Sustainable Development of Polymer Composites and Nanocomposites: Recent Advances and Future Perspective

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Composites and Nanocomposites".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 15527

Special Issue Editors


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Guest Editor
Department of Polymer Technology, Faculty of Chemistry, G. Narutowicza Str. 11/12, Gdańsk University of Technology, 80-233 Gdańsk, Poland
Interests: plastics and rubber recycling; reactive processing; composites; polymer blends and composites compatibilization; bitumen modification
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Guest Editor
Faculty of Chemical Engineering and Technology, Cracow University of Technology, 31-155 Cracow, Poland
Interests: bio-polyols based on vegetable and waste oils; polyurethane bio-foams; epoxydation of natural oils; porous polyurethane composites

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Guest Editor
Institute of Materials Technology, Faculty of Mechanical Engineering, Poznan University of Technology, Piotrowo 3, 61-138 Poznan, Poland
Interests: biocomposites; thermoplastics; extrusion; rheology
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Guest Editor
Division of Polymer Technology and Protective Coatings, Faculty of Chemical Technology and Engineering, UTP University of Science and Technology, Seminaryjna 3, 85-326 Bydgoszcz, Poland
Interests: polymer nanocomposites and biocomposites; carbon nanoparticles; poly(vinyl chloride), modification; thermal properties; recycling

Special Issue Information

Dear Colleagues,

The growing expectations and demand of industry for new sustainable polymers and their composites in recent decades have caused the dynamic development of biobased, biodegradable, and waste-based materials. Achieving materials with low environmental impact can be achieved not only by the appropriate selection of natural-based or valorized waste materials but also by the use of sustainable production technologies. This Special Issue includes a collection of original papers as well as reviews undertaking the search for prospective technologically and materially innovative solutions that can contribute to the development and stimulation of the creation of new potentially environmentally friendly materials with high application potential.

Selected example topics include:

- Manufacturing of polymeric materials based on natural origin waste products

- Production of fine polymers and composites based on sustainable materials

- Low-cost materials based on valorized waste fillers for application in developments of the products with high industrial output

- Recycling of thermoplastic and thermosets materials, including achievements in novel separation processes

- Novel methods of immiscible polymeric blends compatibilization 

- Achievements in production technologies with lowered environmental impact

Dr. Krzysztof Formela
Dr. Maria Kurańska
Dr. Mateusz Barczewski
Dr. Katarzyna Skórczewska
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • composites
  • nanocomposites environmentally-friendly materials
  • green technologies
  • matrix-filler interactions
  • compatibilization strategies
  • structure-property relationship

Published Papers (3 papers)

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Research

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10 pages, 2110 KiB  
Article
Bio-Polyurethane Foams Modified with a Mixture of Bio-Polyols of Different Chemical Structures
by Aleksander Prociak, Maria Kurańska, Katarzyna Uram and Monika Wójtowicz
Polymers 2021, 13(15), 2469; https://doi.org/10.3390/polym13152469 - 27 Jul 2021
Cited by 14 | Viewed by 1847
Abstract
We report on rigid polyurethane (PUR) foams prepared using different contents of a mixture of two bio-polyols (20–40 php). The bio-polyols were obtained through epoxidation and a ring opening reaction. Different chemical structures of the bio-polyols resulted from the use of 1-hexanol and [...] Read more.
We report on rigid polyurethane (PUR) foams prepared using different contents of a mixture of two bio-polyols (20–40 php). The bio-polyols were obtained through epoxidation and a ring opening reaction. Different chemical structures of the bio-polyols resulted from the use of 1-hexanol and 1,6-hexanediol as opening agents. The bio-polyols were characterized by hydroxyl values of 104 and 250 mgKOH/g and viscosities of 643 and 5128 mPa·s, respectively. Next, the influence of the bio-polyols on the foaming process of PUR systems as well as the foam properties was evaluated. The bio-foams modified with different contents of the bio-polyols were next compared with a reference foam obtained using a polyether petrochemical polyol. The effect of the apparent density reduction as a result of replacing the petrochemical polyol was minimized by decreasing the water content in the formulation. It was found that the modification of the recipe by changing the content of water, acting as a chemical foaming agent, did not affect the foaming process. However, the introduction of the bio-polyols mixture limited the reactivity of the systems by reducing the maximum temperature of the foaming process. The bio-materials with comparable apparent densities to that of the reference material were characterized by similar values of the thermal conductivity coefficient and a decrease in their mechanical strengths. A deterioration of mechanical properties was caused by the plasticization of the polyurethane matrices with the bio-polyols containing dangling chains. However, all materials were dimensionally stable at room temperature. Full article
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Review

