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Alloys and Composites: Structural and Functional Applications (Volume II)

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Metals and Alloys".

Deadline for manuscript submissions: 10 October 2024 | Viewed by 5644

Special Issue Editor


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Guest Editor
School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
Interests: amorphous alloys; relaxation and rejuvenation of amorphous materials; metal matrix composites; high-entropy alloys; porous alloys; high-temperature alloys
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Special Issue Information

Dear Colleagues,

According to the constituent phases in alloys and composites, materials can exhibit various performance characteristics, thus possessing great potential in different application cases, such as aeronautics and astronautics, the automobile industry, and the electronic and electrical industry. Alloys and composites with high stiffness, high strength, and good ductility can be used as load-bearing components, those with high hardness and ductility can be used as cutting tools, and those with high corrosion resistance can be used as components in seawater or in a chemical atmosphere environment, whereas the heating furnace needs both heating components with a high heat liberation rate, as well as heat insulation components to prevent heat loss.

The aim of this SI is to understand the basic principles of property design and tailoring in alloys and composites, to be used as structural or functional materials. The materials of interest include amorphous alloys, high-entropy alloys, lightweight alloys, metal–matrix composites, ceramic–matrix composites, and polymer–matrix composites. To design and tailor macroscopic properties as structural or functional materials, such as macroscopic stiffness and strength, the phase constituent, volume fraction, and average size of each phase, interface bonding should be well investigated. A thorough understanding of how the composition and processing parameters influence the macroscopic properties will definitely help toward new breakthroughs in the field of alloys and composites and their use in different cases.

Prof. Dr. Wei Guo
Guest Editor

Manuscript Submission Information

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Keywords

  • alloys and composites
  • mechanical properties
  • functional properties
  • phase constituent
  • design and tailoring
  • amorphous alloys
  • high-entropy alloys
  • lightweight alloys
  • metal matrix composites

Related Special Issue

Published Papers (6 papers)

