, such as atacamite, chrysocolla, copper pitch, and copper wad. Among these, copper pitch and copper wad have considerable concentrations of manganese. However, their non-crystalline and amorphous structure makes it challenging to recover the elements of [...] Read more.

Exotic type deposits include several species of minerals, such as atacamite, chrysocolla, copper pitch, and copper wad. Among these, copper pitch and copper wad have considerable concentrations of manganese. However, their non-crystalline and amorphous structure makes it challenging to recover the elements of interest (like Cu or Mn) by conventional hydrometallurgical methods. For this reason, black copper ores are generally not incorporated into the extraction circuits or left unprocessed, whether in stock, leach pads, or waste. Therefore, to dilute MnO₂, the use of reducing agents is essential. In the present research, agitated leaching was performed to dissolve Mn of black copper in an acidic medium, comparing the use of ferrous ions and tailings as reducing agents. Two samples of black copper were studied, of high and low grade of Mn, respectively, the latter with a high content of clays. The effect on the reducing agent/black copper ratio and the concentration of sulfuric acid in the system were evaluated. Better results in removing Mn were achieved using the highest-grade black copper sample when working with ferrous ions at a ratio of Fe²⁺/black copper of 2/1 and 1 mol/L of sulfuric acid. Besides, the low-grade sample induced a significant consumption of H₂SO₄ due to the high presence of gangue and clays. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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16 pages, 3164 KiB

Open AccessArticle

Oxidative Leaching of Zinc and Alkalis from Iron Blast Furnace Sludge

by Ma. de Jesus Soria-Aguilar, Gloria Ivone Davila-Pulido, Francisco Raul Carrillo-Pedroza, Adrian Amilcare Gonzalez-Ibarra, Nallely Picazo-Rodriguez, Felipe de Jesus Lopez-Saucedo and Juan Ramos-Cano

Metals 2019, 9(9), 1015; https://doi.org/10.3390/met9091015 - 18 Sep 2019

Cited by 9 | Viewed by 2783

Abstract

The sludge from a wet-off gas cleaning system of the iron blast furnace (BF) contains significant amounts of iron; however, they cannot be recycled due to their high content of zinc and alkalis. These compounds are detrimental to the optimal performance of iron [...] Read more.

The sludge from a wet-off gas cleaning system of the iron blast furnace (BF) contains significant amounts of iron; however, they cannot be recycled due to their high content of zinc and alkalis. These compounds are detrimental to the optimal performance of iron and steelmaking furnaces. In this work, a comparative laboratory study to reduce zinc and alkali contained in the blast furnace sludge (BFS) is presented. The effect of leaching parameters such as oxidant (i.e., ferric ion, oxygen or ozone), aqueous solution media (i.e., 0.2 M NH₄Cl, 0.2 M HCl and 0.1 M H₂SO₄) and temperature (i.e., 27 and 80 °C) on Zn and alkalis (Na₂O and K₂O) removal were studied by applying an experimental design. The results obtained show that Zn and K₂O removal of 85% and 75% were achieved under the following conditions: Ozone as an oxidant agent and 0.1 M H₂SO₄ as an aqueous medium, temperature had no significant effect. The results are supported by thermodynamic diagrams and the possible chemical reactions are mentioned. Although the results also indicate that leaching under the above conditions dissolves up to 9% of iron, this loss is much less than leaching without the oxidizing conditions generated by the ozone. The BFS obtained from this treatment could be recirculated to the iron or steelmaking processes to recover iron values. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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13 pages, 1807 KiB

Open AccessArticle

Use of the Swebrec Function to Model Particle Size Distribution in an Industrial-Scale Ni-Co Ore Grinding Circuit

by Alfredo L. Coello-Velázquez, Víctor Quijano Arteaga, Juan M. Menéndez-Aguado, Francisco M. Pole and Luis Llorente

Metals 2019, 9(8), 882; https://doi.org/10.3390/met9080882 - 10 Aug 2019

Cited by 9 | Viewed by 4881

Abstract

Mathematical models of particle size distribution (PSD) are necessary in the modelling and simulation of comminution circuits. In order to evaluate the application of the Swebrec PSD model (SWEF) in the grinding circuit at the Punta Gorda Ni-Co plant, a sampling campaign was [...] Read more.

