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16 pages, 3321 KiB

Open AccessArticle

Porous Coordination Polymer MOF-808 as an Effective Catalyst to Enhance Sustainable Chemical Processes

by Catarina E. S. Ferreira, Isabel Santos-Vieira, Carlos R. Gomes, Salete S. Balula and Luís Cunha-Silva

Polymers 2024, 16(7), 968; https://doi.org/10.3390/polym16070968 - 02 Apr 2024

Viewed by 602

Abstract

The improvement of sustainable chemical processes plays a pivotal role in safe environmental and societal development, for example, by reducing the use of hazardous substances, preventing chemical waste, and improving the efficiency of chemical reactions to obtain added-value compounds. In this context, the [...] Read more.

The improvement of sustainable chemical processes plays a pivotal role in safe environmental and societal development, for example, by reducing the use of hazardous substances, preventing chemical waste, and improving the efficiency of chemical reactions to obtain added-value compounds. In this context, the porous coordination polymer MOF-808 (MOF, metal–organic framework) was prepared by a straightforward method in water, at room temperature, and was unequivocally characterized by powder X-ray diffraction, vibrational spectroscopy, thermogravimetric analysis, and scanning electron microscopy. MOF-808 material was applied for the first time as catalysts in ring-opening aminolysis reactions of epoxides. It demonstrated high activity and selectivity for reactions of styrene oxide and cyclohexene oxide with aniline, using a very low amount of an eco-sustainable solvent (0.5 mL of EtOH), at 70 °C. Moreover, MOF-808 demonstrated high stability in the catalytic reaction conditions applied, and a notable reuse capacity of up to 20 consecutive reaction cycles, without significant variation in its catalytic performance. In fact, this Zr-based porous coordination polymer prepared by environment-friendly conditions proved to be a novel efficient heterogeneous catalyst, promoting the ring-opening reaction of epoxides under more sustainable conditions, and using a very low amount of catalyst. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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17 pages, 5887 KiB

Open AccessArticle

Strategies for Improving Sustainability in the Development of High-Performance Styrenic Block Copolymers by Developing Blends with Cellulose Derivatives

by Erika Pajares, Josu Fernández Maestu, Irati Fernandez-de-Mendiola, Unai Silvan, Pedro Costa, Iker Agirrezabal-Telleria, Carmen R. Tubio, Sergio Corona-Galván and Senentxu Lanceros-Mendez

Polymers 2024, 16(6), 856; https://doi.org/10.3390/polym16060856 - 21 Mar 2024

Viewed by 781

Abstract

Next-generation high-performance polymers require consideration as sustainable solutions. Here, to satisfy these criteria, we propose to combine high-performance styrenic block copolymers, a class of thermoplastic elastomer, with cellulose derivatives as a reinforcing agent with the aim of maintaining and/or improving structural and surface [...] Read more.

Next-generation high-performance polymers require consideration as sustainable solutions. Here, to satisfy these criteria, we propose to combine high-performance styrenic block copolymers, a class of thermoplastic elastomer, with cellulose derivatives as a reinforcing agent with the aim of maintaining and/or improving structural and surface properties. A great advantage of the proposed blends is, besides their biocompatibility, a decrease in environmental impact due to blending with a natural polymer. Particularly, we focus on identifying the effect of different blending compounds and blend ratios on the morphological, structural, thermal, mechanical, electrical and cytotoxic characteristics of materials. This research provides, together with novel material formulations, practical guidelines for the design and fabrication of next-generation sustainable high-performance polymers. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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16 pages, 3223 KiB

Open AccessArticle

Reactive Deep Eutectic Solvent for an Eco-Friendly Synthesis of Cellulose Carbamate

by Vincenzo Algieri, Loredana Maiuolo, Debora Procopio, Paola Costanzo, Fiore Pasquale Nicoletta, Sonia Trombino, Maria Luisa Di Gioia and Antonio De Nino

Polymers 2024, 16(6), 757; https://doi.org/10.3390/polym16060757 - 09 Mar 2024

Viewed by 849

Abstract

The limited solubility of natural cellulose in water and common organic solvents hinders its diverse applications, despite being one of the most abundant and easily accessible biopolymers on Earth. Chemical derivatization, such as cellulose carbamate (CC), offers a pathway to enhance both solubility [...] Read more.

