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Special Issue "Polymer Materials in Dentistry"

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A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Processing and Engineering".

Deadline for manuscript submissions: 31 March 2024 | Viewed by 4609

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Prof. Dr. Gaetano Paolone

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Guest Editor

Department of Dentistry, IRCCS San Raffaele Hospital and Dental School, Vita Salute University, 20132 Milan, Italy
Interests: restorative dentistry; dental biomaterials; CAD/CAM; composites; bulk
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Special Issue Information

Dear Colleagues,

In the field of dentistry, polymeric biomaterials are gaining popularity due to their desirable characteristics such as biocompatibility, easy handling, and low cost. These materials are used to treat various dental and maxillofacial diseases and defects, including dental caries, partial and complete edentulousness, and maxillofacial defects, among others. The use of polymeric materials in the oral cavity is particularly noteworthy for their drug delivery capability and antimicrobial properties, as well as their application in preventive, reconstructive, and regenerative therapies. With the advancement of 3D printing technologies, new and promising alternatives in the fields of dentistry and medicine are emerging. These 3D printing resin materials offer improved physical, mechanical, and antibacterial properties for oral and medical appliances. However, there is a lack of data on polymeric biomaterials for oral and maxillofacial reconstructive treatment. To address this knowledge gap, this Special Issue invites researchers and clinicians from various disciplines, including material sciences, dentistry, medicine, 3D printing, and CAD/CAM, to submit their scientific findings in the form of original research articles, review articles and communications. The aim of this Special Issue is to highlight the latest achievements in the field of polymeric sciences for oral treatment.

Prof. Dr. Gaetano Paolone
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

polymeric biomaterials
dentistry
dental diseases
reconstructive
restorations
3D printing
resin materials

Published Papers (4 papers)

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Research

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14 pages, 1126 KiB

Open AccessArticle

Comparison of a Nanofiber-Reinforced Composite with Different Types of Composite Resins

Zümrüt Ceren Özduman

Burcu Oglakci

Derya Merve Halacoglu Bagis

Binnur Aydogan Temel

and

Evrim Eliguzeloglu Dalkilic

Polymers 2023, 15(17), 3628; https://doi.org/10.3390/polym15173628 - 01 Sep 2023

Cited by 1 | Viewed by 704

Abstract

The aim of this study was a comprehensive evaluation and comparison of the physical and mechanical properties of a newly developed nano-sized hydroxyapatite fiber-reinforced composite with other fiber-reinforced and particle-filled composites. Commercially available eight composite resins (3 fiber-reinforced and 5 particle-filled) were used: Fiber-reinforced composites: (1) NovaPro Fill (Nanova): newly developed nano-sized hydroxyapatite fiber-reinforced composite (nHAFC-NF); (2) Alert (Pentron): micrometer-scale glass fiber-reinforced composite (µmGFC-AL); (3) Ever X Posterior (GC Corp): millimeter-scale glass fiber-reinforced composite (mmGFC-EX); Particle-filled composites: (4) SDR Plus (Dentsply) low-viscosity bulk-fill (LVBF-SDR); (5) Estelite Bulk Fill (Tokuyama Corp.) low-viscosity bulk-fill (LVBF-EBF); (6) Filtek Bulk Fill Flow (3M ESPE) low-viscosity bulk-fill (LVBF-FBFF); (7) Filtek Bulk Fill (3M ESPE) high-viscosity bulk-fill (HVBF-FBF); and (8) Filtek Z250 (3M ESPE): microhybrid composite (µH-FZ). For Vickers microhardness, cylindrical-shaped specimens (diameter: 4 mm, height: 2 mm) were fabricated (n = 10). For the three-point bending test, bar-shaped (2 × 2 × 25 mm) specimens were fabricated (n = 10). Flexural strength and modulus elasticity were calculated. AcuVol, a video image device, was used for volumetric polymerization shrinkage (VPS) evaluations (n = 6). The polymerization degree of conversion (DC) was measured on the top and bottom surfaces with Fourier Transform Near-Infrared Spectroscopy (FTIR; n = 5). The data were statistically analyzed using one-way ANOVA, Tukey HSD, Welsch ANOVA, and Games–Howell tests (p < 0.05). Pearson coefficient correlation was used to determine the linear correlation. Group µH-FZ displayed the highest microhardness, flexural strength, and modulus elasticity, while Group HVBF-FBF exhibited significantly lower VPS than other composites. When comparing the fiber-reinforced composites, Group mmGFC-EX showed significantly higher microhardness, flexural strength, modulus elasticity, and lower VPS than Group nHAFC-NF but similar DC. A strong correlation was determined between microhardness, VPS and inorganic filler by wt% and vol% (r = 0.572–0.877). Fiber type and length could affect the physical and mechanical properties of fibers containing composite resins. Full article

(This article belongs to the Special Issue Polymer Materials in Dentistry)

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9 pages, 294 KiB

Open AccessArticle

Effects of Translucency and Thickness of Lithium Disilicate-Reinforced Glass-Ceramic Veneers on the Degree of Conversion of a Purely Light-Curing Bonding Resin: An In Vitro Study

