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15 pages, 5004 KiB

Open AccessArticle

Highly Sustainable Dyes Adsorption in Wastewater Using Textile Filters Fabricated by UV Irradiation

by Sujin Ryu, Young Ki Park, Jaeyun Shim, Seungju Lim and Minsuk Kim

Polymers 2024, 16(1), 15; https://doi.org/10.3390/polym16010015 - 19 Dec 2023

Cited by 2 | Viewed by 912

Abstract

Vast amounts of dyeing wastewater released from the textile industry can not only cause water pollution but also have negative effects on the human body, such as skin irritation and respiratory diseases. Dye adsorption technology is necessary for the treatment of wastewater discharged [...] Read more.

Vast amounts of dyeing wastewater released from the textile industry can not only cause water pollution but also have negative effects on the human body, such as skin irritation and respiratory diseases. Dye adsorption technology is necessary for the treatment of wastewater discharged from the dyeing industry and for environmental improvement. However, to remove dyeing wastewater, more energy and solvents are used to fabricate adsorbents, or excessive energy is used to filter dyeing wastewater out, resulting in more environmental pollution. Therefore, it is necessary to develop a method of filtering dyeing wastewater in a more environmentally friendly manner by minimizing the use of solvents and energy. In this study, we modified the surface of a textile substrate through UV irradiation to create a monomer capable of facilely bonding with dyes. Employing the UV photografting method, we were able to produce a dye adsorption filter in a more environmentally friendly manner, minimizing solvent usage and heat energy consumption required for absorbent synthesis. At a monomer concentration of 10%, the fabricated filter exhibited a dye removal efficiency of 97.34% after 24 h, all without the need for a pressure treatment or temperature increase. Moreover, it displayed an adsorption capacity of approximately 77.88 mg per 1 g of filter material. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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13 pages, 4726 KiB

Open AccessArticle

Non-Wettable Microporous Sheets Using Mixed Polyolefin Waste for Oil–Water Separation

by Junaid Saleem, Zubair Khalid Baig Moghal, Rana A. Shakoor, Adriaan S. Luyt and Gordon McKay

Polymers 2023, 15(14), 3072; https://doi.org/10.3390/polym15143072 - 17 Jul 2023

Cited by 2 | Viewed by 955

Abstract

Mixed polyolefin-based waste needs urgent attention to mitigate its negative impact on the environment. The separation of these plastics requires energy-intensive processes due to their similar densities. Additionally, these materials cannot be blended without compatibilizers, as they are inherently incompatible and immiscible. Herein, [...] Read more.

Mixed polyolefin-based waste needs urgent attention to mitigate its negative impact on the environment. The separation of these plastics requires energy-intensive processes due to their similar densities. Additionally, these materials cannot be blended without compatibilizers, as they are inherently incompatible and immiscible. Herein, non-wettable microporous sheets from recycled polyethylene (PE) and polypropylene (PP) are presented. The methodology involves the application of phase separation and spin-casting techniques to obtain a bimodal porous structure, facilitating efficient oil–water separation. The resulting sheets have an immediate and equilibrium sorption uptake of 100 and 55 g/g, respectively, due to the presence of micro- and macro-pores, as revealed by SEM. Moreover, sheets possess enhanced crystallinity, as evidenced by XRD; hence, they retain their structure during sorption and desorption and are reusable with 98% efficiency. The anti-wetting properties of the sheets are enhanced by applying a silane coating, ensuring waterless sorption and a contact angle of 140°. These results highlight the importance of implementing sustainable solutions to recycle plastics and mitigate the oil spill problem. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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17 pages, 5817 KiB

Open AccessArticle

Metal-Chelated Polymeric Nanomaterials for the Removal of Penicillin G Contamination

by Cansu İlke Kuru, Fulden Ulucan-Karnak and Sinan Akgol

Polymers 2023, 15(13), 2832; https://doi.org/10.3390/polym15132832 - 27 Jun 2023

Viewed by 1178

Abstract

We developed selective and relatively low-cost metal-chelated nanoparticle systems for the removal of the penicillin G (Pen G) antibiotic, presented for the first time in the literature. In the nanosystem, poly(glycidyl methacrylate) nanoparticles were synthesized by a surfactant-free emulsion polymerization method and covalently [...] Read more.