The limited solubility of natural cellulose in water and common organic solvents hinders its diverse applications, despite being one of the most abundant and easily accessible biopolymers on Earth. Chemical derivatization, such as cellulose carbamate (CC), offers a pathway to enhance both solubility and industrial processability. In this study, CC was synthesized by exploiting a novel type IV deep eutectic solvent (DES) composed of erbium trichloride and urea. This DES was shown to be not only an environmentally friendly reaction medium/catalyst but also actively participated in the synthetic process as a reagent. The resultant cellulose carbamate samples were characterized through FT-IR and elemental analysis. A nitrogen content value of 1.59% was afforded determining a degree of substitution corresponding to a value of 0.19. One of the key scientific advancements lies in the preparation of cellulose carbamate using a straightforward and cost-effective method. This approach utilizes non-toxic compounds, aligning with the principles of green chemistry and contributing to sustainable development in cellulose derivative production. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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20 pages, 2295 KiB

Open AccessArticle

Stabilization of Black Locust Flower Extract via Encapsulation Using Alginate and Alginate–Chitosan Microparticles

by Ivana A. Boškov, Ivan M. Savić, Nađa Đ. Grozdanić Stanisavljević, Tatjana D. Kundaković-Vasović, Jelena S. Radović Selgrad and Ivana M. Savić Gajić

Polymers 2024, 16(5), 688; https://doi.org/10.3390/polym16050688 - 02 Mar 2024

Viewed by 950

Abstract

Black locust flower extract contains various polyphenols and their glucosides contribute to the potential health benefits. After intake of these bioactive compounds and passage through the gastrointestinal tract, their degradation can occur and lead to a loss of biological activity. To overcome this [...] Read more.

Black locust flower extract contains various polyphenols and their glucosides contribute to the potential health benefits. After intake of these bioactive compounds and passage through the gastrointestinal tract, their degradation can occur and lead to a loss of biological activity. To overcome this problem, the bioactive compounds should be protected from environmental conditions. This study aimed to encapsulate the black flower extract in the microparticles based on biodegradable polysaccharides, alginate, and chitosan. In the extract, the total antioxidant content was found to be 3.18 ± 0.01 g gallic acid equivalent per 100 g of dry weight. Also, the presence of lipids (16), phenolics (27), organic acids (4), L-aspartic acid derivative, questinol, gibberellic acid, sterol, and saponins (2) was confirmed using the UHPLC–ESI–MS analysis. In vitro assays showed that the extract has weak anti-α-glucosidase activity and moderate antioxidant and cytotoxic activity against the HeLa cell line. The extrusion method with secondary air flow enabled the preparation of microparticles (about 270 μm) encapsulated with extract. An encapsulation efficiency of over 92% was achieved in the alginate and alginate–chitosan microparticles. The swelling study confirmed a lower permeability of alginate–chitosan microparticles compared with alginate microparticles. For both types of microparticles, the release profile of antioxidants in the simulated gastrointestinal fluids at 37 °C followed the Korsmeyer–Peppas model. A lower diffusion coefficient than 0.5 indicated the simple Fick diffusion of antioxidants. The alginate–chitosan microparticles enabled a more sustained release of antioxidants from extract compared to the alginate microparticles. The obtained results indicated an improvement in the antioxidant activity of bioactive compounds from the extract and their protection from degradation in the simulated gastric conditions via encapsulation in the polymer matrixes. Alginate–chitosan showed slightly slower cumulative antioxidant release from microparticles and better antioxidant activity of the extract compared to the alginate system. According to these results, alginate–chitosan microparticles are more suitable for further application in the encapsulation of black locust flower extract. Also, the proposed polymer matrix as a drug delivery system is safe for human use due to its biodegradability and non-toxicity. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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18 pages, 2373 KiB

Open AccessArticle

Crosslinked Polyesters as Fully Biobased Coatings with Cutin Monomer from Tomato Peel Wastes

by Eleonora Ruffini, Andrea Bianchi Oltolini, Mirko Magni, Giangiacomo Beretta, Marco Cavallaro, Raffaella Suriano and Stefano Turri

Polymers 2024, 16(5), 682; https://doi.org/10.3390/polym16050682 - 02 Mar 2024

Viewed by 769

Abstract

Cutin, one of the main structural components of tomato peels, is a waxy biopolymer rich in hydroxylated fatty acids. In this study, 10,16-dihydroxyhexadecanoic acid (10,16-diHHDA) was extracted and isolated from tomato peels and exploited to develop fully crosslinked polyesters as potential candidates for [...] Read more.

