Research

13 pages, 2942 KiB

Open AccessArticle

A Semi-Dissolving Microneedle Patch Incorporating TEMPO-Oxidized Bacterial Cellulose Nanofibers for Enhanced Transdermal Delivery

by Ji Eun Song, Seung-Hyun Jun, Sun-Gyoo Park and Nae-Gyu Kang

Polymers 2020, 12(9), 1873; https://doi.org/10.3390/polym12091873 - 20 Aug 2020

Cited by 27 | Viewed by 5492

Abstract

Although dissolving microneedles have garnered considerable attention as transdermal delivery tools, insufficient drug loading remains a challenge owing to their small dimension. Herein, we report a one-step process of synthesizing semi-dissolving microneedle (SDMN) patches that enable effective transdermal drug delivery without loading drugs [...] Read more.

Although dissolving microneedles have garnered considerable attention as transdermal delivery tools, insufficient drug loading remains a challenge owing to their small dimension. Herein, we report a one-step process of synthesizing semi-dissolving microneedle (SDMN) patches that enable effective transdermal drug delivery without loading drugs themselves by introducing TEMPO-oxidized bacterial cellulose nanofibers (TOBCNs), which are well dispersed, while retaining their unique properties in the aqueous phase. The SDMN patch fabricated by the micro-molding of a TOBCN/hydrophilic biopolymer mixture had a two-layer structure comprising a water-soluble needle layer and a TOBCN-containing insoluble backing layer. Moreover, the SDMN patch, which had a hole in the backing layer where TOBCNs are distributed uniformly, could offer novel advantages for the delivery of large quantities of active ingredients. In vitro permeation analysis confirmed that TOBCNs with high water absorption capacity could serve as drug reservoirs. Upon SDMN insertion and the application of drug aqueous solution through the drug inlet hole, the TOBCNs rapidly absorbed the solution and supplied it to the needle layer. Simultaneously, the needle layer dissolved in body fluids and the drug solution to form micro-channels, which enabled the delivery of larger quantities of drugs to the skin compared to that enabled by solution application alone. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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17 pages, 4279 KiB

Open AccessArticle

Poly(Glycerol Succinate) as an Eco-Friendly Component of PLLA and PLCL Fibres towards Medical Applications

by Dorota Kolbuk, Oliwia Jeznach, Michał Wrzecionek and Agnieszka Gadomska-Gajadhur

Polymers 2020, 12(8), 1731; https://doi.org/10.3390/polym12081731 - 03 Aug 2020

Cited by 24 | Viewed by 5603

Abstract

This study was conducted as a first step in obtaining eco-friendly fibres for medical applications using a synthesised oligomer poly(glycerol succinate) (PGSu) as an additive for synthetic poly(L-lactic acid) (PLLA) and poly (L-lactide-co-caprolactone) (PLCL). The effects of the oligomer on the structure formation, [...] Read more.

This study was conducted as a first step in obtaining eco-friendly fibres for medical applications using a synthesised oligomer poly(glycerol succinate) (PGSu) as an additive for synthetic poly(L-lactic acid) (PLLA) and poly (L-lactide-co-caprolactone) (PLCL). The effects of the oligomer on the structure formation, morphology, crystallisation behaviour, and mechanical properties of electrospun bicomponent fibres were investigated. Nonwovens were investigated by means of scanning electron microscopy (SEM), wide angle X-ray scattering (WAXS), differential scanning calorimetry (DSC), and mechanical testing. The molecular structure of PLLA fibres is influenced by the presence of PGSu mainly acting as an enhancer of molecular orientation. In the case of semicrystalline PLCL, chain mobility was enhanced by the presence of PGSu molecules, and the crystallinity of bicomponent fibres increased in relation to that of pure PLCL. The mechanical properties of bicomponent fibres were influenced by the level of PGSu present and the extent of crystal formation of the main component. An in vitro study conducted using L929 cells confirmed the biocompatible character of all bicomponent fibres. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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15 pages, 5019 KiB