We developed selective and relatively low-cost metal-chelated nanoparticle systems for the removal of the penicillin G (Pen G) antibiotic, presented for the first time in the literature. In the nanosystem, poly(glycidyl methacrylate) nanoparticles were synthesized by a surfactant-free emulsion polymerization method and covalently bound with a tridentate-chelating ligand, iminodiacetic acid, based on the immobilized metal chelate affinity technique. It was modified with Cu²⁺, a chelating metal, to make Pen G specific. Metal-chelated nanoparticles were characterized by Fourier-transform infrared spectroscopy, energy dispersive spectrometry, zeta dimensional analysis, and scanning electron microscopy technology. Optimization studies of the Pen G removal were conducted. As a result of this study, Pen G removal with the p(GMA)-IDA-Cu²⁺ nanoparticle reached its maximum adsorption capacity of 633.92 mg/g in the short time of 15 min. The Pen G adsorption of p(GMA)-IDA-Cu²⁺ was three times more than that of the p(GMA) nanoparticles and two times more than that of the ampicillin adsorption. In addition, there was no significant decrease in the adsorption capacity of Pen G resulting from the repeated adsorption–desorption process of metal-chelated nanoparticles over five cycles. The metal-chelated nanoparticle had an 84.5% ability to regain its ability to regenerate the product with its regeneration capability, making the widespread use of the system very convenient in terms of reducing cost, an important factor in removal processes. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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15 pages, 4765 KiB

Open AccessArticle

Flower-like Thiourea–Formaldehyde Resin Microspheres for the Adsorption of Silver Ions

by Yuhan Li, Xiaoli Wang, Jing Xia, Guangwei Zhou, Xiaomu Wang, Dingxuan Wang, Junying Zhang, Jue Cheng and Feng Gao

Polymers 2023, 15(11), 2423; https://doi.org/10.3390/polym15112423 - 23 May 2023

Cited by 1 | Viewed by 1249

Abstract

Around a quarter of annual worldwide silver consumption comes from recycling. It remains a primary target for researchers to increase the silver ion adsorption capacity of the chelate resin. Herein, a series of flower-like thiourea–formaldehyde microspheres (FTFM) possessing diameters of 15–20 μm were [...] Read more.

Around a quarter of annual worldwide silver consumption comes from recycling. It remains a primary target for researchers to increase the silver ion adsorption capacity of the chelate resin. Herein, a series of flower-like thiourea–formaldehyde microspheres (FTFM) possessing diameters of 15–20 μm were prepared via a one-step reaction under acidic conditions, and the effects of the monomer molar ratio and reaction time on the micro-flower morphology, specific surface area, and silver ion adsorption performance were explored. The nanoflower-like microstructure showed the maximum specific surface area 18.98 ± 0.949 m²/g, which was 55.8 times higher than that of the solid microsphere control. As a result, the maximum silver ion adsorption capacity was 7.95 ± 0.396 mmol/g, which was 10.9 times higher than that of the control. Kinetic studies showed that the equilibrium adsorption amount of FT₁F₄M was 12.61 ± 0.016 mmol/g, which was 11.6 times higher than that of the control. Additionally, the isotherm study of the adsorption process was performed, and the maximum adsorption capacity of FT₁F₄M was 18.17 ± 1.28 mmol/g, which was 13.8 times that of the control according to the Langmuir adsorption model. Its high absorption efficiency, convenient preparation strategy, and low cost recommend FTFM bright for further use in industrial applications. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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15 pages, 3574 KiB

Open AccessArticle

Chitosan Polymer Functionalized-Activated Carbon/Montmorillonite Composite for the Potential Removal of Lead Ions from Wastewater

by Ibrahim Hotan Alsohaimi, Mosaed S. Alhumaimess, Hassan M. A. Hassan, Mohamed Reda, Abdullah M. Aldawsari, Qiao Chen and Mohammed Abdo Kariri

Polymers 2023, 15(9), 2188; https://doi.org/10.3390/polym15092188 - 05 May 2023

Cited by 3 | Viewed by 1975

Abstract

A simple approach for synthesizing a highly adsorbent composite was described for the uptake of heavy metal ions from wastewater. A simple approach for synthesizing a highly adsorbent composite was also described for the elimination of heavy metal ions from contaminated water. The [...] Read more.