Cutin, one of the main structural components of tomato peels, is a waxy biopolymer rich in hydroxylated fatty acids. In this study, 10,16-dihydroxyhexadecanoic acid (10,16-diHHDA) was extracted and isolated from tomato peels and exploited to develop fully crosslinked polyesters as potential candidates for replacing fossil-based metal protective coatings. A preliminary screening was conducted to select the base formulation, and then a design of experiments (DoE) was used as a methodology to identify the optimal composition to develop a suitable coating material. Different formulations containing 10,16-diHHDA and other biorefinery monomers, including 2,5-furandicarboxylic acid, were considered. To this end, all polyesters were characterized through differential scanning calorimetry (DSC) and gel content measurements to determine their T_g value and crosslinking efficiency. Compositions exhibiting the best trade-off between T_g value, chemical resistance, and sufficiently high 10,16-diHHDA content between 39 and 48 wt.% were used to prepare model coatings that were characterized for assessing their wettability, scratch hardness, chemical resistance, and adhesion to metal substrates. These polyester coatings showed a T_g in the range of 45–55 °C, a hydrophobic behavior with a water contact angle of around 100°, a good solvent resistance (>100 MEK double rubs), and an adhesion strength to steel higher than 2 MPa. The results obtained confirmed the potential of cutin-based resins as coatings for metal protection, meeting the requirements for ensuring physicochemical properties of the final product, as well as for optimizing the valorization of such an abundant agri-food waste as tomato peels. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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18 pages, 4312 KiB

Open AccessArticle

Stability in Aqueous Solution of a New Spray-Dried Hydrocolloid of High Andean Algae Nostoc sphaericum

by David Choque-Quispe, Carlos A. Ligarda-Samanez, Yudith Choque-Quispe, Sandro Froehner, Aydeé M. Solano-Reynoso, Elibet Moscoso-Moscoso, Yakov Felipe Carhuarupay-Molleda and Ronald Peréz-Salcedo

Polymers 2024, 16(4), 537; https://doi.org/10.3390/polym16040537 - 16 Feb 2024

Viewed by 665

Abstract

There is a growing emphasis on seeking stabilizing agents with minimal transformation, prioritizing environmentally friendly alternatives, and actively contributing to the principles of the circular economy. This research aimed to assess the stability of a novel spray-dried hydrocolloid from high Andean algae when [...] Read more.

There is a growing emphasis on seeking stabilizing agents with minimal transformation, prioritizing environmentally friendly alternatives, and actively contributing to the principles of the circular economy. This research aimed to assess the stability of a novel spray-dried hydrocolloid from high Andean algae when introduced into an aqueous solution. Nostoc sphaericum freshwater algae were subject to atomization, resulting in the production of spray-dried hydrocolloid (SDH). Subsequently, suspension solutions of SDH were meticulously prepared at varying pH levels and gelling temperatures. These solutions were then stored for 20 days to facilitate a comprehensive evaluation of their stability in suspension. The assessment involved a multifaceted approach, encompassing rheological analysis, scrutiny of turbidity, sedimentation assessment, ζ-potential, and measurement of particle size. The findings from these observations revealed that SDH exhibits a dilatant behavior when in solution, signifying an increase in with higher shear rate. Furthermore, it demonstrates commendable stability when stored under ambient conditions. SDH is emerging as a potential alternative stabilizer for use in aqueous solutions due to its easy extraction and application. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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16 pages, 7436 KiB

Open AccessArticle

Cholesteric Liquid Crystals with Thermally Stable Reflection Color from Mixtures of Completely Etherified Ethyl Cellulose Derivative and Methacrylic Acid

by Kazuma Matsumoto, Naoto Iwata and Seiichi Furumi

Polymers 2024, 16(3), 401; https://doi.org/10.3390/polym16030401 - 31 Jan 2024

Viewed by 689

Abstract

Cellulose derivatives have attracted attention as environmentally friendly materials that can exhibit a cholesteric liquid crystal (CLC) phase with visible light reflection. Previous reports have shown that the chemical structures and the degrees of substitution of cellulose derivatives have significant influence on their [...] Read more.

