Mechanics of Polymer and Polymer Composite Materials and Structures

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Composites and Nanocomposites".

Deadline for manuscript submissions: closed (25 September 2021) | Viewed by 57437

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Institute for Nanomaterials, Advanced Technologies and Innovation (CXI), Technical University of Liberec (TUL), Studentska 2, 461 17 Liberec, Czech Republic
Interests: solid mechanics (mathematical-physical modeling, simulation and experimentation); advanced composites; continuum mechanics; fatigue; fracture and damage mechanics; computational solid mechanics; design and analysis of materials and structures
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Guest Editor
Center of Excellence in Experimental Solid Mechanics and Dynamics, School of Mechanical Engineering, Iran University of Science and Technology, Tehran 13114-16846, Iran
Interests: fracture mechanics; computational solid mechanics; experimental solid mechanics
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Machinery Construction, Institute for Nanomaterials, Advanced Technologies and Innovation (CXI), Technical University of Liberec, Studentská 1402/2, 46117 Liberec 1, Czech Republic
Interests: materials characterization; modeling; optimization; composites; machine design; machine learning
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Polymers and polymer composites are advanced technological materials with excellent features that are widely used in the manufacturing of structures for advanced industries, such as the aerospace, automotive, robotics, marine, oil and gas, and energy industries. These materials continue to fuel the growth of new applications in markets such as transportation, infrastructure, construction, and sports. Therefore, new advancements in the manufacturing, design, and mechanical analysis of polymers and polymer composites have been the goal of many research projects in the academic and industrial sectors.

This Special Issue on the mechanics of polymers and polymer composites promotes and contributes to the new developments and findings related to manufacturing, design, and analysis of polymers and polymer composites at material and structural levels. This Special Issue covers new topics involving the development of new materials, manufacturing science, characterization, mathematical modeling, physical behavior, computational science, experimental solid mechanics, and structural design at different micro-to-macro and structural scales. The Special Issue contains the following research topics:

  • Development of new materials: Thermoplastic, thermoset, FGM, FRP composites, FML, coatings, etc.
  • Manufacturing science: Additive manufacturing, synthesis, molding, forming, etc.
  • Characterization: Mechanical, thermal, physical, etc.
  • Mathematical modeling: Elastic, hyperelastic, viscoelastic, plastic, damage, failure, fatigue, etc.
  • Novel testing methods: Static, monotonic, dynamic, impact, cyclic, creep, etc.
  • Physical behavior: Moisture absorption, erosive or corrosive environmental effects, aging and long-term performance, etc.
  • Computational solid mechanics: Finite element method, finite differences, peridynamics, real-time simulation, etc.
  • Experimental solid mechanics: Material characterization, determination of structural responses, testing of complex structures, experimental stress analysis, etc.
  • Design: Microsystems, material levels, structures and assemblies, super-structures, etc.
  • New Sciences: Photomechanics, repair mechanics, nanomechanics, micromechanics, etc.
  • New applications: Aerospace, automotive, robotics, marine, energy, etc.

Authors are welcome to submit their latest research and findings in the form of original full articles or reviews on the above-mentioned topics.

Dr. Seyed Saeid Rahimian Koloor
Prof. Dr. Majid Reza Ayatollahi
Dr. Michal Petrů
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • polymers
  • polymer composites
  • new polymer-based materials
  • manufacturing science
  • characterization
  • mathematical modeling
  • physical behavior
  • computational solid mechanics
  • novel experimental methods
  • new applications

Published Papers (17 papers)

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17 pages, 7381 KiB  
Article
Mechanical Behaviour of Pin-Reinforced Foam Core Sandwich Panels Subjected to Low Impact Loading
by Ali Farokhi Nejad, Seyed Saeid Rahimian Koloor, Syed Mohd Saiful Azwan Syed Hamzah and Mohd Yazid Yahya
Polymers 2021, 13(21), 3627; https://doi.org/10.3390/polym13213627 - 21 Oct 2021
Cited by 16 | Viewed by 2579
Abstract
As a light structure, composite sandwich panels are distinguished by their significant bending stiffness that is rapidly used in the manufacture of aircraft bodies. This study focuses on the mechanical behaviour of through-thickness polymer, pin-reinforced foam core sandwich panels subjected to indentation and [...] Read more.