A simple approach for synthesizing a highly adsorbent composite was described for the uptake of heavy metal ions from wastewater. A simple approach for synthesizing a highly adsorbent composite was also described for the elimination of heavy metal ions from contaminated water. The nanocomposite was synthesized via a polymer grafting of chitosan on the activated carbon surface, followed by a stacking process with the layers of montmorillonite clay. The spectroscopic analyses were exploited to confirm the composite structure of the prepared materials. Various adsorption parameters, such as pH, initial concentration, and adsorption time, were assessed. The results showed that the adsorption capacity of the composite for Pb²⁺ ions increased as the pH increased until it reached pH 5.5. The maximum adsorption capacity was observed at an initial Pb²⁺ level of 20 mg/L and a contact time of 150 min. Kinetic models were evaluated, and the pseudo second-order model showed the best match. The adsorption isotherm data were processed by fitting the model with different isotherm behaviors, and the Langmuir isotherm was found to be the most suitable for the system. The maximum adsorption capacity for Pb²⁺ ion on the MMT/CS/AC composite was found to be 50 mg/g at pH 5.5. Furthermore, the composite maintained a high adsorption capability of 85% for five adsorption–desorption cycles. Overall, this composite is envisioned as an addition to the market of wastewater remediation technology due to its chemical structure, which provides influential functional groups for wastewater treatment. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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12 pages, 3601 KiB

Open AccessArticle

Synthesis and Application of a Novel Metal–Organic Frameworks-Based Ion-Imprinted Polymer for Effective Removal of Co(II) from Simulated Radioactive Wastewater

by Li Yu, Tu Lan, Guoyuan Yuan, Chongxiong Duan, Xiaoqin Pu and Ning Liu

Polymers 2023, 15(9), 2150; https://doi.org/10.3390/polym15092150 - 30 Apr 2023

Cited by 2 | Viewed by 1275

Abstract

In this work, a novel metal–organic frameworks (MOFs)-based ion-imprinted polymer (MIIP) was prepared to remove Co(II) from simulated radioactive wastewater. The batch experiments indicated that the sorption was well described by the pseudo-second-order kinetic and Langmuir models, and it is monolayer chemisorption. The [...] Read more.

In this work, a novel metal–organic frameworks (MOFs)-based ion-imprinted polymer (MIIP) was prepared to remove Co(II) from simulated radioactive wastewater. The batch experiments indicated that the sorption was well described by the pseudo-second-order kinetic and Langmuir models, and it is monolayer chemisorption. The theoretical maximum sorption capacity was estimated to be 181.5 mg∙g⁻¹, which is by far the reported maximum value of Co(II) sorption by the imprinted materials. The MIIP presented an excellent selectivity for Co(II) in the presence of common monovalent and divalent metal ions, and the selectivity coefficients were 44.31, 33.19, 10.84, 27.71, 9.45, 16.25, and 7.60 to Li(I), K(I), Mg(II), Ca(II), Mn(II), Ba(II), and Cd(II), respectively. The sorption mechanism was explored by X-ray photoelectron spectroscopy (XPS) technology and density functional theory (DFT) calculations, suggesting that Co(II) was adsorbed by the MIIP via the chelation of 4-vinylpyridine (VP) ligands with Co(II), which was a spontaneous process, and the optimal coordination ratio of VP to Co(II) was 6. This work suggested that the MIIP has a high sorption capacity and excellent selectivity for Co(II), which is of great significance for the selective separation of Co-60 from radioactive wastewater. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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18 pages, 2504 KiB

Open AccessArticle

Adsorption Kinetics of Methyl Orange from Model Polluted Water onto N-Doped Activated Carbons Prepared from N-Containing Polymers

by Abdel-Basit Al-Odayni, Faisal S. Alsubaie, Naaser A. Y. Abdu, Haifa Masfeer Al-Kahtani and Waseem Sharaf Saeed

Polymers 2023, 15(9), 1983; https://doi.org/10.3390/polym15091983 - 22 Apr 2023

Cited by 4 | Viewed by 1421

Abstract

This study aimed to assess the role of polymeric sources (polypyrrole, polyaniline, and their copolymer) of nitrogen (N)-doped activated carbons (indexed as PAnAC, PPyAC, and PnyAC, respectively) on their adsorption efficiency to remove methyl orange (MO) as a model cationic dye. The adsorbents [...] Read more.