Cellulose derivatives have attracted attention as environmentally friendly materials that can exhibit a cholesteric liquid crystal (CLC) phase with visible light reflection. Previous reports have shown that the chemical structures and the degrees of substitution of cellulose derivatives have significant influence on their reflection properties. Although many studies have been reported on CLC using ethyl cellulose (EC) derivatives in which the hydroxy groups are esterified, there have been no studies on EC derivatives with etherified side chains. In this article, we optimized the Williamson ether synthesis to introduce pentyl ether groups in the EC side chain. The degree of substitution with pentyl ether group (DS_Pe), confirmed via ¹H-NMR spectroscopic measurements, was controlled using the solvent and the base concentration in this synthesis. All the etherified EC derivatives were soluble in methacrylic acid (MAA), allowing for the preparation of lyotropic CLCs with visible reflection. Although the reflection peak of lyotropic CLCs generally varies with temperature, the reflection peak of lyotropic CLCs of completely etherified EC derivatives with MAA could almost be preserved in the temperature range from 30 to 110 °C even without the aid of any crosslinking. Such thermal stability of the reflection peak of CLCs may be greatly advantageous for fabricating new photonic devices with eco-friendliness. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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13 pages, 25968 KiB

Open AccessArticle

Fluid Mechanics of Droplet Spreading of Chitosan/PVA-Based Spray Coating Solution on Banana Peels with Different Wettability

by Endarto Yudo Wardhono, Nufus Kanani, Mekro Permana Pinem, Dwinanto Sukamto, Yenny Meliana, Khashayar Saleh and Erwann Guénin

Polymers 2023, 15(21), 4277; https://doi.org/10.3390/polym15214277 - 31 Oct 2023

Viewed by 903

Abstract

The spreading behavior of a coating solution is an important factor in determining the effectiveness of spraying applications. It determines how evenly the droplets spread on the substrate surface and how quickly they form a uniform film. Fluid mechanics principles govern it, including [...] Read more.

The spreading behavior of a coating solution is an important factor in determining the effectiveness of spraying applications. It determines how evenly the droplets spread on the substrate surface and how quickly they form a uniform film. Fluid mechanics principles govern it, including surface tension, viscosity, and the interaction between the liquid and the solid surface. In our previous work, chitosan (CS) film properties were successfully modified by blending with polyvinyl alcohol (PVA). It was shown that the mechanical strength of the composite film was significantly improved compared to the virgin CS. Here we propose to study the spreading behavior of CS/PVA solution on fresh bananas. The events upon droplet impact were captured using a high-speed camera, allowing the identification of outcomes as a function of velocity at different surface wettabilities (wetting and non-wetting) on the banana peels. The mathematical model to predict the maximum spreading factor, β_max, was governed by scaling law analysis using fitting experimental data to identify patterns, trends, and relationships between β_max and the independent variables, Weber (We) numbers, and Reynolds (Re) numbers. The results indicate that liquid viscosity and surface properties affect the droplet’s impact and spreading behavior. The Ohnesorge (Oh) numbers significantly influenced the spreading dynamics, while the banana’s surface wettability minimally influenced spreading. The prediction model reasonably agrees with all the data in the literature since the R² = 0.958 is a powerful goodness-of-fit indicator for predicting the spreading factor. It scaled with

β_{m a x} = a + 0.04 {(W e . R e)}^{1 / 3}

, where the “a” constants depend on Oh numbers. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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19 pages, 13708 KiB

