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Atomic Electrocatalyst of Efficient Energy System

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "D2: Electrochem: Batteries, Fuel Cells, Capacitors".

Deadline for manuscript submissions: closed (31 May 2023) | Viewed by 3632

Special Issue Editor


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Guest Editor
School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China
Interests: energy catalysis (water electrolysis for hydrogen production, carbon dioxide fixation, ammonia synthesis, etc.); development of new energy devices (zinc metal batteries, lithium sulfur batteries, fuel cells, etc.)

Special Issue Information

Dear Colleagues,

Atomic electrocatalysts (AECs), which include single/dual-atoms and nanoclusters with the exposed active sites at atomic level, have emerged as emerging frontier in the field of heterogeneous catalysis and materials research account for its optimized selectivity and catalytic activity attributed to homogeneous catalytic site with definite low atomic coordination number. AECs have different structural characteristics from those of nanoparticles and bulk materials, enable efficient electrochemical conversion in energy system, e.g., prominent photo- and/or electro-reactions (hydrogen evolution, oxygen evolution, hydrogen oxidation, oxygen reduction, nitrogen reduction, and carbon dioxide reduction, etc.) and sustainable energy devices (water splitting systems, fuel cells, and metal air/carbon dioxide batteries, etc.). Although remarkable development has been made in the rational design and preparation, as well as potential application of AECs in recent years, there are still some key elusiveness needs to insight:

  • The anchoring mechanisms and regulation at atomic-level precision for different types of supported AECs;
  • The determination of real active sites in dynamic structure evolution between the catalytic centers and reactive intermediates;
  • The low-cost industrialization method to improve the production and develop multi-functionality of AECs;
  • The practical application of AECs to expand sustainable energy technologies.

Therefore, the joint efforts of researchers from all over the world are needed to address the above existing challenges. In this Special Issue of Energies on “Atomic Electrocatalyst of Efficient Energy Systems”, we welcome your original papers to quickly share your research results in this field.

Prof. Dr. Xijun Liu
Guest Editor

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • atomic electrocatalysts
  • synthesis strategies
  • electrochemical reactions
  • structure-function relationship
  • sustainable energy devices

Published Papers (2 papers)

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Research

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10 pages, 3027 KiB  
Article
Coupling of NiFe Layered Double Hydroxides with Sulfides for Highly Efficient Urea Electrolysis and Hydrogen Evolution
by Wenxian Liu, Zhengguang Qin, Xiaojing Dai, Shibo Meng, Xinxin Niu, Wenhui Shi, Fangfang Wu and Xiehong Cao
Energies 2023, 16(3), 1092; https://doi.org/10.3390/en16031092 - 19 Jan 2023
Cited by 5 | Viewed by 1713
Abstract
Urea electrolysis is regarded as a prospective method for energy-saving hydrogen production. However, the practical application of this technology is limited by the lack of high-performance bifunctional catalysts for hydrogen evolution reaction (HER) and urea oxidation reaction (UOR). Herein, a heterostructure catalyst composed [...] Read more.
Urea electrolysis is regarded as a prospective method for energy-saving hydrogen production. However, the practical application of this technology is limited by the lack of high-performance bifunctional catalysts for hydrogen evolution reaction (HER) and urea oxidation reaction (UOR). Herein, a heterostructure catalyst composed of NiFe layered double hydroxide (LDH) and sulfides (NiFe LDH-NiFeSx/NF) catalysts is prepared via a simple one-step hydrothermal approach. Remarkably, the prepared NiFe LDH-NiFeSx/NF required 138 mV and 1.34 V to achieve 10 mA cm−2 for HER and UOR in 1 M KOH and 0.33 M urea, respectively. Furthermore, when NiFe LDH-NiFeSx/NF is used as a cathode for urea electrolysis, only 1.44 V is required at 10 mA cm−2, which is much lower than the 1.53 V needed for overall water splitting. Full article
(This article belongs to the Special Issue Atomic Electrocatalyst of Efficient Energy System)
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Review

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18 pages, 3006 KiB  
Review
A Mini Review: Recent Advances in Asymmetrically Coordinated Atom Sites for High-Efficiency Hydrogen Evolution Reaction
by Junyang Ding, Wenxian Liu, Shusheng Zhang, Jun Luo and Xijun Liu
Energies 2023, 16(6), 2664; https://doi.org/10.3390/en16062664 - 12 Mar 2023
Cited by 4 | Viewed by 1687
Abstract
Energy is the substance foundation of human society. Single−atom catalysts (SACs) have emerged as promising electrode materials in the energy field owing to their unique characteristics. It was demonstrated that the hydrogen evolution reaction (HER) performance of SACs relies on the metal−centric species [...] Read more.
Energy is the substance foundation of human society. Single−atom catalysts (SACs) have emerged as promising electrode materials in the energy field owing to their unique characteristics. It was demonstrated that the hydrogen evolution reaction (HER) performance of SACs relies on the metal−centric species and the corresponding local coordination engineering. Herein, the recent progress relating to asymmetric atomic catalysts for the HER is reviewed, including low coordination, heteroatomic coordination, and bimetallic coordination. In addition, the connection between the coordination structures and the presented electrocatalytic performance was discussed. The main challenges that need to be addressed for the asymmetric atomic catalysts in the HER are summarized. Finally, some insights into the development of high−quality asymmetric atomic catalysts are included. Full article
(This article belongs to the Special Issue Atomic Electrocatalyst of Efficient Energy System)
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