This study aimed to assess the role of polymeric sources (polypyrrole, polyaniline, and their copolymer) of nitrogen (N)-doped activated carbons (indexed as PAnAC, PPyAC, and PnyAC, respectively) on their adsorption efficiency to remove methyl orange (MO) as a model cationic dye. The adsorbents were characterized using FTIR, SEM, TGA, elemental analysis, and surface area. The kinetic experiments were performed in batches at different MO concentrations (C₀) and adsorbent dosages. The adsorption kinetic profiles of pseudo-first-order, pseudo-second-order (PSO), Elovich, intraparticle diffusion, and liquid film diffusion models were compared. The results showed a better fit to the PSO model, suggesting a chemisorption process. The adsorption capacity (q_e, mg/g) was found to have increased as MO C₀ increased, yet decreased as the adsorbent quantity increased. At the adsorption operating condition, including MO C₀ (200 ppm) and adsorbent dose (40 mg), the calculated q_e values were in the order of PAnAC (405 mg/g) > PPyAC (204 mg/g) > PnyAC (182 mg/g). This trend proved the carbon precursor’s importance in the final properties of the intended carbons; elemental analysis confirmed that the more nitrogen atoms are in the activated carbon, the greater the number of active sites in the adsorbent for accommodating adsorbates. The diffusion mechanism also assumed a rate-limiting step controlled by the film and intraparticle diffusion. Therefore, such an efficient performance may support the target route’s usefulness in converting nitrogenous-species waste into valuable materials. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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17 pages, 4704 KiB

Open AccessArticle

Decoding the Role of Extracellular Polymeric Substances in Enhancing Nitrogen Removal from High-Ammonia and Low-C/N Wastewater in a Sequencing Batch Packed-Bed Biofilm Reactor

by Zheng Fan and Xin Zhou

Polymers 2023, 15(6), 1510; https://doi.org/10.3390/polym15061510 - 17 Mar 2023

Viewed by 1478

Abstract

Although the role of extracellular polymeric substances (EPSs) as a viscous high-molecular polymer in biological wastewater treatment has been recognized, in-depth knowledge of how EPSs affect nitrogen removal remains limited in biofilm-based reactors. Herein, we explored EPS characteristics associated with nitrogen removal from [...] Read more.

Although the role of extracellular polymeric substances (EPSs) as a viscous high-molecular polymer in biological wastewater treatment has been recognized, in-depth knowledge of how EPSs affect nitrogen removal remains limited in biofilm-based reactors. Herein, we explored EPS characteristics associated with nitrogen removal from high-ammonia (NH₄⁺-N: 300 mg/L) and low carbon-to-nitrogen ratio (C/N: 2–3) wastewater in a sequencing batch packed-bed biofilm reactor (SBPBBR) under four different operating scenarios for a total of 112 cycles. Scanning electron microscopy (SEM), atomic force microscopy (AFM), and Fourier-transform infrared (FTIR) analysis revealed that the distinct physicochemical properties, interface microstructure, and chemical composition of the bio-carrier were conducive to biofilm formation and microbial immobilization and enrichment. Under the optimal conditions (C/N: 3, dissolved oxygen: 1.3 mg/L, and cycle time: 12 h), 88.9% ammonia removal efficiency (ARE) and 81.9% nitrogen removal efficiency (NRE) could be achieved in the SBPBBR. Based on visual and SEM observations of the bio-carriers, biofilm development, biomass concentration, and microbial morphology were closely linked with nitrogen removal performance. Moreover, FTIR and three-dimensional excitation–emission matrix (3D-EEM) spectroscopy demonstrated that tightly bound EPSs (TB-EPSs) play a more important role in maintaining the stability of the biofilm. Significant shifts in the number, intensity, and position of fluorescence peaks of EPSs determined different nitrogen removal. More importantly, the high presence of tryptophan proteins and humic acids might promote advanced nitrogen removal. These findings uncover intrinsic correlations between EPSs and nitrogen removal for better controlling and optimizing biofilm reactors. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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14 pages, 2803 KiB

