Advanced Nanoparticles: New Perspective in Catalysis

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Chemical Processes and Systems".

Deadline for manuscript submissions: 20 June 2024 | Viewed by 705

Special Issue Editors


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Guest Editor
Department of Environmental Science and Engineering, State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an 710049, China
Interests: environmental catalysis; air pollution control technology and functional nanomaterials
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Biomimetics & Nanostructured Materials Lab, University of California, Irvine, CA 92697, USA
Interests: catalysis; biomaterials; functional nanoparticles

Special Issue Information

Dear Colleagues,

With the global population steadily increasing each year and our reliance on non-renewable resources, particularly fossil fuels, persisting, the pursuit of chemical production guided by principles such as energy conservation, emission reduction, and environmental protection remains a paramount theme in sustainable social development. Catalytic reactions, constituting nearly 85% of various processes, play a pivotal role in achieving these goals. Their crucial functions include enhancing production conversion rates, reducing activation energy barriers in reactions, and minimizing the generation of industrial waste. Within the catalysis process, metal nanoparticles emerge as key players, significantly enhancing catalytic activity and selectivity and reducing reaction time. Heterogeneous catalysts, primarily based on noble metals, alloys, and their atomically dispersed forms, dominate the landscape. As such, the development of high-efficiency catalysts is essential to mitigate the scarcity and high costs associated with these noble metallic species. Understanding the catalytic process, where the interaction between the surface of nanoparticles and substrates dictates reaction rates and target product outcomes, is imperative. This necessitates the use of advanced characterization methods and equipment, such as in situ characterization, to monitor the morphology and catalytic active sites of the catalysts and optimize these catalytic processes.

In light of these considerations, this Special Issue, entitled "Advanced Nanoparticles: New Perspectives in Catalysis”, seeks to explore the influence of nanoparticles on catalytic reactions and the overarching strategies for optimizing catalytic processes. Additionally, we welcome contributions that delve into advanced characterization and simulation methods as indispensable tools in this field.

Suitable topics include, but are not limited to, the following:

  • Design and synthesis of catalysts;
  • Methods for nanoparticle characterization;
  • Optimization of parameters during the catalytic process;
  • In situ characterization (SEM, TEM, XRD, optical microscopy, AFM, Raman, etc.) of catalytic reactions;
  • Simulations of catalysis mechanisms;
  • Surface and interface chemistry in catalysis;
  • Stability and regeneration of catalysts;
  • Catalyst applications in energy conversion and storage.

Prof. Dr. Chi He
Dr. Haitao Yu
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Processes is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • catalysis
  • characterizaion
  • catalytic process
  • nanoparticles
  • in situ
  • active site
  • energy conversion
  • simulation

Published Papers (1 paper)

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Research

18 pages, 4383 KiB  
Article
Catalytic Acetone Oxidation over MnOx Catalysts: Regulating Their Crystal Structures and Surface Properties
by Bohang Cai, Fawei Lin, Xuan Guo and Yongtao Li
Processes 2024, 12(2), 326; https://doi.org/10.3390/pr12020326 - 02 Feb 2024
Viewed by 531
Abstract
This study investigates the catalytic oxidation of acetone by different crystal phases of MnO2 prepared via different methods. Compared with β-MnO2 and γ-MnO2, α-MnO2 exhibited superior catalytic activity. Moreover, as replacements for traditional hydrothermal methods and air calcination, [...] Read more.
This study investigates the catalytic oxidation of acetone by different crystal phases of MnO2 prepared via different methods. Compared with β-MnO2 and γ-MnO2, α-MnO2 exhibited superior catalytic activity. Moreover, as replacements for traditional hydrothermal methods and air calcination, the use of microwave hydrothermal methods and N2 calcination significantly enhanced the catalytic performance of the MnO2 catalyst. The optimal catalyst, MnO2-WN (α-MnO2 synthesized via microwave hydrothermal method and N2 calcination), converted 100% of 100 ppm acetone below 150 °C, with the CO2 yields reaching 100%. Further, the stability of the catalyst and its potential for other volatile organic compounds (VOCs) were also determined. The experimental data demonstrated that its outstanding activity primarily stemmed from the improved preparation method, enhancing the specific surface area of the catalyst, optimizing the pore structure, improving the redox performance, and generating more acidic sites and active oxygen species, thereby creating a synergistic effect. Finally, the reaction pathway of acetone oxidation on the catalyst surface has been explored. This work provides a new perspective for developing economically efficient MnOx catalysts for removing VOCs. Full article
(This article belongs to the Special Issue Advanced Nanoparticles: New Perspective in Catalysis)
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