Open AccessArticle

Effect of Cellulose Nanocrystals and Lignin Nanoparticles on Mechanical, Antioxidant and Water Vapour Barrier Properties of Glutaraldehyde Crosslinked PVA Films

by Weijun Yang, Guochuang Qi, José Maria Kenny, Debora Puglia and Piming Ma

Polymers 2020, 12(6), 1364; https://doi.org/10.3390/polym12061364 - 17 Jun 2020

Cited by 90 | Viewed by 7821

Abstract

In this work, PVA nanocomposite films containing cellulose nanocrystals (CNC) and different amounts of lignin nanoparticles (LNP), prepared via a facile solvent cast method, were crosslinked by adding glutaraldehyde (GD). The primary objective was to investigate the effects of crosslinker and bio-based nanofillers [...] Read more.

In this work, PVA nanocomposite films containing cellulose nanocrystals (CNC) and different amounts of lignin nanoparticles (LNP), prepared via a facile solvent cast method, were crosslinked by adding glutaraldehyde (GD). The primary objective was to investigate the effects of crosslinker and bio-based nanofillers loading on thermal, mechanical, antioxidant and water barrier behaviour of PVA nanocomposite films for active food packaging. Thermogravimetric analysis showed improved thermal stability, due to the strong interactions between LNP, CNC and PVA in the presence of GD, while Wide-angle X-ray diffraction results confirmed a negative effect on crystallinity, due to enhanced crosslinking interactions between the nanofillers and PVA matrix. Meanwhile, the tensile strength of PVA-2CNC-1LNP increased from 26 for neat PVA to 35.4 MPa, without sacrificing the ductility, which could be explained by a sacrificial hydrogen bond reinforcing mechanism induced by spherical-like LNP. UV irradiation shielding effect was detected for LNP containing PVA films, also migrating ingredients from PVA nanocomposite films induced radical scavenging activity (RSA) in the produced films in presence of LNP. Furthermore, PVA-CNC-LNP films crosslinked by GD showed marked barrier ability to water vapour. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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13 pages, 2254 KiB

Open AccessArticle

Thermal and Mechanical Properties of the Biocomposites of Miscanthus Biocarbon and Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) (PHBV)

by Zonglin Li, Christoff Reimer, Tao Wang, Amar K. Mohanty and Manjusri Misra

Polymers 2020, 12(6), 1300; https://doi.org/10.3390/polym12061300 - 06 Jun 2020

Cited by 41 | Viewed by 4810

Abstract

Miscanthus biocarbon (MB), a renewable resource-based, carbon-rich material, was melt-processed with poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) to produce sustainable biocomposites. The addition of the biocarbon improved the Young’s modulus of PHBV from 3.6 to 5.2 GPa at 30 wt % filler loading. An [...] Read more.

Miscanthus biocarbon (MB), a renewable resource-based, carbon-rich material, was melt-processed with poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) to produce sustainable biocomposites. The addition of the biocarbon improved the Young’s modulus of PHBV from 3.6 to 5.2 GPa at 30 wt % filler loading. An increase in flexural modulus, up to 48%, was also observed. On the other hand, the strength, elongation-at-break and impact strength decreased. Morphological study of the impact-fractured surfaces showed weak interaction at the interface and the existence of voids and agglomerates, especially with high filler contents. The thermal stability of the PHBV/MB composites was slightly reduced compared with the neat PHBV. The biocarbon particles were not found to have a nucleating effect on the polymer. The degradation of PHBV and the formation of unstable imperfect crystals were revealed by differential scanning calorimetry (DSC) analysis. Higher filler contents resulted in reduced crystallinity, indicating more pronounced effect on polymer chain mobility restriction. With the addition of 30 wt % biocarbon, the heat deflection temperature (HDT) became 13 degrees higher and the coefficient of linear thermal expansion (CLTE) decreased from 100.6 to 75.6 μm/(m·°C), desired improvement for practical applications. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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11 pages, 3775 KiB