As a light structure, composite sandwich panels are distinguished by their significant bending stiffness that is rapidly used in the manufacture of aircraft bodies. This study focuses on the mechanical behaviour of through-thickness polymer, pin-reinforced foam core sandwich panels subjected to indentation and low impact loading. Experimental and computational approaches are used to study the global and internal behaviour of the sandwich panel. The samples for experimental testing were made from glass/polyester laminates as the face sheets and polyurethane foam as the foam core. To further reinforce the samples against bending, different sizes of polymeric pins were implemented on the sandwich panels. The sandwich panel was fabricated using the vacuum infusion process. Using the experimental data, a finite element model of the sample was generated in LS-DYNA software, and the effect of pin size and loading rate were examined. Results of the simulation were validated through a proper prediction compared to the test data. The results of the study show that using polymeric pins, the flexural strength of the panel significantly increased under impact loading. In addition, the impact resistance of the pin-reinforced foam core panel increased up to 20%. Moreover, the size of pins has a significant influence on the flexural behaviour while the sample was under a moderate strain rate. To design an optimum pin-reinforced sandwich panel a “design of experiment model” was generated to predict energy absorption and the maximum peak load of proposed sandwich panels. The best design of the panel is recommended with 1.8 mm face sheet thickness and 5 mm pins diameter. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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19 pages, 7533 KiB  
Article
Geometry Effects on Mode I Brittle Fracture in VO-Notched PMMA Specimens
by Robab Bahadori, Majid Reza Ayatollahi, Sergio Cicero and José Alberto Álvarez
Polymers 2021, 13(17), 3017; https://doi.org/10.3390/polym13173017 - 06 Sep 2021
Viewed by 1995
Abstract
This paper gathers experimental and theoretical investigations about both the geometry-dependent fracture initiation angle and the fracture strength in VO-notched polymethyl methacrylate (PMMA) specimens under mode I loading conditions. The numerical analyses revealed that despite the application of pure mode I loading on [...] Read more.
This paper gathers experimental and theoretical investigations about both the geometry-dependent fracture initiation angle and the fracture strength in VO-notched polymethyl methacrylate (PMMA) specimens under mode I loading conditions. The numerical analyses revealed that despite the application of pure mode I loading on the geometrically symmetric VO-notched samples, the maximum tangential stress occurs at two points symmetrically placed on either side of the notch bisector line. The experimental tests performed on some specimens showed that a crack does not necessarily propagate along the notch bisector line. Stress-based theoretical studies were then carried out to justify the experimental findings. The conventional maximum tangential stress (MTS) criterion gave weak predictions of the fracture. Therefore, the predictions were checked with the generalized MTS (GMTS) criterion by taking into consideration the higher-order stress terms. It was demonstrated that the GMTS criterion predictions have satisfactory consistency with the experimental results of the crack initiation angle and the fracture strength. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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20 pages, 4662 KiB  
Article
Optimization of a Totally Fiber-Reinforced Plastic Composite Sandwich Construction of Helicopter Floor for Weight Saving, Fuel Saving and Higher Safety
by Alaa Al-Fatlawi, Károly Jármai and György Kovács
Polymers 2021, 13(16), 2735; https://doi.org/10.3390/polym13162735 - 15 Aug 2021
Cited by 6 | Viewed by 3954
Abstract
The application of fiber-reinforced plastic (FRP) composites as structural elements of air vehicles provides weight saving, which results in a reduction in fuel consumption, fuel cost, and air pollution, and a higher speed. The goal of this research was to elaborate a new [...] Read more.