Open AccessArticle

Native Potato Starch and Tara Gum as Polymeric Matrices to Obtain Iron-Loaded Microcapsules from Ovine and Bovine Erythrocytes

by Carlos A. Ligarda-Samanez, Elibet Moscoso-Moscoso, David Choque-Quispe, Betsy S. Ramos-Pacheco, José C. Arévalo-Quijano, Germán De la Cruz, Mary L. Huamán-Carrión, Uriel R. Quispe-Quezada, Edgar Gutiérrez-Gómez, Domingo J. Cabel-Moscoso, Mauricio Muñoz-Melgarejo and Wilber César Calsina Ponce

Polymers 2023, 15(19), 3985; https://doi.org/10.3390/polym15193985 - 04 Oct 2023

Cited by 3 | Viewed by 1388

Abstract

Iron deficiency leads to ferropenic anemia in humans. This study aimed to encapsulate iron-rich ovine and bovine erythrocytes using tara gum and native potato starch as matrices. Solutions containing 20% erythrocytes and different proportions of encapsulants (5, 10, and 20%) were used, followed [...] Read more.

Iron deficiency leads to ferropenic anemia in humans. This study aimed to encapsulate iron-rich ovine and bovine erythrocytes using tara gum and native potato starch as matrices. Solutions containing 20% erythrocytes and different proportions of encapsulants (5, 10, and 20%) were used, followed by spray drying at 120 and 140 °C. Iron content in erythrocytes ranged between 2.24 and 2.52 mg of Fe/g; microcapsules ranged from 1.54 to 2.02 mg of Fe/g. Yields varied from 50.55 to 63.40%, and temperature and encapsulant proportion affected moisture and water activity. Various red hues, sizes, and shapes were observed in the microcapsules. SEM-EDS analysis revealed the surface presence of iron in microcapsules with openings on their exterior, along with a negative zeta potential. Thermal and infrared analyses confirmed core encapsulation within the matrices. Iron release varied between 92.30 and 93.13% at 120 min. Finally, the most effective treatments were those with higher encapsulant percentages and dried at elevated temperatures, which could enable their utilization in functional food fortification to combat anemia in developing countries. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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24 pages, 15248 KiB

Open AccessArticle

Preservation of Fresh-Cut ‘Maradol’ Papaya with Polymeric Nanocapsules of Lemon Essential Oil or Curcumin

by Moises Job Galindo-Pérez, Lizbeth Martínez-Acevedo, Gustavo Vidal-Romero, Luis Eduardo Serrano-Mora and María de la Luz Zambrano-Zaragoza

Polymers 2023, 15(17), 3515; https://doi.org/10.3390/polym15173515 - 23 Aug 2023

Cited by 2 | Viewed by 993

Abstract

Papaya is one of the most consumed fruits in the world; however, tissue damage caused by cuts quickly leads to its decay. Therefore, this study aimed to prepare and characterize lemon oil and curcumin nanocapsules to evaluate their capacity for preserving fresh-cut papaya. [...] Read more.

Papaya is one of the most consumed fruits in the world; however, tissue damage caused by cuts quickly leads to its decay. Therefore, this study aimed to prepare and characterize lemon oil and curcumin nanocapsules to evaluate their capacity for preserving fresh-cut papaya. Lemon essential oil and curcumin nanocapsules were prepared using ethyl cellulose (EC) and poly-(ε-caprolactone) (PCL) by the emulsification–diffusion method coupled with ultrasound. The particles had sizes smaller than 120 nm, with polydispersity indices below 0.25 and zeta potentials exceeding −12 mV, as confirmed by scanning electron microscopy. The nanoparticles remained stable for 27 days, with sedimentation being the instability mechanism observed. These nanoparticles were employed to coat fresh-cut papaya, which was stored for 17 days. The results demonstrated their remarkable efficacy in reducing the respiration rate. Furthermore, nanocapsules maintained the pH and acidity levels of the papayas for an extended period. The lemon oil/EC nanocapsule treatment retained the color better. Additionally, all systems exhibited the ability to minimize texture loss associated with reduced pectin methylesterase activity. Finally, the nanocapsules showed a notable reduction in polyphenol oxidase activity correlating with preserving total phenolic compounds in the fruit. Therefore, the lemon oil and curcumin nanoparticles formed using EC and PCL demonstrated their effectiveness in preserving fresh-cut ‘Maradol’ papaya. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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16 pages, 3323 KiB