Open AccessArticle

Mechanical Properties of a Soy Protein Isolate–Grafted–Acrylate (SGA) Copolymer Used for Wood Coatings

by Bin Feng, Di Wang, Yuhui Li, Junpeng Qian, Chenlei Yu, Mingsi Wang, Danni Luo and Shuangying Wei

Polymers 2020, 12(5), 1137; https://doi.org/10.3390/polym12051137 - 15 May 2020

Cited by 8 | Viewed by 3204

Abstract

Changing demands have led to rapidly growing interest in the modification of waterborne wood coatings. To improve the performance of a polyacrylate wood coating, especially the strength, hardness, and abrasion resistance of the film, a soy protein isolate–grafted–acrylate (SGA) copolymer was prepared in [...] Read more.

Changing demands have led to rapidly growing interest in the modification of waterborne wood coatings. To improve the performance of a polyacrylate wood coating, especially the strength, hardness, and abrasion resistance of the film, a soy protein isolate–grafted–acrylate (SGA) copolymer was prepared in an aqueous solution with ammonium persulfate (APS) as an initiator and sodium pyrosulfite (SPS) as an unfolding agent for the soybean protein isolate (SPI). The emulsion was characterized using transmission electron microscopy, Fourier-transform infrared spectroscopy (FTIR), and a particle size analyzer. Furthermore, the mechanical properties of the film, including the tensile strength, elastic modulus, elongation at break, and pencil hardness, were measured. The results showed that the glass transition temperature of the polyacrylic resin decreased to 35 °C after the SPI grafting. The elastic modulus of the film increased from 0.317 to 46.949 MPa, and the elongation at break decreased from 453.133% to 187.125% as the addition of SPI varied from 0 to 4 g, respectively. The pencil hardness of the wood coating increased from HB to 3H. This paper proposes a feasible route for the utilization of SPI for wood coatings. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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14 pages, 4945 KiB

Open AccessArticle

3D Printed Laminated CaCO₃-Nanocellulose Films as Controlled-Release 5-Fluorouracil

by Denesh Mohan, Nur Fatin Khairullah, Yan Ping How, Mohd Shaiful Sajab and Hatika Kaco

Polymers 2020, 12(4), 986; https://doi.org/10.3390/polym12040986 - 23 Apr 2020

Cited by 25 | Viewed by 3603

Abstract

Drug delivery constitutes the formulations, technologies, and systems for the transport of pharmaceutical compounds to specific areas in the body to exert safe therapeutic effects. The main criteria for selecting the correct medium for drug delivery are the quantity of the drug being [...] Read more.

Drug delivery constitutes the formulations, technologies, and systems for the transport of pharmaceutical compounds to specific areas in the body to exert safe therapeutic effects. The main criteria for selecting the correct medium for drug delivery are the quantity of the drug being carried and the amount of time required to release the drug. Hence, this research aimed to improve the aforementioned criteria by synthesizing a medium based on calcium carbonate-nanocellulose composite and evaluating its efficiency as a medium for drug delivery. Specifically, the efficiency was assessed in terms of the rates of uptake and release of 5-fluorouracil. Through the evaluation of the morphological and chemical properties of the synthesized composite, the established 3D printing profiles of nanocellulose and CaCO₃ took place following the layer-by-layer films. The 3D printed double laminated CaCO₃-nanocellulose managed to release the 5-fluorouracil as an effective single composition and in a time-controlled manner. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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13 pages, 6226 KiB

Open AccessArticle

Cellulose Nanocrystals Derived from Textile Waste through Acid Hydrolysis and Oxidation as Reinforcing Agent of Soy Protein Film

by Shuting Huang, Ran Tao, Ashraf Ismail and Yixiang Wang

Polymers 2020, 12(4), 958; https://doi.org/10.3390/polym12040958 - 20 Apr 2020

Cited by 41 | Viewed by 4778

Abstract

More than 10 million tons of textile waste are disposed through landfill every year in North America. The disposal of textile waste via landfill or incineration causes environmental problems and represents a waste of useful resources. In this work, we explored the possibility [...] Read more.