The application of fiber-reinforced plastic (FRP) composites as structural elements of air vehicles provides weight saving, which results in a reduction in fuel consumption, fuel cost, and air pollution, and a higher speed. The goal of this research was to elaborate a new optimization method for a totally FRP composite construction for helicopter floors. During the optimization, 46 different layer combinations of 4 different FRP layers (woven glass fibers with phenolic resin; woven glass fibers with epoxy resin; woven carbon fibers with epoxy resin; hybrid composite) and FRP honeycomb core structural elements were investigated. The face sheets were composed of a different number of layers with cross-ply, angle-ply, and multidirectional fiber orientations. During the optimization, nine design constraints were considered: deflection; face sheet stress (bending load, end loading); stiffness; buckling; core shear stress; skin wrinkling; intracell buckling; and shear crimping. The single-objective weight optimization was solved by applying the Interior Point Algorithm of the Matlab software, the Generalized Reduced Gradient (GRG) Nonlinear Algorithm of the Excel Solver software, and the Laminator software. The Digimat-HC software solved the numerical models for the optimum sandwich plates of helicopter floors. The main contribution is developing a new method for optimizing a totally FRP composite sandwich structure—due to its material constituents and construction—that is more advantageous than traditional helicopter floors. A case study validated this fact. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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24 pages, 3718 KiB  
Article
Redesign of the Geometry of Parts Produced from PBT Composite to Improve Their Operational Behavior
by Dan Dobrotă and Sergiu Viorel Lazăr
Polymers 2021, 13(15), 2536; https://doi.org/10.3390/polym13152536 - 31 Jul 2021
Cited by 2 | Viewed by 1579
Abstract
Parts produced from PBT-GF30 (70% polybutylene terephthalate +30% fiberglass) are very often used in car construction, due to the properties of this material. The current trend is to make parts with a shape designed to be as complex as possible, to take over [...] Read more.
Parts produced from PBT-GF30 (70% polybutylene terephthalate +30% fiberglass) are very often used in car construction, due to the properties of this material. The current trend is to make parts with a shape designed to be as complex as possible, to take over many functions in operation. During the research, a part that is a component of the structure of car safety systems, and that must be completely reliable in operation, was analyzed. This piece has a complex shape that involves the intersection of several walls. Thus, the research aimed at establishing the optimal radius of connection between the walls (R), the ratio between the thickness of the intersecting walls (K) and the angle of inclination of the walls (α). The composite central design method was used to design the experiments. Both new parts and parts subject to an artificial aging process were tested. All parts were subjected to shear stress, to determine the load (L) and displacement (D) at which they break. In order to observe other changes in the properties of the parts, in addition to the mechanical ones, an analysis of the color of the new and aged parts was performed, as well as a topography of the surface layer in the breaking area. The design of the parts involved changes to the parameters of the injection process. In these conditions, a PBT-GF30 viscosity analysis was performed for new and artificially aged parts. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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21 pages, 6927 KiB  
Article
Effect of Manufacturing on the Transverse Response of Polymer Matrix Composites
by Sagar P. Shah and Marianna Maiarù
Polymers 2021, 13(15), 2491; https://doi.org/10.3390/polym13152491 - 28 Jul 2021
Cited by 31 | Viewed by 2897
Abstract
The effect of residual stress build-up on the transverse properties of thermoset composites is studied through direct and inverse process modeling approaches. Progressive damage analysis is implemented to characterize composite stiffness and strength of cured composites microstructures. A size effect study is proposed [...] Read more.
The effect of residual stress build-up on the transverse properties of thermoset composites is studied through direct and inverse process modeling approaches. Progressive damage analysis is implemented to characterize composite stiffness and strength of cured composites microstructures. A size effect study is proposed to define the appropriate dimensions of Representative Volume Elements (RVEs). A comparison between periodic (PBCs) and flat (FBCs) boundary conditions during curing is performed on converged RVEs to establish computationally efficient methodologies. Transverse properties are analyzed as a function of the fiber packing through the nearest fiber distance statistical descriptor. A reasonable mechanical equivalence is achieved for RVEs consisting of 40 fibers. It has been found that process-induced residual stresses and fiber packing significantly contribute to the scatter in composites transverse strength. Variation of ±5% in average strength and 18% in standard deviation are observed with respect to ideally cured RVEs that neglect residual stresses. It is established that process modeling is needed to optimize the residual stress state and improve composite performance. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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23 pages, 10577 KiB  
Article
Polymer Composites Based on Polycarbonate (PC) Applied to Additive Manufacturing Using Melted and Extruded Manufacturing (MEM) Technology
by Katarzyna Bulanda, Mariusz Oleksy, Rafał Oliwa, Grzegorz Budzik, Łukasz Przeszłowski, Jacek Fal and Teofil Jesionowski
Polymers 2021, 13(15), 2455; https://doi.org/10.3390/polym13152455 - 26 Jul 2021
Cited by 21 | Viewed by 3387
Abstract
As part of the present work, polymer composites used in 3D printing technology, especially in Melted and Extruded Manufacturing (MEM) technology, were obtained. The influence of modified fillers such as alumina modified silica, quaternary ammonium bentonite, lignin/silicon dioxide hybrid filler and unmodified multiwalled [...] Read more.