Open AccessArticle

FDM 3D Printing and Soil-Burial-Degradation Behaviors of Residue of Astragalus Particles/Thermoplastic Starch/Poly(lactic acid) Biocomposites

by Zhibing Ni, Jianan Shi, Mengya Li, Wen Lei and Wangwang Yu

Polymers 2023, 15(10), 2382; https://doi.org/10.3390/polym15102382 - 19 May 2023

Cited by 4 | Viewed by 1319

Abstract

Astragalus residue powder (ARP)/thermoplastic starch (TPS)/poly(lactic acid) (PLA) biocomposites were prepared by fused-deposition modeling (FDM) 3D-printing technology for the first time in this paper, and certain physico-mechanical properties and soil-burial-biodegradation behaviors of the biocomposites were investigated. The results showed that after raising the [...] Read more.

Astragalus residue powder (ARP)/thermoplastic starch (TPS)/poly(lactic acid) (PLA) biocomposites were prepared by fused-deposition modeling (FDM) 3D-printing technology for the first time in this paper, and certain physico-mechanical properties and soil-burial-biodegradation behaviors of the biocomposites were investigated. The results showed that after raising the dosage of ARP, the tensile and flexural strengths, the elongation at break and the thermal stability of the sample decreased, while the tensile and flexural moduli increased; after raising the dosage of TPS, the tensile and flexural strengths, the elongation at break and the thermal stability all decreased. Among all of the samples, sample C—which was composed of 11 wt.% ARP, 10 wt.% TPS and 79 wt.% PLA—was the cheapest and also the most easily degraded in water. The soil-degradation-behavior analysis of sample C showed that, after being buried in soil, the surfaces of the samples became grey at first, then darkened, after which the smooth surfaces became rough and certain components were found to detach from the samples. After soil burial for 180 days, there was weight loss of 21.40%, and the flexural strength and modulus, as well as the storage modulus, reduced from 82.1 MPa, 11,922.16 MPa and 2395.3 MPa to 47.6 MPa, 6653.92 MPa and 1476.5 MPa, respectively. Soil burial had little effect on the glass transition, cold crystallization or melting temperatures, while it reduced the crystallinity of the samples. It is concluded that the FDM 3D-printed ARP/TPS/PLA biocomposites are easy to degrade in soil conditions. This study developed a new kind of thoroughly degradable biocomposite for FDM 3D printing. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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13 pages, 5218 KiB

Open AccessArticle

Furan as Impurity in Green Ethylene and Its Effects on the Productivity of Random Ethylene–Propylene Copolymer Synthesis and Its Thermal and Mechanical Properties

by Joaquín Hernández-Fernández, Esneyder Puello-Polo and Edgar Márquez

Polymers 2023, 15(10), 2264; https://doi.org/10.3390/polym15102264 - 11 May 2023

Cited by 4 | Viewed by 1380

Abstract

The presence of impurities such as H₂S, thiols, ketones, and permanent gases in propylene of fossil origin and their use in the polypropylene production process affect the efficiency of the synthesis and the mechanical properties of the polymer and generate millions [...] Read more.

The presence of impurities such as H₂S, thiols, ketones, and permanent gases in propylene of fossil origin and their use in the polypropylene production process affect the efficiency of the synthesis and the mechanical properties of the polymer and generate millions of losses worldwide. This creates an urgent need to know the families of inhibitors and their concentration levels. This article uses ethylene green to synthesize an ethylene–propylene copolymer. It describes the impact of trace impurities of furan in ethylene green and how this furan influences the loss of properties such as thermal and mechanical properties of the random copolymer. For the development of the investigation, 12 runs were carried out, each in triplicate. The results show an evident influence of furan on the productivity of the Ziegler–Natta catalyst (ZN); productivity losses of 10, 20, and 41% were obtained for the copolymers synthesized with ethylene rich in 6, 12, and 25 ppm of furan, respectively. PP0 (without furan) did not present losses. Likewise, as the concentration of furan increased, it was observed that the melt flow index (MFI), thermal (TGA), and mechanical properties (tensile, bending, and impact) decreased significantly. Therefore, it can be affirmed that furan should be a substance to be controlled in the purification processes of green ethylene. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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18 pages, 22462 KiB