Open AccessArticle

Study on Flocculation Behavior of Cr(VI) Using a Novel Chitosan Functionalized with Thiol Groups

by Yuelong Zhao, Peng Zhang, Wei Zhang and Yali Fan

Polymers 2023, 15(5), 1117; https://doi.org/10.3390/polym15051117 - 23 Feb 2023

Cited by 1 | Viewed by 1257

Abstract

In this study, CTS-GSH was prepared by grafting thiol (–SH) groups onto chitosan (CTS), which was characterized through Fourier Transform Infrared (FT-IR) spectra, Scanning Electron Microscopy (SEM) and Differential Thermal Analysis–Thermogravimetric Analysis (DTA-TG). The performance of CTS-GSH was evaluated by measuring Cr(VI) removal [...] Read more.

In this study, CTS-GSH was prepared by grafting thiol (–SH) groups onto chitosan (CTS), which was characterized through Fourier Transform Infrared (FT-IR) spectra, Scanning Electron Microscopy (SEM) and Differential Thermal Analysis–Thermogravimetric Analysis (DTA-TG). The performance of CTS-GSH was evaluated by measuring Cr(VI) removal efficiency. The –SH group was successfully grafted onto CTS, forming a chemical composite, CTS-GSH, with a rough, porous and spatial network surface. All of the molecules tested in this study were efficient at removing Cr(VI) from the solution. The more CTS-GSH added, the more Cr(VI) removed. When a suitable dosage of CTS-GSH was added, Cr(VI) was almost completely removed. The acidic environment at pH 5–6 was beneficial for the removal of Cr(VI), and at pH 6, the maximum removal efficiency was achieved. Further experimentation showed that with 100.0 mg/L CTS-GSH for the disposal of 5.0 mg/L Cr(VI) solution, the removal rate of Cr(VI) reached 99.3% with a slow stirring time of 8.0 min and sedimentation time of 3 h; the presence of four common ions, including Mg²⁺, Ca²⁺, SO₄²⁻ and CO₃²⁻, had an inhibitory effect on CTS-GSH’s ability to remove Cr(VI) from the aqueous solution, and more CTS-GSH was needed to reduce this inhibiting action. Overall, CTS-GSH exhibited good results in Cr(VI) removal, and thus has good potential for the further treatment of heavy metal wastewater. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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17 pages, 3348 KiB

Open AccessArticle

Sodium Alginate/Modified Bentonite Composite Bead Adsorptive Removal of Norfloxacin: Static and Dynamic Adsorption

by Jun Zhou and Qianyu Sun

Polymers 2022, 14(19), 3984; https://doi.org/10.3390/polym14193984 - 23 Sep 2022

Cited by 7 | Viewed by 1665

Abstract

The low-cost calcium-based bentonite modified with anionic and cationic surfactants was granulated by cross-linking to sodium alginate (SA) to promote the adsorption efficiencies of norfloxacin (NOR). The characterization studies illustrated that the intercalation of cetyltrimethylammonium bromide (CTAB) and sodium dodecyl benzene sulfonate (SDBS) [...] Read more.

The low-cost calcium-based bentonite modified with anionic and cationic surfactants was granulated by cross-linking to sodium alginate (SA) to promote the adsorption efficiencies of norfloxacin (NOR). The characterization studies illustrated that the intercalation of cetyltrimethylammonium bromide (CTAB) and sodium dodecyl benzene sulfonate (SDBS) was successful. The modification improved the pore structure and the granular SA/organically modified bentonite composite (GOMBt) exhibited a lamellar structure with some roughness. The adsorption kinetics and isotherms indicated that adsorption of NOR on GOMBt was an endothermic process. The effects of various factors on the adsorption of NOR suggested that the maximum adsorption capacity was obtained under acidic conditions and cations improved the adsorption process. A fixed-bed column was employed to investigate the dynamic adsorption characteristics of NOR by GOMBt. The breakthrough time and bed height had a positive correlation; however, the relation of flow rate, pH, and breakthrough time had a negative correlation. The results showed that the dynamic adsorption data of NOR on GOMBt fitted Thomas and Yoon–Nelson models. The internal and external diffusion in GOMBt dynamic adsorption was not a rate-limiting step. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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20 pages, 12032 KiB