As part of the present work, polymer composites used in 3D printing technology, especially in Melted and Extruded Manufacturing (MEM) technology, were obtained. The influence of modified fillers such as alumina modified silica, quaternary ammonium bentonite, lignin/silicon dioxide hybrid filler and unmodified multiwalled carbon nanotubes on the properties of polycarbonate (PC) composites was investigated. In the first part of the work, the polymer and its composites containing 0.5–3 wt.% filler were used to obtain a filament using the proprietary technological line. The moldings for testing functional properties were obtained with the use of 3D printing and injection molding techniques. In the next part of the work, the rheological properties—mass flow rate (MFR) and mechanical properties—Rockwell hardness, Charpy impact strength and static tensile strength with Young’s modulus were examined. The structure of the obtained composites was also described and determined using scanning electron microscopy (SEM). The porosity, roughness and dimensional stability of samples obtained by 3D printing were also determined. On the other hand, the physicochemical properties were presented on the basis of the research results using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), wide angle X-ray scattering analysis (WAXS) and Fourier Transform infrared spectroscopy (FT-IR). Additionally, the electrical conductivity of the obtained composites was investigated. On the basis of the obtained results, it was found that both the amount and the type of filler significantly affected the functional properties of the composites tested in the study. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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23 pages, 3997 KiB  
Article
A Comparative Study on the Role of Polyvinylpyrrolidone Molecular Weight on the Functionalization of Various Carbon Nanotubes and Their Composites
by Muthuraman Namasivayam, Mats R. Andersson and Joseph G. Shapter
Polymers 2021, 13(15), 2447; https://doi.org/10.3390/polym13152447 - 25 Jul 2021
Cited by 8 | Viewed by 3323
Abstract
Polyvinylidene fluoride (PVDF) nanocomposites filled with polyvinylpyrrolidone (PVP) wrapped carbon nanotubes were prepared via a solution casting technique. The effect of the molecular weight (polymer chain length) of the PVP on the ability to wrap different nanotube structures and its impact towards nanotube [...] Read more.
Polyvinylidene fluoride (PVDF) nanocomposites filled with polyvinylpyrrolidone (PVP) wrapped carbon nanotubes were prepared via a solution casting technique. The effect of the molecular weight (polymer chain length) of the PVP on the ability to wrap different nanotube structures and its impact towards nanotube dispersibility in the polymer matrix was explored. The study was conducted with PVP of four different molecular weights and nanotubes of three different structures. The composites that exhibit an effective nanotube dispersion lead to a nanotube network that facilitates improved thermal, electrical, and mechanical properties. It was observed that nanotubes of different structures exhibit stable dispersions in the polymer matrix though PVP functionalization of different molecular weights, but the key is achieving an effective nanotube dispersion at low PVP concentrations. This is observed in MWNT and AP-SWNT based composites with PVP of low molecular weight, leading to a thermal conductivity enhancement of 147% and 53%, respectively, while for P3-SWNT based composites, PVP of high molecular weight yields an enhancement of 25% in thermal conductivity compared to the non-functionalized CNT-PVDF composite. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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18 pages, 6474 KiB  
Article
Displacement Rate Effects on the Mode II Shear Delamination Behavior of Carbon Fiber/Epoxy Composites
by Kean Ong Low, Mahzan Johar, Haris Ahmad Israr, Khong Wui Gan, Seyed Saeid Rahimian Koloor, Michal Petrů and King Jye Wong
Polymers 2021, 13(11), 1881; https://doi.org/10.3390/polym13111881 - 06 Jun 2021
Cited by 6 | Viewed by 2765
Abstract
This paper studies the influence of displacement rate on mode II delamination of unidirectional carbon/epoxy composites. End-notched flexure test is performed at displacement rates of 1, 10, 100 and 500 mm/min. Experimental results reveal that the mode II fracture toughness GIIC increases [...] Read more.