More than 10 million tons of textile waste are disposed through landfill every year in North America. The disposal of textile waste via landfill or incineration causes environmental problems and represents a waste of useful resources. In this work, we explored the possibility to directly extract cellulose nanocrystals (CNCs) from untreated textile waste through two methods, namely sulfuric acid hydrolysis and three-step oxidization. CNCs with cellulose I_β crystalline structure and rod-like shape were successfully obtained. The aspect ratios of CNCs prepared from acid hydrolysis and oxidization were 10.00 ± 3.39 and 17.10 ± 12.85, respectively. Their application as reinforcing agent of soybean protein isolate (SPI) film was evaluated. With the addition of 20% CNCs, the composite film maintained the high transparency, while their water vapor barrier property, tensile strength, and Young’s modulus were significantly improved. This research demonstrates a promising approach to recycle textile waste, and more value-added applications based on the derived CNCs could be expected. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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10 pages, 1931 KiB

Open AccessArticle

An Eco-Effective Soybean Meal-Based Adhesive Enhanced with Diglycidyl Resorcinol Ether

by Jing Luo, Ying Zhou, Yi Zhang, Qiang Gao and Jianzhang Li

Polymers 2020, 12(4), 954; https://doi.org/10.3390/polym12040954 - 20 Apr 2020

Cited by 14 | Viewed by 2892

Abstract

Soybean meal-based adhesive is a good wood adhesive mainly due to its renewable, degradable, and environmentally friendly features. To improve the enhancement efficiency for adhesives, diglycidyl resorcinol ether (DRE) containing a benzene ring and flexible chain structure was used as an efficient cross-linker [...] Read more.

Soybean meal-based adhesive is a good wood adhesive mainly due to its renewable, degradable, and environmentally friendly features. To improve the enhancement efficiency for adhesives, diglycidyl resorcinol ether (DRE) containing a benzene ring and flexible chain structure was used as an efficient cross-linker to enhance the adhesive in the study. The physicochemical properties of adhesives, the dry shear strength, and wet shear strength of plywood were measured. Results suggested that DRE reacted with the functional groups of soybean meal adhesive and formed a cross-linking network during hot press process in a ring-opening reaction through a covalent bond. As expected, compared to adhesive control, the soybean meal adhesive with 4 wt% DRE incorporation showed a significant increment in wet shear strength by 227.8% and in dry shear strength by 82.7%. In short, soybean meal adhesive enhanced with DRE showed considerable potential as a wood adhesive for industrial applications. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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11 pages, 2719 KiB

Open AccessArticle

Preparation of Biomass-Based Ester End-Capped Hyperbranched Poly(ether)s via Facile One-Pot Reaction and Their Performance as Non-Toxic Plasticizers

by Qiaoguang Li, Xugang Shu, Puyou Jia and Yonghong Zhou

Polymers 2020, 12(4), 913; https://doi.org/10.3390/polym12040913 - 15 Apr 2020

Cited by 13 | Viewed by 3081

Abstract

The aim of this study was to develop a facile one-pot reaction for the synthesis of biomass-based hyperbranched poly(ether)s end-capped as acetate esters (BHE) for use as a sustainable, safe and feasible plasticizer for flexible poly(vinyl chloride) (PVC) materials. BHE is completely miscible [...] Read more.

The aim of this study was to develop a facile one-pot reaction for the synthesis of biomass-based hyperbranched poly(ether)s end-capped as acetate esters (BHE) for use as a sustainable, safe and feasible plasticizer for flexible poly(vinyl chloride) (PVC) materials. BHE is completely miscible with PVC but shows weaker plasticizing effect than dioctyl phthalate (DOP) (EΔTg value of BHE reaches 64.8%). PVC plasticized with BHE displays greater thermal stability than that of PVC or PVC plasticized with DOP materials. BHE improves the thermal stability and flexibility of PVC materials. As a plasticizer, BHE displays lower solvent extractability and greater volatilization resistance than DOP. Acute oral toxicity indicates that BHE has toxic doses of 5 g/kg, suggesting that BHE is non-toxic. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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12 pages, 5681 KiB

