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Nanomaterials Based Electrodes for Supercapacitor Applications

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".

Deadline for manuscript submissions: closed (30 June 2023) | Viewed by 2477

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Guest Editor
Carbon Composite Energy Nanomaterials Research Center, Woosuk University, Wanju-gun, Chonbuk 55338, Republic of Korea
Interests: energy storage and conversion applications; wastewater treatment
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Owing to the massive consumption of fossil fuels and mushrooming environmental concerns, multifarious emerging energy sources has being explored, and it is thus urgent to design alternative and sustainable energy storage devices. Among the diverse of energy storage devices, supercapacitors have proclaimed much attention thanks to their fast charging capability, high power density, and ultra-long cycle life. Particularly, the hybrid supercapacitors (HSCs), as a typical supercapacitor, is starting to receive enormous attention from researchers due to its excellent energy density and high power density. Therefore, it is crucial to design and develop high specific capacitance and widened potential window based electrode materials. To date, various nanomaterials including transition metal based oxides, sulfides, selenides hydroxides, phosphides, conductive polymers etc. have been exploited as pseudocapacitive electrode materials, and these electrode materials operates via faradic reactions. On the other hand, carbon based electrode materials (carbon nanotubes, graphene, activated carbon etc.) are named as electric double layer capacitors (EDLCs) and store the charges through ion-adsorption at the electrode/electrolyte interface. Therefore, it is highly recommend to assemble the pseudocapacitive and EDLCs nanomaterials in a single frame to design and develop high-performance hybrid supercapacitors (HSCs) with high energy density and power density.

Dr. Ojha Gunendra Prasad
Guest Editor

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Keywords

  • supercapacitors
  • hybrid supercapacitors
  • energy density
  • power density
  • specific capacitance
  • pseudocapacitors
  • electric double layer capacitors (EDLCs)
  • nanomaterials
  • cyclic stability

Published Papers (1 paper)

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Research

16 pages, 5306 KiB  
Article
Nanoarchitectonics of Three-Dimensional Carbon Nanofiber-Supported Hollow Copper Sulfide Spheres for Asymmetric Supercapacitor Applications
by Miyeon Shin, Ganesh Prasad Awasthi, Krishna Prasad Sharma, Puran Pandey, Mira Park, Gunendra Prasad Ojha and Changho Yu
Int. J. Mol. Sci. 2023, 24(11), 9685; https://doi.org/10.3390/ijms24119685 - 02 Jun 2023
Cited by 6 | Viewed by 1527
Abstract
Three-dimensional carbon nanofiber (3D-CNF)-supported hollow copper sulfide (HCuS) spheres were synthesized by the facile hydrothermal method. The morphology of the as-synthesized HCuS@3D-CNF composite clearly revealed that the 3D-CNFs act as a basement for HCuS spheres. The electrochemical performance of as-synthesized HCuS@3D-CNFs was evaluated [...] Read more.
Three-dimensional carbon nanofiber (3D-CNF)-supported hollow copper sulfide (HCuS) spheres were synthesized by the facile hydrothermal method. The morphology of the as-synthesized HCuS@3D-CNF composite clearly revealed that the 3D-CNFs act as a basement for HCuS spheres. The electrochemical performance of as-synthesized HCuS@3D-CNFs was evaluated by cyclic voltammetry (CV) tests, gravimetric charge–discharge (GCD) tests, and Nyquist plots. The obtained results revealed that the HCuS@3D-CNFs exhibited greater areal capacitance (4.6 F/cm2) compared to bare HCuS (0.64 F/cm2) at a current density of 2 mA/cm2. Furthermore, HCuS@3D-CNFs retained excellent cyclic stability of 83.2% after 5000 cycles. The assembled asymmetric device (HCuS@3D-CNFs//BAC) exhibits an energy density of 0.15 mWh/cm2 with a working potential window of 1.5 V in KOH electrolyte. The obtained results demonstrate that HZnS@3D-CNF nanoarchitectonics is a potential electrode material for supercapacitor applications. Full article
(This article belongs to the Special Issue Nanomaterials Based Electrodes for Supercapacitor Applications)
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