This paper studies the influence of displacement rate on mode II delamination of unidirectional carbon/epoxy composites. End-notched flexure test is performed at displacement rates of 1, 10, 100 and 500 mm/min. Experimental results reveal that the mode II fracture toughness GIIC increases with the displacement, with a maximum increment of 45% at 100 mm/min. In addition, scanning electron micrographs depict that fiber/matrix interface debonding is the major damage mechanism at 1 mm/min. At higher speeds, significant matrix-dominated shear cusps are observed contributing to higher GIIC. Besides, it is demonstrated that the proposed rate-dependent model is able to fit the experimental data from the current study and the open literature generally well. The mode II fracture toughness measured from the experiment or deduced from the proposed model can be used in the cohesive element model to predict failure. Good agreement is found between the experimental and numerical results, with a maximum difference of 10%. The numerical analyses indicate crack jump occurs suddenly after the peak load is attained, which leads to the unstable crack propagation seen in the experiment. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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19 pages, 13508 KiB  
Article
Constant Temperature Approach for the Assessment of Injection Molding Parameter Influence on the Fatigue Behavior of Short Glass Fiber Reinforced Polyamide 6
by Selim Mrzljak, Alexander Delp, André Schlink, Jan-Christoph Zarges, Daniel Hülsbusch, Hans-Peter Heim and Frank Walther
Polymers 2021, 13(10), 1569; https://doi.org/10.3390/polym13101569 - 13 May 2021
Cited by 11 | Viewed by 2802
Abstract
Short glass fiber reinforced plastics (SGFRP) offer superior mechanical properties compared to polymers, while still also enabling almost unlimited geometric variations of components at large-scale production. PA6-GF30 represents one of the most used SGFRP for series components, but the impact of injection molding [...] Read more.
Short glass fiber reinforced plastics (SGFRP) offer superior mechanical properties compared to polymers, while still also enabling almost unlimited geometric variations of components at large-scale production. PA6-GF30 represents one of the most used SGFRP for series components, but the impact of injection molding process parameters on the fatigue properties is still insufficiently investigated. In this study, various injection molding parameter configurations were investigated on PA6-GF30. To take the significant frequency dependency into account, tension–tension fatigue tests were performed using multiple amplitude tests, considering surface temperature-adjusted frequency to limit self-heating. The frequency adjustment leads to shorter testing durations as well as up to 20% higher lifetime under fatigue loading. A higher melt temperature and volume flow rate during injection molding lead to an increase of 16% regarding fatigue life. In situ X-ray microtomography analysis revealed that this result was attributed to a stronger fiber alignment with larger fiber lengths in the flow direction. Using digital volume correlation, differences of up to 100% in local strain values at the same stress level for different injection molding process parameters were identified. The results prove that the injection molding parameters have a high influence on the fatigue properties and thus offer a large optimization potential, e.g., with regard to the component design. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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24 pages, 3974 KiB  
Article
Simulation of Mode I Interlaminar Damage of a GFRP Composite Using Cohesive Laws in the Framework of the Equivalent LEFM R-Curve and an Optimised Algorithm
by Luis Torres, Karin Saavedra, Gonzalo Pincheira and Juan Carlos Pina
Polymers 2021, 13(9), 1482; https://doi.org/10.3390/polym13091482 - 04 May 2021
Cited by 2 | Viewed by 2450
Abstract
This paper is focused on mode I delimitation of a unidirectional glass fibre reinforced polymer (GFRP) composite. The aim is to propose an accurate and simple characterisation of three cohesive zone models (CZM)—bilinear, trilinear, and potential—from the measurement of the load-displacement curve during [...] Read more.
This paper is focused on mode I delimitation of a unidirectional glass fibre reinforced polymer (GFRP) composite. The aim is to propose an accurate and simple characterisation of three cohesive zone models (CZM)—bilinear, trilinear, and potential—from the measurement of the load-displacement curve during a double cantilever beam experimental test. For that, a framework based on the equivalent linear elastic fracture mechanics (LEFM) R-curve is here proposed, which has never before been developed for a bilinear and a potential CZM. Besides, in order to validate this strategy, an optimisation algorithm for solving an inverse problem is also implemented. It is shown that the parameters’ identification using the equivalent LEFM R-curve enables the same accuracy but reduces 72% the numerical efforts respect to a “blind fitting” (i.e., the optimisation algorithm). Therefore, even if optimisation techniques become popular at present due to their easy numerical implementation, strategies founded on physical models are still better solutions especially when evaluating the objective function is expensive as in mechanical problems. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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19 pages, 6367 KiB  
Article
Fabrication and Thermo-Electro and Mechanical Properties Evaluation of Helical Multiwall Carbon Nanotube-Carbon Fiber/Epoxy Composite Laminates
by Alamry Ali, Andri Andriyana, Shukur Bin Abu Hassan and Bee Chin Ang
Polymers 2021, 13(9), 1437; https://doi.org/10.3390/polym13091437 - 29 Apr 2021
Cited by 8 | Viewed by 2372
Abstract
The development of advanced composite materials has taken center stage because of its advantages over traditional materials. Recently, carbon-based advanced additives have shown promising results in the development of advanced polymer composites. The inter- and intra-laminar fracture toughness in modes I and II, [...] Read more.