Open AccessArticle

Study on the Properties of Transparent Bamboo Prepared by Epoxy Resin Impregnation

by Yan Wu, Yajing Wang, Feng Yang, Jing Wang and Xuehua Wang

Polymers 2020, 12(4), 863; https://doi.org/10.3390/polym12040863 - 09 Apr 2020

Cited by 38 | Viewed by 5545

Abstract

In this paper, Moso bamboo (Phyllostachys heterocycle) before and after heat treatment were used as raw materials to prepare transparent bamboo (TB). In an acidic environment, the lignin contained in the bamboo material was removed to obtain a bamboo template, and [...] Read more.

In this paper, Moso bamboo (Phyllostachys heterocycle) before and after heat treatment were used as raw materials to prepare transparent bamboo (TB). In an acidic environment, the lignin contained in the bamboo material was removed to obtain a bamboo template, and an epoxy resin similar to the cellulose refractive index was used for vacuum impregnation into the bamboo template to obtain a transparent bamboo material. The purpose of this study was to compare the physical and chemical properties of TB and original bamboo and the differences between TBs before and after heat treatment, taken from different parts of bamboo, in order to explore the performance advantages and disadvantages of TB as a new material. The Fourier transform infrared spectroscopy analysis (FTIR), scanning electron microscope testing (SEM), three elements analysis, light transmittance testing, and mechanical strength testing were used to study the molecular composition, microstructure, chemical composition, light transmittance, and tensile strength of the TB samples. The results showed that the lignin content of the delignified bamboo templates was greatly reduced. In addition, the SEM images showed that a large amount of epoxy resin (type E51 and type B210 curing agent) was covered on the cross-section surface and pores of the TB samples. The FTIR showed that the epoxy molecular groups appeared on the TB, and the delignified bamboo template and the resin had a good synergy effect. According to the light transmittance testing, the original bamboo samples hardly contained light transmittance under visible light. The transmittance of transparent inner bamboo (TIB) and transparent heat-treated inner bamboo (THIB) could reach about 11%, and the transmittance of transparent outer bamboo (TOB) and transparent heat-treated outer bamboo (THOB) was about 2%. The light transmittance had been significantly improved when compared with the original bamboo samples. The transmittances of the TB samples before and after heat treatment in different parts of bamboo were different. In the visible light irradiation range, the light transmittances of TB samples were as follows: TIB > THIB and THOB > TOB. Meanwhile, the tensile strength of TB was reduced, especially for TOB and THOB. In addition, TB has a wide range of raw materials, and the preparation process is environmentally friendly. It can be used for decorative materials in homes, buildings, etc., and has a great application potential. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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13 pages, 3766 KiB

Open AccessArticle

Bio-Based Aromatic Copolyesters: Influence of Chemical Microstructures on Thermal and Crystalline Properties

by Keling Hu

Polymers 2020, 12(4), 829; https://doi.org/10.3390/polym12040829 - 05 Apr 2020

Cited by 4 | Viewed by 2822

Abstract

Aromatic copolyesters, derived from bio-based nipagin and eugenol, were synthesized with renewable 1,6-hexandiol as the spacer. Number-average, weight-average molecular weights (M_n, M_w), and polydispersity (D) values were determined by size exclusion chromatography (SEC). Chemical structures were [...] Read more.