Open AccessArticle

The Synergistic Effects of Al³⁺ and Chitosan on the Solid–Liquid Separation of Coal Wastewater and Their Mechanism of Action

by Ming Chang, Xiaomin Ma, Xianshu Dong, Yuping Fan and Ruxia Chen

Polymers 2022, 14(19), 3970; https://doi.org/10.3390/polym14193970 - 22 Sep 2022

Cited by 3 | Viewed by 1693

Abstract

It is important to identify an environmentally friendly and efficient flocculant that can replace polyacrylamide for the solid–liquid separation of coal wastewater. In this study, to explore whether chitosan can be used as an environmentally friendly and efficient flocculant for the solid–liquid separation [...] Read more.

It is important to identify an environmentally friendly and efficient flocculant that can replace polyacrylamide for the solid–liquid separation of coal wastewater. In this study, to explore whether chitosan can be used as an environmentally friendly and efficient flocculant for the solid–liquid separation of coal wastewater, AlCl₃–chitosan was used to conduct flocculation–sedimentation and dewatering tests under different chitosan dosages and shear-strength conditions for the prepared coal wastewater. Focused beam reflectance was measured to dynamically monitor the number of refractory fine particles, and the settled flocs were photographed and analyzed with microscopy to explore the effect of AlCl₃–chitosan on the flocculation settlement effect and floc characteristics. The synergistic mechanisms of AlCl₃ and chitosan were investigated using quartz crystal dissipative microbalance and zeta potential measurement. The results showed that the addition of chitosan can significantly improve the flocculation–sedimentation and dewatering effects of coal wastewater. A reasonable dosage under a certain shear strength is conducive to the reduction of fine slime particles, which results in a compact floc structure, increases the floc size, and improves the settling effect. The synergistic effect of AlCl₃–chitosan improved the electric neutralization and adsorption bridging abilities of the chitosan, and the mixed solution of AlCl₃ and chitosan had stronger adsorption on the carbon surface. This study provides a new approach to the selection of flocculants for coal wastewater treatment. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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14 pages, 3906 KiB

Open AccessArticle

Fast Granulation by Combining External Sludge Conditioning with FeCl₃ Addition and Reintroducing into an SBR

by Jun Liu, Shunchang Yin, Dong Xu, Sarah Piché-Choquette, Bin Ji, Xin Zhou and Jun Li

Polymers 2022, 14(17), 3688; https://doi.org/10.3390/polym14173688 - 05 Sep 2022

Cited by 1 | Viewed by 1375

Abstract

The separation of light and heavy sludge, as well as the aggregation rate of floccular sludge, are two critical aspects of the rapid granulation process in sequencing batch reactors (SBRs) in the early stages. In this study, we investigated the impact of a [...] Read more.

The separation of light and heavy sludge, as well as the aggregation rate of floccular sludge, are two critical aspects of the rapid granulation process in sequencing batch reactors (SBRs) in the early stages. In this study, we investigated the impact of a method to improve both sludge separation and granulation by coupling effluent sludge external conditioning with FeCl₃ addition and then reintroducing it into the SBR. By supplementation with 0.1 g Fe³⁺ (g dried sludge (DS))⁻¹, the concentration of extracellular polymeric substances (EPS) and sludge retention efficiency greatly increased, whereas the moisture content and specific oxygen uptake rate (SOUR) sharply decreased within 24 h external conditioning. Aggregates (1.75 ± 0.05 g·L⁻¹) were reintroduced into the bioreactor once daily from day 13 to day 15. Afterwards, on day 17, aerobic granules with a concentration of mixed liquor suspended solids (MLSS) of 5.636 g/L, a sludge volume index (SVI₃₀) of 45.5 mL/g and an average size of 2.5 mm in diameter were obtained. These results suggest that the external conditioning step with both air-drying and the addition of Fe³⁺ enhanced the production of EPS in the effluent sludge and improved rapid aggregation and high sludge retention efficiency. Consequently, the reintroduced aggregates with good traits shortened the time required to obtain mature aerobic granular sludge (AGS) and properly separate light and heavy sludge. Indeed, this method jump-started the aggregation, and rapid granulation processes were successful in this work. Additionally, while the removal efficiency of chemical oxygen demand (COD) and nitrogen from ammonium (NH₄⁺-N) decreased when reintroducing the treated sludge into the SBR, such properties increased again as the AGS matured in the SBR, up to removal efficiencies of 96% and 95%, respectively. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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20 pages, 5546 KiB