Mathematical models of particle size distribution (PSD) are necessary in the modelling and simulation of comminution circuits. In order to evaluate the application of the Swebrec PSD model (SWEF) in the grinding circuit at the Punta Gorda Ni-Co plant, a sampling campaign was carried out with variations in the operating parameters. Subsequently, the fitting of the data to the Gates-Gaudin-Schumann (GGS), Rosin-Rammler (RRS) and SWEF PSD functions was evaluated under statistical criteria. The fitting of the evaluated distribution models showed that these functions are characterized as being sufficiently accurate, as the estimation error does not exceed 3.0% in any of the cases. In the particular case of the Swebrec function, reproducibility for all the products is high. Furthermore, its estimation error does not exceed 2.7% in any of the cases, with a correlation coefficient of the ratio between experimental and simulated data greater than 0.99. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 5329 KiB

Open AccessArticle

Copper Dissolution from Black Copper Ore under Oxidizing and Reducing Conditions

by Oscar Benavente, María Cecilia Hernández, Evelyn Melo, Damián Núñez, Víctor Quezada and Yuri Zepeda

Metals 2019, 9(7), 799; https://doi.org/10.3390/met9070799 - 19 Jul 2019

Cited by 14 | Viewed by 3455

Abstract

Black copper oxides are amorphous materials of copper-bearing phases of manganese. They are complex mineral compounds with difficult to recognize mineralogy and have slow dissolution kinetics in conventional hydrometallurgical processes. This study evaluates the effects of various leaching media on copper dissolution from [...] Read more.

Black copper oxides are amorphous materials of copper-bearing phases of manganese. They are complex mineral compounds with difficult to recognize mineralogy and have slow dissolution kinetics in conventional hydrometallurgical processes. This study evaluates the effects of various leaching media on copper dissolution from black copper minerals. Leach of a pure black copper sample from Lomas Bayas Mine and another from a regional mine were characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), scanning electron microscopy (SEM), Qemscan and mechanically prepared for acid leaching under standard, oxidizing and reducing conditions through the addition of oxygen, iron sulfate or sulfur dioxide, respectively. Standard and high potential leaching (770 mV (SHE)) results in a copper dissolution rate of 70% and manganese dissolution rate of 2%. The addition of potential reducing agents (FeSO₄ or SO₂) decreases the redox potential to 696 and 431 mV, respectively, and favors the dissolution of manganese, thus increasing the overall copper extraction rate. The addition of SO₂ results in the lowest redox potential and the highest copper extraction rates of 86.2% and 75.5% for the Lomas Bayas and regional samples, respectively, which represent an increase of 15% over the copper extract rates under standard and oxidizing conditions. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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13 pages, 1938 KiB

Open AccessArticle

Leaching of Pure Chalcocite in a Chloride Media Using Sea Water and Waste Water

by Norman Toro, Williams Briceño, Kevin Pérez, Manuel Cánovas, Emilio Trigueros, Rossana Sepúlveda and Pía Hernández

Metals 2019, 9(7), 780; https://doi.org/10.3390/met9070780 - 12 Jul 2019

Cited by 21 | Viewed by 3377

Abstract

Chalcocite is the most important and abundant secondary copper ore in the world with a rapid dissolution of copper in an acid-chloride environment. In this investigation, the methodology of surface optimization will be applied to evaluate the effect of three independent variables (time, [...] Read more.

Chalcocite is the most important and abundant secondary copper ore in the world with a rapid dissolution of copper in an acid-chloride environment. In this investigation, the methodology of surface optimization will be applied to evaluate the effect of three independent variables (time, concentration of sulfuric acid and chloride concentration) in the leaching of pure chalcocite to extract the copper with the objective of obtaining a quadratic model that allows us to predict the extraction of copper. The kinetics of copper dissolution in regard to the function of temperature is also analyzed. An ANOVA indicates that the linear variables with the greatest influence are time and the chloride concentration. Also, the concentration of chloride-time exerts a significant synergic effect in the quadratic model. The ANOVA indicates that the quadratic model is representative and the R² value of 0.92 is valid. The highest copper extraction (67.75%) was obtained at 48 h leaching under conditions of 2 mol/L H₂SO₄ and 100 g/L chloride. The XRD analysis shows the formation of a stable and non-polluting residue; such as elemental sulfur (S⁰). This residue was obtained in a leaching time of 4 h at room temperature under conditions of 0.5 mol/L H₂SO₄ and 50 g/L Cl⁻. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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12 pages, 5226 KiB

Open AccessArticle

Comparison of Butyric Acid Leaching Behaviors of Zinc from Three Basic Oxygen Steelmaking Filter Cakes

by Jingxiu Wang, Zhe Wang, Zhongzhi Zhang and Guangqing Zhang

Metals 2019, 9(4), 417; https://doi.org/10.3390/met9040417 - 07 Apr 2019

Cited by 5 | Viewed by 2516

Abstract

The selective leaching of zinc from three different basic oxygen steelmaking (BOS) filter cakes by butyric acid was investigated to compare the leaching behaviors of zinc and further to establish the correlation of the zinc leaching performances and the chemical compositions. The effects [...] Read more.