Aromatic copolyesters, derived from bio-based nipagin and eugenol, were synthesized with renewable 1,6-hexandiol as the spacer. Number-average, weight-average molecular weights (M_n, M_w), and polydispersity (D) values were determined by size exclusion chromatography (SEC). Chemical structures were confirmed by ¹H NMR and ¹³C NMR spectroscopies. Chemical microstructure analysis suggested that the nipagin and eugenol-derived units were inserted into polymer chains in an arbitrary manner. Due to the short chain of 1,6-hexanediol, the splitting of magnetically different methylene carbons, adjacent to the alcohol-oxygens, proved to be more sensitive towards sequence distributions, at the dyed level, than those from 1,10-decanediol. Thermal gravimetric analysis (TGA) demonstrated that these polyester materials have excellent thermal stability (>360 °C), regardless of the content of eugenol-derived composition incorporated. Differential scanning calorimetric (DSC) and wide-angle X-ray diffraction (WXRD) experiments revealed the semicrystalline nature for this kind of copolyesters. The crystallinities gradually decreased with the increase of eugenol-derived composition. Thermal and crystalline properties were well discussed from the microscopic perspective. The point of this work lies in establishing guidance for future design and modification of high-performance polymer materials from the microscopic perspective. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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13 pages, 3439 KiB

Open AccessEditor’s ChoiceArticle

Tensile Mechanical Behaviour of Multi-Polymer Sandwich Structures via Fused Deposition Modelling

by David Moises Baca Lopez and Rafiq Ahmad

Polymers 2020, 12(3), 651; https://doi.org/10.3390/polym12030651 - 12 Mar 2020

Cited by 55 | Viewed by 6959

Abstract

The application of single homogeneous materials produced through the fused deposition modelling (FDM) technology restricts the production of high-level multi-material components. The fabrication of a sandwich-structured specimen with different material combinations using conventional thermoplastics such as poly (lactic acid) (PLA), acrylonitrile butadiene styrene [...] Read more.

The application of single homogeneous materials produced through the fused deposition modelling (FDM) technology restricts the production of high-level multi-material components. The fabrication of a sandwich-structured specimen with different material combinations using conventional thermoplastics such as poly (lactic acid) (PLA), acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) through the filament-based extrusion process can demonstrate an improvement on its properties. This paper aims to assess among these materials, the best material sandwich-structured arrangement design, to enhance the mechanical properties of a part and to compare the results with the homogeneous materials selected. The samples were subjected to tensile testing to identify the tensile strength, elongation at break and Young’s modulus of each material combination. The experimental results demonstrate that applying the PLA-ABS-PLA sandwich arrangement leads to the best mechanical properties between these materials. This study enables users to consider sandwich structure designs as an alternative to manufacturing multi-material components using conventional and low-cost materials. Future work will consider the flexural tests to identify the maximum stresses and bending forces under pressure. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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23 pages, 6747 KiB

Open AccessArticle

Concurrent Modelling and Experimental Investigation of Material Properties and Geometries Produced by Projection Microstereolithography

by Khaled G. Mostafa, Muhammad Arshad, Aman Ullah, David S. Nobes and Ahmed Jawad Qureshi

Polymers 2020, 12(3), 506; https://doi.org/10.3390/polym12030506 - 26 Feb 2020

Cited by 14 | Viewed by 3251

Abstract

Projection microstereolithography additive manufacturing (PµSLA-AM) systems utilize free radical photopolymerization to selectively transform liquid resins into accurate and complex, shaped, solid parts upon UV light exposure. The material properties are coupled with geometrical accuracy, implying that optimizing one response will affect the other. [...] Read more.

Projection microstereolithography additive manufacturing (PµSLA-AM) systems utilize free radical photopolymerization to selectively transform liquid resins into accurate and complex, shaped, solid parts upon UV light exposure. The material properties are coupled with geometrical accuracy, implying that optimizing one response will affect the other. Material properties can be enhanced by the post-curing process, while geometry is controlled during manufacturing. This paper uses designed experiments and analytical curing models concurrently to investigate the effects of process parameters on the green material properties (after manufacturing and before applying post curing), and the geometrical accuracy of the manufactured parts. It also presents a novel accumulated energy model that considers the light absorbance of the liquid resin and solid polymer. An essential definition, named the irradiance affected zone (IAZ), is introduced to estimate the accumulated energy for each layer and to assess the feasibility of the geometries. Innovative methodologies are used to minimize the effect of irradiance irregularities on the responses and to characterize the light absorbance of liquid and cured resin. Analogous to the working curve, an empirical model is proposed to define the critical energies required to start developing the different material properties. The results of this study can be used to develop an appropriate curing scheme, to approximate an initial solution and to define constraints for projection microstereolithography geometry optimization algorithms. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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20 pages, 4319 KiB