The development of advanced composite materials has taken center stage because of its advantages over traditional materials. Recently, carbon-based advanced additives have shown promising results in the development of advanced polymer composites. The inter- and intra-laminar fracture toughness in modes I and II, along with the thermal and electrical conductivities, were investigated. The HMWCNTs/epoxy composite was prepared using a multi-dispersion method, followed by uniform coating at the mid-layers of the CF/E prepregs interface using the spray coating technique. Analysis methods, such as double cantilever beam (DCB) and end notched flexure (ENF) tests, were carried out to study the mode I and II fracture toughness. The surface morphology of the composite was analyzed using field emission scanning electron microscopy (FESEM). The DCB test showed that the fracture toughness of the 0.2 wt.% and 0.4 wt.% HMWCNT composite laminates was improved by 39.15% and 115.05%, respectively, compared with the control sample. Furthermore, the ENF test showed that the mode II interlaminar fracture toughness for the composite laminate increased by 50.88% and 190%, respectively. The FESEM morphology results confirmed the HMWCNTs bridging at the fracture zones of the CF/E composite and the improved interlaminar fracture toughness. The thermogravimetric analysis (TGA) results demonstrated a strong intermolecular bonding between the epoxy and HMWCNTs, resulting in an improved thermal stability. Moreover, the differential scanning calorimetry (DSC) results confirmed that the addition of HMWCNT shifted the Tg to a higher temperature. An electrical conductivity study demonstrated that a higher CNT concentration in the composite laminate resulted in a higher conductivity improvement. This study confirmed that the demonstrated dispersion technique could create composite laminates with a strong interfacial bond interaction between the epoxy and HMWCNT, and thus improve their properties. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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18 pages, 5113 KiB  
Article
Flammability, Tensile, and Morphological Properties of Oil Palm Empty Fruit Bunches Fiber/Pet Yarn-Reinforced Epoxy Fire Retardant Hybrid Polymer Composites
by M.J. Suriani, Fathin Sakinah Mohd Radzi, R.A. Ilyas, Michal Petrů, S.M. Sapuan and C.M. Ruzaidi
Polymers 2021, 13(8), 1282; https://doi.org/10.3390/polym13081282 - 14 Apr 2021
Cited by 56 | Viewed by 4116
Abstract
Oil palm empty fruit bunches (OPEFB) fiber is a natural fiber that possesses many advantages, such as biodegradability, eco-friendly, and renewable nature. The effect of the OPEFB fiber loading reinforced fire retardant epoxy composites on flammability and tensile properties of the polymer biocomposites [...] Read more.
Oil palm empty fruit bunches (OPEFB) fiber is a natural fiber that possesses many advantages, such as biodegradability, eco-friendly, and renewable nature. The effect of the OPEFB fiber loading reinforced fire retardant epoxy composites on flammability and tensile properties of the polymer biocomposites were investigated. The tests were carried out with four parameters, which were specimen A (constant), specimen B (20% of fiber), specimen C (35% of fiber), and specimen D (50% of fiber). The PET yarn and magnesium hydroxide were used as the reinforcement material and fire retardant agent, respectively. The results were obtained from several tests, which were the horizontal burning test, tensile test, and scanning electron microscopy (SEM). The result for the burning test showed that specimen B exhibited better flammability properties, which had the lowest average burning rate (11.47 mm/min). From the tensile strength, specimen A revealed the highest value of 10.79 N/mm2. For the SEM morphological test, increasing defects on the surface ruptured were observed that resulted in decreased tensile properties of the composites. It can be summarized that the flammability and tensile properties of OPEFB fiber reinforced fire retardant epoxy composites were reduced when the fiber volume contents were increased at the optimal loading of 20%, with the values of 11.47 mm/min and 4.29 KPa, respectively. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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12 pages, 1846 KiB  
Article
Critical Load Prediction in Notched E/Glass–Epoxy-Laminated Composites Using the Virtual Isotropic Material Concept Combined with the Average Strain Energy Density Criterion
by Marcos Sánchez, Sergio Cicero, Ali Reza Torabi and Majid Reza Ayatollahi
Polymers 2021, 13(7), 1057; https://doi.org/10.3390/polym13071057 - 27 Mar 2021
Cited by 7 | Viewed by 1782
Abstract
This paper attempts to validate the application of the Virtual Isotropic Material Concept (VIMC) in combination with the average strain energy density (ASED) criterion to predict the critical load in notched laminated composites. This methodology was applied to E/glass–epoxy-laminated composites containing U-notches. For [...] Read more.