The selective leaching of zinc from three different basic oxygen steelmaking (BOS) filter cakes by butyric acid was investigated to compare the leaching behaviors of zinc and further to establish the correlation of the zinc leaching performances and the chemical compositions. The effects of acid concentration and the acid to solid (L/S) stoichiometric ratio were studied, with different optimal leaching conditions obtained. BOS-1 showed the lowest leachability with only less than 10% of zinc removed by 0.5 M acid concentration and 90% of the L/S stoichiometric ratio in 10 h. The best zinc selectivity was achieved with BOS-2 at 51.2% of zinc leaching efficiency, with only 0.47% of iron loss under optimal conditions of 1.5 M acid concentration and a 70% stoichiometric ratio. BOS-3 showed the highest leaching of zinc but the optimal conditions depend on the priority consideration. Using 1.0 M acid and 90% stoichiometric ratio for 10 h, the leaching efficiency of zinc was 84.6% with 20% iron loss. The filter cakes and the leaching residues were characterized. The results indicate different zinc and iron leaching behaviors, which were probably related to the storage conditions, zinc containing phases and the leaching parameters. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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11 pages, 2005 KiB

Open AccessReview

A Review of the Cyanidation Treatment of Copper-Gold Ores and Concentrates

by Diego Medina and Corby G. Anderson

Metals 2020, 10(7), 897; https://doi.org/10.3390/met10070897 - 05 Jul 2020

Cited by 53 | Viewed by 20242

Abstract

Globally, copper, silver, and gold orebody grades have been dropping, and the mineralogy surrounding them has become more diversified and complex. The cyanidation process for gold production has remained dominant for over 130 years because of its selectivity and feasibility in the mining [...] Read more.

Globally, copper, silver, and gold orebody grades have been dropping, and the mineralogy surrounding them has become more diversified and complex. The cyanidation process for gold production has remained dominant for over 130 years because of its selectivity and feasibility in the mining industry. For this reason, the industry has been adjusting its methods for the extraction of gold, by utilizing more efficient processes and technologies. Often, gold may be found in conjunction with copper and silver in ores and concentrates. Hence, the application of cyanide to these types of ores can present some difficulty, as the diversity of minerals found within these ores can cause the application of cyanidation to become more complicated. This paper outlines the practices, processes, and reagents proposed for the effective treatment of these ores. The primary purpose of this review paper is to present the hydrometallurgical processes that currently exist in the mining industry for the treatment of silver, copper, and gold ores, as well as concentrate treatments. In addition, this paper aims to present the most important challenges that the industry currently faces, so that future processes that are both more efficient and feasible may be established. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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34 pages, 10964 KiB

Open AccessFeature PaperReview

Hydrometallurgical Recovery of Rare Earth Elements from NdFeB Permanent Magnet Scrap: A Review

by Yuanbo Zhang, Foquan Gu, Zijian Su, Shuo Liu, Corby Anderson and Tao Jiang

Metals 2020, 10(6), 841; https://doi.org/10.3390/met10060841 - 24 Jun 2020

Cited by 57 | Viewed by 11365

Abstract

NdFeB permanent magnet scrap is regarded as an important secondary resource which contains rare earth elements (REEs) such as Nd, Pr and Dy. Recovering these valuable REEs from the NdFeB permanent magnet scrap not only increases economic potential, but it also helps to [...] Read more.

NdFeB permanent magnet scrap is regarded as an important secondary resource which contains rare earth elements (REEs) such as Nd, Pr and Dy. Recovering these valuable REEs from the NdFeB permanent magnet scrap not only increases economic potential, but it also helps to reduce problems relating to disposal and the environment. Hydrometallurgical routes are considered to be the primary choice for recovering the REEs because of higher REEs recovery and its application to all types of magnet compositions. In this paper, the authors firstly reviewed the chemical and physical properties of NdFeB permanent magnet scrap, and then carried out an in-depth discussion on a variety of hydrometallurgical processes for recovering REEs from the NdFeB permanent magnet scrap. The methods mainly included selective leaching or complete leaching processes followed by precipitation, solvent extraction or ionic liquids extraction processes. Particular attention is devoted to the specific technical challenge that emerges in the hydrometallurgical recovery of REEs from NdFeB permanent magnet scrap and to the corresponding potential measures for improving REEs recovery by promoting the processing efficiency. This summarized review will be useful for researchers who are developing processes for recovering REEs from NdFeB permanent magnet scrap. Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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Other

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2 pages, 181 KiB

Open AccessCorrection

Correction: Torres, D. et al. Leaching Manganese Nodules in an Acid Medium and Room Temperature Comparing the Use of Different Fe Reducing Agents. Metals 2019, 9, 1316

by David Torres, Luís Ayala, Manuel Saldaña, Manuel Cánovas, Ricardo I. Jeldres, Steven Nieto, Jonathan Castillo, Pedro Robles and Norman Toro

Metals 2020, 10(4), 506; https://doi.org/10.3390/met10040506 - 14 Apr 2020

Cited by 1 | Viewed by 1661

Abstract

The authors wish to make the following corrections to this paper [...] Full article

(This article belongs to the Special Issue Advances in Mineral Processing and Hydrometallurgy)

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