Open AccessArticle

Microstructure and Mechanical/Elastic Performance of Biobased Poly (Butylene Furanoate)–Block–Poly (Ethylene Oxide) Copolymers: Effect of the Flexible Segment Length

by Magdalena Kwiatkowska, Inez Kowalczyk, Konrad Kwiatkowski and Agata Zubkiewicz

Polymers 2020, 12(2), 271; https://doi.org/10.3390/polym12020271 - 28 Jan 2020

Cited by 12 | Viewed by 3140

Abstract

The aim of this paper is to extend knowledge on biobased poly(butylene furanoate)–block–poly (ethylene oxide) (PBF-b-PEO) copolymers’ performance by studying the effect of the PEO segment’s molecular weight on the microstructure and materials behavior. As crystallization ability of PEO depends on [...] Read more.

The aim of this paper is to extend knowledge on biobased poly(butylene furanoate)–block–poly (ethylene oxide) (PBF-b-PEO) copolymers’ performance by studying the effect of the PEO segment’s molecular weight on the microstructure and materials behavior. As crystallization ability of PEO depends on its molecular weight, the idea was to use two PEO segment lengths, expecting that the longer one would be able to crystallize affecting the phase separation in copolymers, thus affecting their mechanical performance, including elasticity. Two series of PBF-block-PEOs with the PEO segments of 1000 and 2000 g/mol and different PBF/PEO segment ratios were synthesized by polycondensation in melt, injection molded to confirm their processability, and subjected to characterization by NMR, FTIR, DSC, DMTA, WAXS, TGA, and mechanical parameters. Indeed, the PEO2000 segment not only supported the crystallization of the PBF segments in copolymers, but at contents at least 50 wt % is getting crystallizable in the low temperature range, which results in the microstructure development and affects the mechanical properties. While the improvement in the phase separation slightly reduces the copolymers’ ability to deformation, it is beneficial for the elastic recovery of the materials. The investigations were performed on the injection molded samples reflecting the macroscopic properties of the bulk materials. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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17 pages, 2391 KiB

Open AccessArticle

Evaluation of Different Methods for Cultivating Gluconacetobacter hansenii for Bacterial Cellulose and Montmorillonite Biocomposite Production: Wound-Dressing Applications

by Katharine Valéria Saraiva Hodel, Larissa Moraes dos Santos Fonseca, Isa Moreira da Silva Santos, Jamile Costa Cerqueira, Raimundo Evangelista dos Santos-Júnior, Silmar Baptista Nunes, Josiane Dantas Viana Barbosa and Bruna Aparecida Souza Machado

Polymers 2020, 12(2), 267; https://doi.org/10.3390/polym12020267 - 26 Jan 2020

Cited by 21 | Viewed by 3576

Abstract

Bacterial cellulose (BC) has received considerable attention due to its unique properties, including an ultrafine network structure with high purity, mechanical strength, inherent biodegradability, biocompatibility, high water-holding capacity and high crystallinity. These properties allow BC to be used in biomedical and industrial applications, [...] Read more.

