Research Progress of Catalysts in Thermochemical Conversion of Biomass

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Chemical Processes and Systems".

Deadline for manuscript submissions: 20 June 2024 | Viewed by 528

Special Issue Editor


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Guest Editor
INCAPE—Catalysis and Petrochemistry Research Institute, Ruta Nacional 168, Santa Fe, Argentina
Interests: catalyst; pyrolysis; gasification; biomass; bio-oil; syn-gas; biochar; biorefinery

Special Issue Information

Dear Colleagues,

Thermochemical conversion is one of the most important methods for converting biomass into energy, fuels, and chemicals. Thermochemical conversion can be defined as the controlled heating or oxidation of biomass to generate energy, chemical, and/or calorific products. This definition includes several different techniques, the main ones being pyrolysis, liquefaction, and gasification. Thermochemical conversion techniques differ in their variety of conditions and the degree of control of both oxidation and heating.

It is important to note that the amount of potential energy available from a given biomass source is intrinsic, but depending on the thermochemical conversion technology used, more or less the actual amount of said energy will be recovered in different forms. In this sense, it is essential to advance scientific knowledge regarding the different conditions of biomass thermochemical conversion processes, the effect of the process parameters on the quantity and quality of the products obtained, the different biomasses that can be used as raw materials, as well as knowledge about new technologies or adaptations of existing ones. The different types of catalysts that can be used in the process and the effect of their incorporation into thermochemical processes, or as a subsequent stage the improvement in the products of these processes, are also of interest.

The use of catalysts in the thermochemical process itself, or in subsequent stages, allows for the quality of the products obtained to be improved; this is one of the most popular lines of scientific research on the subject today. This Special Issue, titled "Research Progress of Catalysts in Thermochemical Conversion of Biomass", aims to obtain a deeper insight into this topic and create a space in which new research on the topic can converge, allowing for the visualization of the importance of the valorization of biomass via thermochemical processes as an environmentally friendly alternative for the production of energy, fuels, and chemical products.

Suitable topics for this Special Issue include, but are not limited to, the following:

  • Studies on the operating conditions of thermochemical processes, including modeling, experimental, and exploratory studies whose conclusions are relevant;
  • Preparation and characterization of catalysts for use in biomass recovery processes or their derivative products obtained via thermochemical processes;
  • Studies on different biomasses used as raw materials in thermochemical processes;
  • Characterization of products derived from thermochemical biomass processes and their possibilities of use in different industrial areas;
  • Upgrading oproducts derived from thermochemical biomass processes;
  • Proposals for new processes and adaptation of existing ones to the current requirements in the matter.

Dr. Melisa Paola Bertero
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Processes is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • catalyst
  • pyrolysis
  • gasification
  • biomass
  • liquefaction
  • bio-oil
  • syn-gas
  • biochar
  • biorrefinery

Published Papers (1 paper)

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Research

27 pages, 6252 KiB  
Article
Characterization of Pyrolytic Tars Derived from Different Biomasses
by Paula Saires, Cindy Ariza Barraza, Melisa Bertero, Richard Pujro, Marisa Falco and Ulises Sedran
Processes 2024, 12(4), 817; https://doi.org/10.3390/pr12040817 - 18 Apr 2024
Viewed by 411
Abstract
The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 °C in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and [...] Read more.
The pyrolysis of three different biomasses, rice husk (RH), zoita wood sawdust (ZW) and pine wood sawdust (PW), was studied at 500 °C in a multipurpose unit at the bench scale to determine the yields of the different products and the compositions and properties of the liquid products, with particular emphasis given to the alquitranous fractions (tars). It was possible to link the characteristics of the tars with the compositions of the raw biomasses and verify their potential in various applications. The analytical techniques employed in the characterization of biomasses included lignin, celulose and hemicellulose analysis, ultimate and proximate analysis and thermogravimetry–mass spectrometry analysis (TG-MS). Elemental analysis, gas chromatography–mass spectrometry (GC-MS), nuclear magnetic resonance spectroscopy (1H NMR), Fourier transform infrared spectroscopy (FTIR) and size exclusion chromatography (SEC) were used to characterize the tars. The tar yields were 1.8, 7.4 and 4.0 %wt. in the cases of RH, ZW and PW, respectively. The tars showed higher carbon content, between 60.3 and 62.2 %wt., and lower oxygen content, between 28.8 and 31.6 %wt., than the corresponding raw biomasses. The main components of the tars had aromatic bases, with phenols representing more than 50%. Tar RH included more guaiacols, while Tars ZW and PW included more phenols and alkylated phenols. Full article
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