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Research

16 pages, 3694 KiB  
Article
The {332}<113> Twinning Behavior of a Ti-15Mo Medical Alloy during Cyclic Deformation and Its Effect on Microstructure and Performance
by Tiewei Xu, Bingqing Sun, Shanshan Zhang, Yuancai Liu, Wei Sun, Ning Cui and Binjiang Lv
Materials 2024, 17(7), 1462; https://doi.org/10.3390/ma17071462 - 22 Mar 2024
Viewed by 406
Abstract
In this study, the microstructural evolution of a Ti-15Mo medical alloy was investigated, when the in situ cyclic tensile strain had 2% amplitude and the tension–compression cyclic deformation had 1%, 2%, and 3% amplitude. The Vickers hardness and wear resistance of the alloy [...] Read more.
In this study, the microstructural evolution of a Ti-15Mo medical alloy was investigated, when the in situ cyclic tensile strain had 2% amplitude and the tension–compression cyclic deformation had 1%, 2%, and 3% amplitude. The Vickers hardness and wear resistance of the alloy were also optimized due to the grain-refining effect after cyclic deformation and annealing. The twinning-induced plasticity (TWIP) was considered the main deformation mechanism of the Ti-15Mo alloy during the tensile–compressive cycle deformation with suitable strain amplitude. The {332}<113> twins and boundaries were the main contributors to the grain refinement. The optimal microstructure, hardness, and wear resistance were obtained in the alloy deformed by tension–compression cyclic strain with a 3% strain amplitude. The wear resistance of the annealed alloy in Hank’s solution was excellent in contrast to the original Ti-15Mo alloy due to its reasonable microstructure and hardness. It is clear that abundant twins were formed and retained in the coarse grains of the original alloy after cyclic deformation and annealing, which provided the expected refined grains and performance. Full article
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12 pages, 3422 KiB  
Article
Microstructure and Friction Properties of AlCrTiVNbx High-Entropy Alloys via Annealing Manufactured by Vacuum Arc Melting
by Baowei Li, Zihao Zhang, Xiaoling Luo, Kangmin Chen, Jiaqi Zhang, Pan Gong and Zhen Peng
Materials 2024, 17(4), 812; https://doi.org/10.3390/ma17040812 - 08 Feb 2024
Viewed by 683
Abstract
To enhance the friction and wear properties of alloys, AlCrTiVNbx high-entropy alloys (HEAs) with various Nb contents were prepared using the arc melting technique and then annealed at 1000 °C for 2 h. The microstructure and hardness changes in the AlCrTiVNbx [...] Read more.
To enhance the friction and wear properties of alloys, AlCrTiVNbx high-entropy alloys (HEAs) with various Nb contents were prepared using the arc melting technique and then annealed at 1000 °C for 2 h. The microstructure and hardness changes in the AlCrTiVNbx (x = 0.3, 0.4, and 0.5) HEAs after casting and annealing were studied via scanning electron microscopy, X-ray diffractometry, optical microscopy and the Vickers hardness test. The MFT-EC400 ball disc reciprocating friction and wear tester was used to investigate the wear resistance of the HEAs before and after annealing. The results show that the annealed AlCrTiVNbx HEAs changed from a single-phase structure to a multi-phase structure, and the content of the face-center cubic (FCC) phase and hexagonal close-packed (HCP) phase further increases with the increase in Nb content. The hardness value of the annealed HEAs is greatly enhanced compared with the casting state, and the hardness of the Nb0.5 HEA is increased from 543 HV to 725 HV after annealing. The wear resistance of the alloys after the annealing treatment is also greatly improved, among which Nb0.5 has the best wear resistance. The average friction coefficient of Nb0.5 is 0.154 and the wear rate is 2.117 × 10−5 mm3/(N·m). We believe that the precipitation strengthening after the annealing treatment and the lubrication effect of the FCC phase are the reasons for the significant improvement in wear resistance. The morphology of the samples indicates that the wear mechanism of the alloy includes adhesive wear, abrasive wear and a certain degree of oxidation wear. Full article
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8 pages, 6353 KiB  
Communication
ZrO2 Superhydrophobic Coating with an Excellent Corrosion Resistance and Stable Degradation Performance on Zr-Based Bulk Metallic Glass
by Ranfeng Wei, Rui Zheng, Chaojun Li, Wei Wang, Hao Zhang, Qijing Sun, Jingwang Lv, Guoyang Zhang, Li Liu and Xiangjin Zhao
Materials 2024, 17(1), 118; https://doi.org/10.3390/ma17010118 - 26 Dec 2023
Viewed by 591
Abstract
Photocatalysis is an energy-saving and high-efficiency green environmental technology. Because of its wide band gap and low light utilization, few studies have been conducted on ZrO2 used as a photocatalytic material. In this paper, a corrosion-resistant superhydrophobic ZrO2 coating was prepared [...] Read more.
Photocatalysis is an energy-saving and high-efficiency green environmental technology. Because of its wide band gap and low light utilization, few studies have been conducted on ZrO2 used as a photocatalytic material. In this paper, a corrosion-resistant superhydrophobic ZrO2 coating was prepared on the surface of Zr-based bulk metallic glass by electrochemical etching. This coating not only showed a better corrosion resistance and easier collection, but also presented a stable degradation performance when combined with H2O2; these characteristics are necessary for photocatalysts to survive under harsh environments. This study provides a new direction for designing superhydrophobic surfaces on bulk metallic glass that possess a functional performance. Full article
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18 pages, 4059 KiB  
Article
Recommendation of SLM Process Parameters Based on Analytic Hierarchy Process and Weighted Particle Swarm Optimization for High-Temperature Alloys
by Ze-Jun Zhang, Yuan-Jie Wu, Ze-Ming Wang, Xiao-Yuan Ji, Wei Guo, Dong-Jian Peng, Xian-Meng Tu, Sheng-Zhi Zhou, Huan-Qing Yang and Jian-Xin Zhou