This paper attempts to validate the application of the Virtual Isotropic Material Concept (VIMC) in combination with the average strain energy density (ASED) criterion to predict the critical load in notched laminated composites. This methodology was applied to E/glass–epoxy-laminated composites containing U-notches. For this purpose, a series of fracture test data recently published in the literature on specimens with different notch tip radii, lay-up configurations, and a number of plies were employed. It was shown that the VIMC–ASED combined approach provided satisfactory predictions of the last-ply failure (LPF) loads (i.e., critical loads). Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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17 pages, 46452 KiB  
Article
Axial and Radial Compression Behavior of Composite Rocket Launcher Developed by Robotized Filament Winding: Simulation and Experimental Validation
by Rajesh Mishra, Bijoy Kumar Behera, Sayan Mukherjee, Michal Petru and Miroslav Muller
Polymers 2021, 13(4), 517; https://doi.org/10.3390/polym13040517 - 09 Feb 2021
Cited by 4 | Viewed by 3765
Abstract
The principal objective of the work is to compare among carbon-glass filament wound epoxy matrix hybrid composites with a different fiber ratio made by robotized winding processes and optimize the geometry suitable for the Rocket Propelled Grenade Launcher. ANSYS based finite element analysis [...] Read more.
The principal objective of the work is to compare among carbon-glass filament wound epoxy matrix hybrid composites with a different fiber ratio made by robotized winding processes and optimize the geometry suitable for the Rocket Propelled Grenade Launcher. ANSYS based finite element analysis was used to predict the axial as well as radial compression behavior. Experimental samples were developed by a robot-controlled filament winding process that was incorporated with continuous resin impregnation. The experimental samples were evaluated for the corresponding compressional properties. Filament wound tubular composite structures were developed by changing the sequence of stacking of hoop layers and helical layers, and also by changing the angle of wind of the helical layers while keeping the sequence constant. The samples were developed from carbon and glass filaments with different carbon proportions (0%, 25%, 50%, 75%, and 100%) and impregnated with epoxy resin. The compressional properties of the tubular composites that were prepared by filament winding were compared with the predicted axial and radial compressional properties from computational modelling using the finite element model. A very high correlation and relatively small prediction error was obtained. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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18 pages, 3268 KiB  
Article
Thermal Delamination Modelling and Evaluation of Aluminium–Glass Fibre-Reinforced Polymer Hybrid
by Zhen Pei Chow, Zaini Ahmad, King Jye Wong, Seyed Saeid Rahimian Koloor and Michal Petrů
Polymers 2021, 13(4), 492; https://doi.org/10.3390/polym13040492 - 04 Feb 2021
Cited by 11 | Viewed by 2467
Abstract
This paper aims to propose a temperature-dependent cohesive model to predict the delamination of dissimilar metal–composite material hybrid under Mode-I and Mode-II delamination. Commercial nonlinear finite element (FE) code LS-DYNA was used to simulate the material and cohesive model of hybrid aluminium–glass fibre-reinforced [...] Read more.