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42 pages, 3433 KiB  
Review
Recent Advances in Development of Waste-Based Polymer Materials: A Review
by Krzysztof Formela, Maria Kurańska and Mateusz Barczewski
Polymers 2022, 14(5), 1050; https://doi.org/10.3390/polym14051050 - 06 Mar 2022
Cited by 23 | Viewed by 6937
Abstract
Limited petroleum sources, suitable law regulations, and higher awareness within society has caused sustainable development of manufacturing and recycling of polymer blends and composites to be gaining increasing attention. This work aims to report recent advances in the manufacturing of environmentally friendly and [...] Read more.
Limited petroleum sources, suitable law regulations, and higher awareness within society has caused sustainable development of manufacturing and recycling of polymer blends and composites to be gaining increasing attention. This work aims to report recent advances in the manufacturing of environmentally friendly and low-cost polymer materials based on post-production and post-consumer wastes. Sustainable development of three groups of materials: wood polymer composites, polyurethane foams, and rubber recycling products were comprehensively described. Special attention was focused on examples of industrially applicable technologies developed in Poland over the last five years. Moreover, current trends and limitations in the future “green” development of waste-based polymer materials were also discussed. Full article
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28 pages, 3442 KiB  
Review
Production and Surface Modification of Cellulose Bioproducts
by Sumedha Liyanage, Sanjit Acharya, Prakash Parajuli, Julia L. Shamshina and Noureddine Abidi
Polymers 2021, 13(19), 3433; https://doi.org/10.3390/polym13193433 - 07 Oct 2021
Cited by 38 | Viewed by 5567
Abstract
Petroleum-based synthetic plastics play an important role in our life. As the detrimental health and environmental effects of synthetic plastics continue to increase, the renewable, degradable and recyclable properties of cellulose make subsequent products the “preferred environmentally friendly” alternatives, with a small carbon [...] Read more.
Petroleum-based synthetic plastics play an important role in our life. As the detrimental health and environmental effects of synthetic plastics continue to increase, the renewable, degradable and recyclable properties of cellulose make subsequent products the “preferred environmentally friendly” alternatives, with a small carbon footprint. Despite the fact that the bioplastic industry is growing rapidly with many innovative discoveries, cellulose-based bioproducts in their natural state face challenges in replacing synthetic plastics. These challenges include scalability issues, high cost of production, and most importantly, limited functionality of cellulosic materials. However, in order for cellulosic materials to be able to compete with synthetic plastics, they must possess properties adequate for the end use and meet performance expectations. In this regard, surface modification of pre-made cellulosic materials preserves the chemical profile of cellulose, its mechanical properties, and biodegradability, while diversifying its possible applications. The review covers numerous techniques for surface functionalization of materials prepared from cellulose such as plasma treatment, surface grafting (including RDRP methods), and chemical vapor and atomic layer deposition techniques. The review also highlights purposeful development of new cellulosic architectures and their utilization, with a specific focus on cellulosic hydrogels, aerogels, beads, membranes, and nanomaterials. The judicious choice of material architecture combined with a specific surface functionalization method will allow us to take full advantage of the polymer’s biocompatibility and biodegradability and improve existing and target novel applications of cellulose, such as proteins and antibodies immobilization, enantiomers separation, and composites preparation. Full article
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