Open AccessArticle

Fabrication of Novel Agrowaste (Banana and Potato Peels)-Based Biochar/TiO₂ Nanocomposite for Adsorption of Cr(VI), Statistical Optimization via RSM Approach

by Aamna Ashfaq, Raziya Nadeem, Hongyu Gong, Umer Rashid, Saima Noreen, Shafique ur Rehman, Zubair Ahmed, Muhammad Adil, Nayab Akhtar, Muhammad Zeeshan Ashfaq, Fahad A. Alharthi and Elham Ahmed Kazerooni

Polymers 2022, 14(13), 2644; https://doi.org/10.3390/polym14132644 - 29 Jun 2022

Cited by 3 | Viewed by 2175

Abstract

In this research work, a simple, efficient, and eco-friendly procedure for the biosorption of Cr(VI) ions was studied. A detailed comparative study was performed to check the adsorption efficiency of agrowaste (banana and potato peels)-based adsorbents. Firstly, mixed biosorbent was washed, dried and [...] Read more.

In this research work, a simple, efficient, and eco-friendly procedure for the biosorption of Cr(VI) ions was studied. A detailed comparative study was performed to check the adsorption efficiency of agrowaste (banana and potato peels)-based adsorbents. Firstly, mixed biosorbent was washed, dried and ground into powder, secondly, biosorbent was pyrolyzed into biochar and thirdly TiO₂ nanocomposite (TiO₂ NC) biosorbent was made by sonicating using prepared biochar and TiO₂ NPs. Titanium dioxide nanoparticles (TiO₂ NPs) were synthesized by a green method using Psidium guajava leaf extract. The synthesized adsorbents were characterized by SEM, EDX FT-IR, XRD and UV-visible analysis. The effect of four different factors, i.e., pH of the synthetic metallic solution, time, concentration and adsorbent dosage was studied. The optimum conditions were time (120 min), pH (3), concentration (10 ppm) and adsorbent dosage (1.0 g). The kinetic modeling showed that the adsorption of Cr(VI) ion follows a pseudo second-order mechanism and the Langmuir isotherm model was found to fit better for this study. Response surface methodology (RSM)-based optimized parameters provided optimal parameter sets that better represent the adsorption rate models. The uptake capacity of Cr(VI) from aqueous solution was found to be biomass (76.49 mg/L) ˂ biochar (86.51 mg/L) ˂ TiO₂ NC (92.89 mg/L). It can be suggested that the produced TiO₂ NC could possibly be an efficient biosorbent for the removal of Cr(IV). Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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18 pages, 7724 KiB

Open AccessArticle

Advanced Research on Polymer Floating Carrier Application in Activated Sludge Reactors

by Nikolay Makisha

Polymers 2022, 14(13), 2604; https://doi.org/10.3390/polym14132604 - 27 Jun 2022

Cited by 2 | Viewed by 1028

Abstract

This research estimates the efficiency of domestic wastewater treatment in the removal of organic pollutants and nitrogen compounds with a two-stage treatment sequence (an activated sludge reactor in the first stage, and a trickling filter in the second stage), and with the application [...] Read more.

This research estimates the efficiency of domestic wastewater treatment in the removal of organic pollutants and nitrogen compounds with a two-stage treatment sequence (an activated sludge reactor in the first stage, and a trickling filter in the second stage), and with the application of floating carriers in the activated sludge reactor. The materials “Polyvom”, “Polystyrene” and “Bioballs” were adopted as floating carriers with previously determined filling ratios in the reactor volume of 10%, 20% and 20%, respectively. After the first stage of the study, it was found that the most effective treatment was achieved using the “Polyvom” material. Therefore, only this floating carrier was considered in the second and third stages of the study. Within the stages of the research, lab-scale benches operated under different operation modes of the treatment sequence. At the end of the study, it was possible to achieve the following levels of purification: BOD₅ (2.1 mg/L), NH₄ (0.4 mg/L), NO₂ (1.0 mg/L), and NO₃ (25 mg/L). The mean values of the concentrations of BOD, NH₄, and NO₃ met the requirements, but the concentration of NO₂ exceeded the requirements (1.0 mg/L vs. 0.08 mg/L). These results were achieved under a hydraulic retention time in the activated sludge reactor of 8 h, and the MLSS for the free-floating and immobilized activated sludge was 0.2 and 0.9 g/L, respectively. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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Review