Anthony Poca

Kenza De Peretti Della Rocca

Karim Nasr

Romain Ducassé

and

Thibault Canceill

Polymers 2023, 15(7), 1617; https://doi.org/10.3390/polym15071617 - 24 Mar 2023

Viewed by 1111

Abstract

The objective of this study was to evaluate the variations in the degree of conversion (DC) of a light-curing composite resin when the thickness or the translucency of lithium disilicate-enriched glass-ceramic veneers are modified. IPS e. max^® CAD blocks of the MT-A2, LT-A2 and MO1 types were cut to obtain four slices with thicknesses ranging from 0.6 mm to 1 mm. A strictly light-curing composite resin (G-aenial Universal Injectable) was injected in the empty part of a silicone mold so that the veneer could then be inserted under digital pressure to the stop. A 40 s light cure (1400 mW/cm²) was then performed. Resin samples were analyzed using Fourier transform infrared (FTIR) spectroscopy. When the degree of translucency of the ceramic was modified, a decrease in the resin conversion rate was noted, but with a non-significant global p-value (p = 0.062). Interestingly, the degree of conversion of the light-curing composite resin was also modified when the ceramic’s thickness increased, especially when it was over 1 mm (DC_0.6 > DC_0.7 > DC_0.8 > DC₁; p < 0.0001). This confirms that the degree of conversion of a bonding material is very dependent on the ceramic’s thickness. Contradictory data are, however, found in the literature, where there are reports of an absence of a difference between the DC obtained with thicknesses of ceramics of 0.7 and 2 mm. Full article

(This article belongs to the Special Issue Polymer Materials in Dentistry)

13 pages, 4293 KiB

Open AccessArticle

Translucency of CAD/CAM and 3D Printable Composite Materials for Permanent Dental Restorations

and

Polymers 2023, 15(6), 1443; https://doi.org/10.3390/polym15061443 - 15 Mar 2023

Cited by 14 | Viewed by 1601

Abstract

The aim of the study was to compare the translucency of CAD/CAM and printable composite materials for fixed dental prostheses (FDP). Eight A3 composite materials (7 CAD/CAM and 1 printable) for FPD were used to prepare a total of 150 specimens. CAD/CAM materials, all characterized by two different opacity levels, were: Tetric CAD (TEC) HT/MT; Shofu Block HC (SB) HT/LT; Cerasmart (CS) HT/LT; Brilliant Crios (BC) HT/LT; Grandio Bloc (GB) HT/LT; Lava Ultimate (LU) HT/LT, Katana Avencia (KAT) LT/OP. The printable system was Permanent Crown Resin. 1.0 mm-thick specimens were cut from commercial CAD/CAM blocks using a water-cooled diamond saw, or 3D printed. Measurements were performed using a benchtop spectrophotometer with an integrating sphere. Contrast Ratio (CR), Translucency Parameter (TP), and Translucency Parameter 00 (TP₀₀) were calculated. One Way ANOVA followed by Tukey test for post hoc were performed for each of the translucency system. The tested materials exhibited a wide range of translucency values. CR ranged from 59 to 84, TP from 15.75 to 8.96, TP₀₀ from 12.47 to 6.31. KAT(OP) and CS(HT) showed, respectively, the lowest and highest translucency for CR, TP and TP₀₀. Due to the significant range of reported translucency values, clinicians should exercise caution when choosing the most appropriate material, especially considering factors such as substrate masking, and the necessary clinical thickness. Full article

(This article belongs to the Special Issue Polymer Materials in Dentistry)

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Review

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18 pages, 2672 KiB

Open AccessReview

Different Polymers for the Base of Removable Dentures? Part I: A Narrative Review of Mechanical and Physical Properties

Pierre Le Bars

Octave Nadile Bandiaky

Laurent Le Guéhennec

Roselyne Clouet

and

Alain Ayepa Kouadio

Polymers 2023, 15(17), 3495; https://doi.org/10.3390/polym15173495 - 22 Aug 2023

Viewed by 735

Abstract

Even before considering their introduction into the mouth, the choice of materials for the optimization of the prosthesis depends on specific parameters such as their biocompatibility, solidity, resistance, and longevity. In the first part of this two-part review, we approach the various mechanical characteristics that affect this choice, which are closely related to the manufacturing process. Among the materials currently available, it is mainly polymers that are suitable for this use in this field. Historically, the most widely used polymer has been polymethyl methacrylate (PMMA), but more recently, polyamides (nylon) and polyether ether ketone (PEEK) have provided interesting advantages. The incorporation of certain molecules into these polymers will lead to modifications aimed at improving the mechanical properties of the prosthetic bases. In the second part of the review, the safety aspects of prostheses in the oral ecosystem (fragility of the undercuts of soft/hard tissues, neutral pH of saliva, and stability of the microbiota) are addressed. The microbial colonization of the prosthesis, in relation to the composition of the material used and its surface conditions (roughness, hydrophilicity), is of primary importance. Whatever the material and manufacturing process chosen, the coating or finishes dependent on the surface condition remain essential (polishing, non-stick coating) for limiting microbial colonization. The objective of this narrative review is to compile an inventory of the mechanical and physical properties as well as the clinical conditions likely to guide the choice between polymers for the base of removable prostheses. Full article

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