Preparation and Photocatalytic Activity of TiO2-Based Composite Catalysts

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Photocatalysis".

Deadline for manuscript submissions: closed (30 December 2022) | Viewed by 6170

Special Issue Editor


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Guest Editor
College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
Interests: photocatalytic applications; titanium dioxide; composite catalyst

Special Issue Information

Dear Colleagues,

With the development of urbanization and the improvement of industrialization, modern industry has brought convenience and comfort to people, but it has also brought serious pollution problems. The discharge of waste water and exhaust gas has brought great harm to people’s living environment. Titanium dioxide has received extensive attention from scientists as a photocatalyst due to its photocatalytic degradation ability, environmental friendliness, and low price, and further advantages have been identified, such as its high chemical stability, low toxicity, and low operating cost. Titanium belongs to the N-order semiconductor material, while the band gap of titanium dioxide is 3.2eV. When titanium is irradiated by ultraviolet light whose wavelength is less than or equal to 387.5 nm, there is a photocatalytic effect, which is however limited by the high coupling probability of photogenerated carriers, and the photocatalytic efficiency of TiO2 is low. The most commonly used method to improve this photocatalytic efficiency is increasing its photoresponse range and reducing photo-generated carrier coupling. Through element doping, changing the morphology size and the construction of the heterojunction can make it improve its photocatalytic efficiency. In this issue, mainstream preparation methods of titanium dioxide are reviewed, and several suitable preparation schemes for improving the photocatalytic efficiency of titanium dioxide are introduced.

The main preparation methods of titanium dioxide are the sol–gel method, solvothermal method, hydrothermal method, anodic oxidation method, microwave-assisted method, CVD, PVD, etc. As titanium has a wide range of applications in harmful gas purification, building materials, coatings, daily necessities, and so on, titanium preparation and application have become one of the most popular research fields all around the world, and it is for this reason that we are launching this Special Issue dedicated to this topic. We look forward to your contributions.

Dr. Junjiao Yang
Guest Editor

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Keywords

  • titanium dioxide
  • titanium preparation
  • composite catalyst
  • photodegradation

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Review

39 pages, 8915 KiB  
Review
Preparation and Photocatalytic Activities of TiO2-Based Composite Catalysts
by Huaitao Yang, Beibei Yang, Wei Chen and Junjiao Yang
Catalysts 2022, 12(10), 1263; https://doi.org/10.3390/catal12101263 - 17 Oct 2022
Cited by 31 | Viewed by 5915
Abstract
While modern industry has contributed to the prosperity of an increasingly urbanized society, it has also led to serious pollution problems, with discharged wastewater and exhaust gases causing significant environmental harm. Titanium dioxide (TiO2), which is an excellent photocatalyst, has received [...] Read more.
While modern industry has contributed to the prosperity of an increasingly urbanized society, it has also led to serious pollution problems, with discharged wastewater and exhaust gases causing significant environmental harm. Titanium dioxide (TiO2), which is an excellent photocatalyst, has received extensive attention because it is inexpensive and able to photocatalytically degrade pollutants in an environmentally friendly manner. TiO2 has many advantages, including high chemical stability, low toxicity, low operating costs, and environmental friendliness. TiO2 is an N-order semiconductor material with a bandgap of 3.2 eV. Only when the wavelength of ultraviolet light is less than or equal to 387.5 nm, the valence band electrons can obtain the energy of the photon and pass through the conduction band to form photoelectrons, meanwhile the valence band forms a photogenerated hole. And light in other wavelength regions does not excite this photogenerated electrons. The most common methods used to improve the photocatalytic efficiency of TiO2 involve increasing its photoresponse range and reducing photogenerated-carrier coupling. The morphology, size, and structure of a heterojunction can be altered through element doping, leading to improved photocatalytic efficiency. Mainstream methods for preparing TiO2 are reviewed in this paper, with several excellent preparation schemes for improving the photocatalytic efficiency of TiO2 introduced. TiO2 is mainly prepared using sol-gel, solvothermal, hydrothermal, anodic oxidation, microwave-assisted, CVD and PVD methods, and TiO2 nanoparticles with excellent photocatalytic properties can also be prepared. Ti-containing materials are widely used to purify harmful gases, as well as contaminants from building materials, coatings, and daily necessities. Therefore, the preparation and applications of titanium materials have become globally popular research topics. Full article
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