Jump to: Research

31 pages, 4778 KiB

Open AccessReview

Starch-Based Polymer Materials as Advanced Adsorbents for Sustainable Water Treatment: Current Status, Challenges, and Future Perspectives

by Pui San Khoo, R. A. Ilyas, M. N. A. Uda, Shukur Abu Hassan, A. H. Nordin, A. S. Norfarhana, N. H. Ab Hamid, M. S. A. Rani, Hairul Abral, M. N. F. Norrrahim, V. F. Knight, Chuan Li Lee and S. Ayu Rafiqah

Polymers 2023, 15(14), 3114; https://doi.org/10.3390/polym15143114 - 21 Jul 2023

Cited by 12 | Viewed by 2825

Abstract

Over the past three decades, chemical and biological water contamination has become a major concern, particularly in the industrialized world. Heavy metals, aromatic compounds, and dyes are among the harmful substances that contribute to water pollution, which jeopardies the human health. For this [...] Read more.

Over the past three decades, chemical and biological water contamination has become a major concern, particularly in the industrialized world. Heavy metals, aromatic compounds, and dyes are among the harmful substances that contribute to water pollution, which jeopardies the human health. For this reason, it is of the utmost importance to locate methods for the cleanup of wastewater that are not genuinely effective. Owing to its non-toxicity, biodegradability, and biocompatibility, starch is a naturally occurring polysaccharide that scientists are looking into as a possible environmentally friendly material for sustainable water remediation. Starch could exhibit significant adsorption capabilities towards pollutants with the substitution of amide, amino, carboxyl, and other functional groups for hydroxyl groups. Starch derivatives may effectively remove contaminants such as oil, organic solvents, pesticides, heavy metals, dyes, and pharmaceutical pollutants by employing adsorption techniques at a rate greater than 90%. The maximal adsorption capacities of starch-based adsorbents for oil and organic solvents, pesticides, heavy metal ions, dyes, and pharmaceuticals are 13,000, 66, 2000, 25,000, and 782 mg/g, respectively. Although starch-based adsorbents have demonstrated a promising future for environmental wastewater treatment, additional research is required to optimize the technique before the starch-based adsorbent can be used in large-scale in situ wastewater treatment. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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28 pages, 1079 KiB

Open AccessReview

Insights into the Applications of Natural Fibers to Metal Separation from Aqueous Solutions

by Lavinia Tofan

Polymers 2023, 15(9), 2178; https://doi.org/10.3390/polym15092178 - 03 May 2023

Cited by 2 | Viewed by 1711

Abstract

There is a wide range of renewable materials with attractive prospects for the development of green technologies for the removal and recovery of metals from aqueous streams. A special category among them are natural fibers of biological origin, which combine remarkable biosorption properties [...] Read more.

There is a wide range of renewable materials with attractive prospects for the development of green technologies for the removal and recovery of metals from aqueous streams. A special category among them are natural fibers of biological origin, which combine remarkable biosorption properties with the adaptability of useful forms for cleanup and recycling purposes. To support the efficient exploitation of these advantages, this article reviews the current state of research on the potential and real applications of natural cellulosic and protein fibers as biosorbents for the sequestration of metals from aqueous solutions. The discussion on the scientific literature reports is made in sections that consider the classification and characterization of natural fibers and the analysis of performances of lignocellulosic biofibers and wool, silk, and human hair waste fibers to the metal uptake from diluted aqueous solutions. Finally, future research directions are recommended. Compared to other reviews, this work debates, systematizes, and correlates the available data on the metal biosorption on plant and protein biofibers, under non-competitive and competitive conditions, from synthetic, simulated, and real solutions, providing a deep insight into the biosorbents based on both types of eco-friendly fibers. Full article

(This article belongs to the Special Issue Polymeric Materials for Water/Wastewater Treatment Applications)

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