Open AccessArticle

The Contribution of BaTiO₃ to the Stability Improvement of Ethylene–Propylene–Diene Rubber: Part I—Pristine Filler

by Tunde Borbath, Nicoleta Nicula, Traian Zaharescu, Istvan Borbath and Tiberiu Francisc Boros

Polymers 2023, 15(9), 2190; https://doi.org/10.3390/polym15092190 - 05 May 2023

Cited by 3 | Viewed by 1459

Abstract

This study presents the functional effects of BaTiO₃ powder loaded in ethylene–propylene–diene rubber (EPDM) in three concentrations: 0, 1, and 2.5 phr. The characterization of mechanical properties, oxidation strength, and biological vulnerability is achieved on these materials subjected to an accelerated degradation [...] Read more.

This study presents the functional effects of BaTiO₃ powder loaded in ethylene–propylene–diene rubber (EPDM) in three concentrations: 0, 1, and 2.5 phr. The characterization of mechanical properties, oxidation strength, and biological vulnerability is achieved on these materials subjected to an accelerated degradation stimulated by their γ-irradiation at 50 and 100 kGy. The thermal performances of these materials are improved when the content of filler becomes higher. The results obtained by chemiluminescence, FTIR-ATR, and mechanical testing indicate that the loading of 2.5 phr is the most proper composition that resists for a long time after it is γ-irradiated at a high dose. If the oxidation starts at 176 °C in the pristine polymer, it becomes significant at 188 and 210 °C in the case of composites containing 1 and 2.5 phr of filler, respectively. The radiation treatment induces a significant stability improvement measured by the enlargement of temperature range by more than 1.5 times, which explains the durability growth for the radiation-processed studied composites. The extension of the stability period is also based on the interaction between degrading polymer substrate and particle surface in the composite richest in titanate fraction when the exposure is 100 kGy was analyzed. The mechanical testing as well as the FTIR investigation clearly delimits the positive effects of carbon black on the functionality of EPDM/BaTiO₃ composites. The contribution of carbon black is a defining feature of the studied composites based on the nucleation of the host matrix by which the polymer properties are effectively ameliorated. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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17 pages, 4496 KiB

Open AccessArticle

Reinforcement Behavior of Chemically Unmodified Cellulose Nanofiber in Natural Rubber Nanocomposites

by Bunsita Wongvasana, Bencha Thongnuanchan, Abdulhakim Masa, Hiromu Saito, Tadamoto Sakai and Natinee Lopattananon

Polymers 2023, 15(5), 1274; https://doi.org/10.3390/polym15051274 - 02 Mar 2023

Cited by 9 | Viewed by 1955

Abstract

We investigated the reinforcement behavior of small amounts of chemically unmodified cellulose nanofiber (CNF) in eco-friendly natural rubber (NR) nanocomposites. For this purpose, NR nanocomposites filled with 1, 3, and 5 parts per hundred rubber (phr) of cellulose nanofiber (CNF) were prepared by [...] Read more.

We investigated the reinforcement behavior of small amounts of chemically unmodified cellulose nanofiber (CNF) in eco-friendly natural rubber (NR) nanocomposites. For this purpose, NR nanocomposites filled with 1, 3, and 5 parts per hundred rubber (phr) of cellulose nanofiber (CNF) were prepared by a latex mixing method. By using TEM, a tensile test, DMA, WAXD, a bound rubber test, and gel content measurements, the effect of CNF concentration on the structure–property relationship and reinforcing mechanism of the CNF/NR nanocomposite was revealed. Increasing the content of CNF resulted in decreased dispersibility of the nanofiber in the NR matrix. It was found that the stress upturn in the stress–strain curves was remarkably enhanced when the NR was combined with 1–3 phr CNF, and a noticeable increase in tensile strength (an approximately 122% increase in tensile strength over that of NR) was observed without sacrificing the flexibility of the NR in the NR filled with 1 phr CNF, though no acceleration in their strain-induced crystallization was observed. Since the NR chains were not inserted in the uniformly dispersed CNF bundles, the reinforcement behavior by the small content of CNF might be attributed to the shear stress transfer at the CNF/NR interface through the interfacial interaction (i.e., physical entanglement) between the nano-dispersed CNFs and the NR chains. However, at a higher CNF filling content (5 phr), the CNFs formed micron-sized aggregates in the NR matrix, which significantly induced the local stress concentration and promoted strain-induced crystallization, causing a substantially increased modulus but reduced the strain at the rupture of the NR. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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Review

