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Advances in Multicomponent Alloy Design, Simulation and Properties

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Metals and Alloys".

Deadline for manuscript submissions: 20 October 2024 | Viewed by 870

Special Issue Editors


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Guest Editor
Department of Physics, American University of Sharjah, Sharjah, United Arab Emirates
Interests: electronic properties; magnetic properties; superconductivity; alloy design; structural properties and thin films

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Guest Editor
Department of Mechanical Engineering, American University of Sharjah, Sharjah, United Arab Emirates
Interests: metallic materials; mechanical properties; high-temperature properties; cryogenic temperature properties; high-temperature high-entropy alloys; cryogenic-temperature alloys; high-temperature shape memory alloys
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Special Issue Information

Dear Colleagues,

Materials science research has a strong impact on technological advancement and pushing manufacturing towards industry 4.0 and the possible space era.  Materials with versatile electronic, magnetic, and mechanical functionalities in extreme environments are in high demand; hence, the discovery of new materials and/or combinations of existing materials is essential. Conventional alloys generally relying on the presence of a single principal element and various minor constituents have been pushed toward their functional limits. Nearly two decades ago, new groups of materials, known as high-entropy alloys (HEA) and medium-entropy alloys, were introduced.  The utilization of a large percentage of multiple principal constituent elements created unique alloying and composition optimization processes, in which materials with functionalities surpassing existing alloys could be realized. According to  Boltzmann’s simple entropy formula, if the configurations in an alloy all have the same weighting or energy, the configurational entropy is given as S=kBLn(R), where S is the total configurational entropy, kB is the Boltzmann constant, and R is the number of possible configurations. It was suggested that the presence of multiple elements (in earlier studies, five or more elements were used) with near equiatomic ratios would maximize the configurational entropy to the degree required to overcome compound formation enthalpy and subsequently stabilize the solid solution state with relatively simple crystal structures.  Recent experimental and theoretical studies revealed the importance of the low enthalpy of the mixing, in addition to the high-entropy criterion. The low-enthalpy criterion is very attractive, as it offers a wider compositional range that comprises alloys with fewer elements, as well as alloy structures that deviate from equiatomic compositions. Such progress led to the renaming of this group of alloys; nowadays, multicomponent alloy systems terminology is preferred over high-entropy alloy terminology.  Such alloying techniques have had a significant impact on the design of new alloys with superior electronic, magnetic, mechanical, and electrochemical functionalities.

This Special Issue will bring together recent experimental and theoretical developments in the field of multicomponent alloys, including, but not limited to, alloy design and the electrical and magnetic, mechanical, and electrochemical properties of these alloys in bulk, single-crystal, and thin-film form. 

Prof. Dr. Mehmet Egilmez
Dr. Wael Abuzaid
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

high-entropy alloys

mechanical properties

multi-principal element alloys

high-entropy alloy thin films

high-entropy alloy design

high-entropy alloy superconductors

cryogenic alloys

Published Papers (1 paper)

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Research

18 pages, 3586 KiB  
Article
The Impact of Marangoni and Buoyancy Convections on Flow and Segregation Patterns during the Solidification of Fe-0.82wt%C Steel
by Ibrahim Sari, Menghuai Wu, Mahmoud Ahmadein, Sabbah Ataya, Nashmi Alrasheedi and Abdellah Kharicha
Materials 2024, 17(5), 1205; https://doi.org/10.3390/ma17051205 - 05 Mar 2024
Viewed by 564
Abstract
Due to the high computational costs of the Eulerian multiphase model, which solves the conservation equations for each considered phase, a two-phase mixture model is proposed to reduce these costs in the current study. Only one single equation for each the momentum and [...] Read more.
Due to the high computational costs of the Eulerian multiphase model, which solves the conservation equations for each considered phase, a two-phase mixture model is proposed to reduce these costs in the current study. Only one single equation for each the momentum and enthalpy equations has to be solved for the mixture phase. The Navier–Stokes and energy equations were solved using the 3D finite volume method. The model was used to simulate the liquid–solid phase transformation of a Fe-0.82wt%C steel alloy under the effect of both thermocapillary and buoyancy convections. The alloy was cooled in a rectangular ingot (100 × 100 × 10 mm3) from the bottom cold surface to the top hot free surface by applying a heat transfer coefficient of h = 600 W/m2/K, which allows for heat exchange with the outer medium. The purpose of this work is to study the effect of the surface tension on the flow and segregation patterns. The results before solidification show that Marangoni flow was formed at the free surface of the molten alloy, extending into the liquid depth and creating polygonized hexagonal patterns. The size and the number of these hexagons were found to be dependent on the Marangoni number, where the number of convective cells increases with the increase in the Marangoni number. During solidification, the solid front grew in a concave morphology, as the centers of the cells were hotter; a macro-segregation pattern with hexagonal cells was formed, which was analogous to the hexagonal flow cells generated by the Marangoni effect. After full solidification, the segregation was found to be in perfect hexagonal shapes with a strong compositional variation at the free surface. This study illuminates the crucial role of surface-tension-driven Marangoni flow in producing hexagonal patterns before and during the solidification process and provides valuable insights into the complex interplay between the Marangoni flow, buoyancy convection, and solidification phenomena. Full article
(This article belongs to the Special Issue Advances in Multicomponent Alloy Design, Simulation and Properties)
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