Materials 2023, 16(16), 5656; https://doi.org/10.3390/ma16165656 - 17 Aug 2023
Cited by 1 | Viewed by 831
Abstract
Selective laser melting (SLM) of high-temperature alloys involves intricate interdependencies among key process parameters, such as laser power and scanning speed, affecting properties such as density and tensile strength. However, relying solely on experiential knowledge for process parameter design often hampers the precise [...] Read more.
Selective laser melting (SLM) of high-temperature alloys involves intricate interdependencies among key process parameters, such as laser power and scanning speed, affecting properties such as density and tensile strength. However, relying solely on experiential knowledge for process parameter design often hampers the precise attainment of target requirements. To address this challenge, we propose an innovative approach that integrates the analytic hierarchy process (AHP) and weighted particle swarm optimization (WPSO) to recommend SLM process parameters for high-temperature alloy fabrication. Our proposed AHP–WPSO model consists of three main steps. First, a comprehensive historical database is established, capturing the process parameters and performance metrics of high-temperature alloy SLM parts. Utilizing an AHP framework, we compute the performance similarity between target and historical cases, applying rational thresholds to identify analogous cases. When suitable analogs are elusive, the model seamlessly transitions to the second step. Here, the WPSO model optimizes and recommends process parameters according to target specifications. Lastly, our experimental validation of the GH4169 high-temperature alloy through SLM experiments corroborates the effectiveness of our AHP–WPSO model in making process parameter recommendations. The outcomes underscore the model’s high accuracy, attaining a recommendation precision of 99.81% and 96.32% when historical analogs are present and absent, respectively. This innovative approach offers a robust and reliable solution to the challenges posed in SLM process parameter optimization for high-temperature alloy applications. Full article
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20 pages, 8421 KiB  
Article
Study of Bond Formation in Ceramic and Composite Materials Ultrasonically Soldered with Bi–Ag–Mg-Type Solder
by Roman Kolenak, Tomas Melus, Jaromir Drapala, Peter Gogola and Matej Pasak
Materials 2023, 16(8), 2991; https://doi.org/10.3390/ma16082991 - 10 Apr 2023
Cited by 1 | Viewed by 1126
Abstract
This research aimed to study a Bi–Ag–Mg soldering alloy and the direct soldering of Al2O3 ceramics and Ni–SiC composites. Bi11Ag1Mg solder has a broad melting interval, which mainly depends on the silver and magnesium content. The solder starts to melt [...] Read more.
This research aimed to study a Bi–Ag–Mg soldering alloy and the direct soldering of Al2O3 ceramics and Ni–SiC composites. Bi11Ag1Mg solder has a broad melting interval, which mainly depends on the silver and magnesium content. The solder starts to melt at a temperature of 264 °C. Full fusion terminates at a temperature of 380 °C. The microstructure of the solder is formed by a bismuth matrix. The matrix contains segregated silver crystals and an Ag (Mg, Bi) phase. The average tensile strength of solder is 26.7 MPa. The boundary of the Al2O3/Bi11Ag1Mg joint is formed by the reaction of magnesium, which segregates in the vicinity of a boundary with a ceramic substrate. The thickness of the high-Mg reaction layer at the interface with the ceramic material was approximately 2 μm. The bond at the boundary of the Bi11Ag1Mg/Ni–SiC joint was formed due to the high silver content. At the boundary, there were also high contents of Bi and Ni, which suggests that there is a NiBi3 phase. The average shear strength of the combined Al2O3/Ni–SiC joint with Bi11Ag1Mg solder is 27 MPa. Full article
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19 pages, 5472 KiB  
Article
Optimization of Plating Process on Inner Wall of Metal Pipe and Research on Coating Performance
by Chenming Zhang, Yongfeng Li, Xiaochang Xu, Mingming Zhang, Haoyuan Leng and Bin Sun
Materials 2023, 16(7), 2800; https://doi.org/10.3390/ma16072800 - 31 Mar 2023
Cited by 2 | Viewed by 1475
Abstract
An innovative brush plating process for preparing coatings on the inner wall of metal pipes is proposed, which aims to solve the limitations of current electroplating technology and improve the performance of the inner walls of metal pipes. While optimizing the process, the [...] Read more.
An innovative brush plating process for preparing coatings on the inner wall of metal pipes is proposed, which aims to solve the limitations of current electroplating technology and improve the performance of the inner walls of metal pipes. While optimizing the process, the effect of working voltage on the microhardness, thickness, surface morphology, corrosion resistance, and elastoplasticity of the Ni coating on the inner wall of the tube was studied under the new process. The results indicate this technique can produce high-quality coatings on the inner wall of pipes in a simple and efficient manner. As the working voltage increases, the surface quality and comprehensive performance of the coating show an increasing trend followed by a decreasing trend. At 12 V, the coating exhibits the highest surface density and uniformity, the lowest surface roughness, the best corrosion resistance, and the maximum microhardness of 575.8 HV, with a corrosion current density of 1.040 × 10−5 A·cm−2, a corrosion rate of 0.122 mm·a−1, the maximum elastic recovery ratio he/hmax of 0.36, and the best deformation resistance. This study demonstrated the effectiveness of this method in improving the durability and functionality of metal pipes and its potential for various industrial applications. Full article
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