This paper aims to propose a temperature-dependent cohesive model to predict the delamination of dissimilar metal–composite material hybrid under Mode-I and Mode-II delamination. Commercial nonlinear finite element (FE) code LS-DYNA was used to simulate the material and cohesive model of hybrid aluminium–glass fibre-reinforced polymer (GFRP) laminate. For an accurate representation of the Mode-I and Mode-II delamination between aluminium and GFRP laminates, cohesive zone modelling with bilinear traction separation law was implemented. Cohesive zone properties at different temperatures were obtained by applying trends of experimental results from double cantilever beam and end notched flexural tests. Results from experimental tests were compared with simulation results at 30, 70 and 110 °C to verify the validity of the model. Mode-I and Mode-II FE models compared to experimental tests show a good correlation of 5.73% and 7.26% discrepancy, respectively. Crack front stress distribution at 30 °C is characterised by a smooth gradual decrease in Mode-I stress from the centre to the edge of the specimen. At 70 °C, the entire crack front reaches the maximum Mode-I stress with the exception of much lower stress build-up at the specimen’s edge. On the other hand, the Mode-II stress increases progressively from the centre to the edge at 30 °C. At 70 °C, uniform low stress is built up along the crack front with the exception of significantly higher stress concentrated only at the free edge. At 110 °C, the stress distribution for both modes transforms back to the similar profile, as observed in the 30 °C case. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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Review

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23 pages, 3526 KiB  
Review
Hybrid and Synthetic FRP Composites under Different Strain Rates: A Review
by Ali Farokhi Nejad, Mohamad Yusuf Bin Salim, Seyed Saeid Rahimian Koloor, Stanislav Petrik, Mohd Yazid Yahya, Shukur Abu Hassan and Mohd Kamal Mohd Shah
Polymers 2021, 13(19), 3400; https://doi.org/10.3390/polym13193400 - 02 Oct 2021
Cited by 12 | Viewed by 3286
Abstract
As a high-demand material, polymer matrix composites are being used in many advanced industrial applications. Due to ecological issues in the past decade, some attention has been paid to the use of natural fibers. However, using only natural fibers is not desirable for [...] Read more.
As a high-demand material, polymer matrix composites are being used in many advanced industrial applications. Due to ecological issues in the past decade, some attention has been paid to the use of natural fibers. However, using only natural fibers is not desirable for advanced applications. Therefore, hybridization of natural and synthetic fibers appears to be a good solution for the next generation of polymeric composite structures. Composite structures are normally made for various harsh operational conditions, and studies on loading rate and strain-dependency are essential in the design stage of the structures. This review aimed to highlight the different materials’ content of hybrid composites in the literature, while addressing the different methods of material characterization for various ranges of strain rates. In addition, this work covers the testing methods, possible failure, and damage mechanisms of hybrid and synthetic FRP composites. Some studies about different numerical models and analytical methods that are applicable for composite structures under different strain rates are described. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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24 pages, 4230 KiB  
Review
Delamination and Manufacturing Defects in Natural Fiber-Reinforced Hybrid Composite: A Review
by M. J. Suriani, Hannah Zalifah Rapi, R. A. Ilyas, Michal Petrů and S. M. Sapuan
Polymers 2021, 13(8), 1323; https://doi.org/10.3390/polym13081323 - 18 Apr 2021
Cited by 68 | Viewed by 9357
Abstract
In recent years, most boat fabrication companies use 100% synthetic fiber-reinforced composite materials, due to their high performance of mechanical properties. In the new trend of research on the fabrication of boat structure using natural fiber hybrid with kevlar/fiberglass-reinforced composite, the result of [...] Read more.
In recent years, most boat fabrication companies use 100% synthetic fiber-reinforced composite materials, due to their high performance of mechanical properties. In the new trend of research on the fabrication of boat structure using natural fiber hybrid with kevlar/fiberglass-reinforced composite, the result of tensile, bending, and impact strength showed that glass fiber-reinforced polyester composite gave high strength with increasing glass fiber contents. At some point, realizing the cost of synthetic fiber is getting higher, researchers today have started to use natural fibers that are seen as a more cost-effective option. Natural fibers, however, have some disadvantages, such as high moisture absorption, due to repelling nature; low wettability; low thermal stability; and quality variation, which lead to the degradation of composite properties. In recent times, hybridization is recommended by most researchers as a solution to natural fiber’s weaknesses and to reduce the use of synthetic fibers that are not environmentally friendly. In addition, hybrid composite has its own special advantages, i.e., balanced strength and stiffness, reduced weight and cost, improved fatigue resistance and fracture toughness, and improved impact resistance. The synthetic–nature fiber hybrid composites are used in a variety of applications as a modern material that has attracted most manufacturing industries’ attention to shift to using the hybrid composite. Some of the previous studies stated that delamination and manufacturing had influenced the performance of the hybrid composites. In order to expand the use of natural fiber as a successful reinforcement in hybrid composite, the factor that affects the manufacturing defects needs to be investigated. In this review paper, a compilation of the reviews on the delamination and a few common manufacturing defect types illustrating the overview of the impact on the mechanical properties encountered by most of the composite manufacturing industries are presented. Full article
(This article belongs to the Special Issue Mechanics of Polymer and Polymer Composite Materials and Structures)
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