Jump to: Research

34 pages, 10404 KiB

Open AccessReview

The Potential of Electrospun Membranes in the Treatment of Textile Wastewater: A Review

by Joana M. Rocha, Rui P. C. L. Sousa, Raul Fangueiro and Diana P. Ferreira

Polymers 2024, 16(6), 801; https://doi.org/10.3390/polym16060801 - 13 Mar 2024

Viewed by 797

Abstract

Water security and industrial wastewater treatment are significant global concerns. One of the main issues with environmental contamination has been the discharge of dye wastewater from the textile and dye industries, contributing to an ever-growing problem with water pollution, poisoning water supplies, and [...] Read more.

Water security and industrial wastewater treatment are significant global concerns. One of the main issues with environmental contamination has been the discharge of dye wastewater from the textile and dye industries, contributing to an ever-growing problem with water pollution, poisoning water supplies, and harming the ecosystem. The traditional approach to wastewater treatment has been found to be inefficient, and biosorption techniques and mechanisms have been proven to be a successful replacement for conventional methods. Recent developments have led to the recognition of fibrous materials as an environmentally friendly option with broad application in several industries, including wastewater treatment. This review explores the potential of fibrous materials produced by the electrospinning technique as adsorbents for wastewater treatment, while at the same time, for the removal of adsorbates such as oil, dyes, heavy metals, and other substances, as reported in the literature. Textile wastewater filtering structures, produced by electrospinning, are summarized and the use of synthetic and natural polymers for this purpose is discussed. The limitations of electrospun textile wastewater filtering structures are also mentioned. Electrospun nanofibrous membranes appear to be a very promising route to filter textile wastewater and therefore contribute to water reuse and to reducing the contamination of water courses. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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19 pages, 3959 KiB

Open AccessReview

Recent Advances in Lignocellulose-Based Monomers and Their Polymerization

by Fuyun Pei, Lijuan Liu, Huie Zhu and Haixin Guo

Polymers 2023, 15(4), 829; https://doi.org/10.3390/polym15040829 - 07 Feb 2023

Cited by 5 | Viewed by 2944

Abstract

Replacing fossil-based polymers with renewable bio-based polymers is one of the most promising ways to solve the environmental issues and climate change we human beings are facing. The production of new lignocellulose-based polymers involves five steps, including (1) fractionation of lignocellulose into cellulose, [...] Read more.

Replacing fossil-based polymers with renewable bio-based polymers is one of the most promising ways to solve the environmental issues and climate change we human beings are facing. The production of new lignocellulose-based polymers involves five steps, including (1) fractionation of lignocellulose into cellulose, hemicellulose, and lignin; (2) depolymerization of the fractionated cellulose, hemicellulose, and lignin into carbohydrates and aromatic compounds; (3) catalytic or thermal conversion of the depolymerized carbohydrates and aromatic compounds to platform chemicals; (4) further conversion of the platform chemicals to the desired bio-based monomers; (5) polymerization of the above monomers to bio-based polymers by suitable polymerization methods. This review article will focus on the progress of bio-based monomers derived from lignocellulose, in particular the preparation of bio-based monomers from 5-hydroxymethylfurfural (5-HMF) and vanillin, and their polymerization methods. The latest research progress and application scenarios of related bio-based polymeric materials will be also discussed, as well as future trends in bio-based polymers. Full article

(This article belongs to the Special Issue Advances in Sustainable Polymeric Materials II)

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