Bacterial cellulose (BC) has received considerable attention due to its unique properties, including an ultrafine network structure with high purity, mechanical strength, inherent biodegradability, biocompatibility, high water-holding capacity and high crystallinity. These properties allow BC to be used in biomedical and industrial applications, such as medical product. This research investigated the production of BC by Gluconacetobacter hansenii ATCC 23769 using different carbon sources (glucose, mannitol, sucrose and xylose) at two different concentrations (25 and 50 g∙L⁻¹). The BC produced was used to develop a biocomposite with montmorillonite (MMT), a clay mineral that possesses interesting characteristics for enhancing BC physical-chemical properties, at 0.5, 1, 2 and 3% concentrations. The resulting biocomposites were characterized in terms of their physical and barrier properties, morphologies, water-uptake capacities, and thermal stabilities. Our results show that bacteria presented higher BC yields in media with higher glucose concentrations (50 g∙L⁻¹) after a 14-day incubation period. Additionally, the incorporation of MMT significantly improved the mechanical and thermal properties of the BC membranes. The degradation temperature of the composites was extended, and a decrease in the water holding capacity (WHC) and an improvement in the water release rate (WRR) were noted. Determining a cost-effective medium for the production of BC and the characterization of the produced composites are extremely important for the biomedical applications of BC, such as in wound dressing materials. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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16 pages, 4391 KiB

Open AccessArticle

Synthesis and Properties of Thermosets from Tung Oil and Furfuryl Methacrylate

by Sunanda Sain, Dan Åkesson and Mikael Skrifvars

Polymers 2020, 12(2), 258; https://doi.org/10.3390/polym12020258 - 22 Jan 2020

Cited by 14 | Viewed by 3789

Abstract

This work focuses on the development of cross-linked polymer from a highly unsaturated vegetable oil, tung oil (TO) and a bio-based acrylate, furfuryl methacrylate (FMA). The presence of a high degree of unsaturated carbon-carbon bonding in TO makes it a suitable precursor for [...] Read more.

This work focuses on the development of cross-linked polymer from a highly unsaturated vegetable oil, tung oil (TO) and a bio-based acrylate, furfuryl methacrylate (FMA). The presence of a high degree of unsaturated carbon-carbon bonding in TO makes it a suitable precursor for polymer synthesis. Using this advantage of TO, in this work, we have synthesised a cross-linked polymer from TO and FMA through free radical polymerisation followed by Diels–Alder (DA) reaction. Successful incorporation of both of the raw materials and the two chemical reactions was shown using Fourier-transform infrared (FTIR) and Raman spectroscopy. The development of cross-linked structure was analysed through thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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17 pages, 4491 KiB

Open AccessArticle

Construction of Polymer Electrolyte Based on Soybean Protein Isolate and Hydroxyethyl Cellulose for a Flexible Solid-State Supercapacitor

by Zhiyu Xun, Shoupeng Ni, Zhenhua Gao, Yanhua Zhang, Jiyou Gu and Pengfei Huo

Polymers 2019, 11(11), 1895; https://doi.org/10.3390/polym11111895 - 17 Nov 2019

Cited by 27 | Viewed by 4345

Abstract

Supercapacitors are a very active research topic. However, liquid electrolytes present several drawbacks on security and packaging. Herein, a gel polymer electrolyte was prepared based on crosslinked renewable and environmentally friendly soybean protein isolate (SPI) and hydroxyethyl cellulose (HEC) with 1.0 mol L [...] Read more.

Supercapacitors are a very active research topic. However, liquid electrolytes present several drawbacks on security and packaging. Herein, a gel polymer electrolyte was prepared based on crosslinked renewable and environmentally friendly soybean protein isolate (SPI) and hydroxyethyl cellulose (HEC) with 1.0 mol L⁻¹ Li₂SO₄. Highly hydrophilic SPI and HEC guaranteed a high ionic conductivity of 8.40 × 10⁻³ S cm⁻¹. The fabricated solid-state supercapacitor with prepared gel polymer electrolyte exhibited a good electrochemical performance, that is, a high single electrode gravimetric capacitance of 91.79 F g⁻¹ and an energy density of 7.17 W h kg⁻¹ at a current density of 5.0 A g⁻¹. The fabricated supercapacitor exhibited a flexible performance under bending condition superior to liquid supercapacitor and similar electrochemical performance at various bending angles. In addition, it was proved by an almost 100% cycling retention and a coulombic efficiency over 5000 charge–discharge cycles. For comparison, supercapacitors assembled with commercial aqueous PP/PE separator, pure SPI membrane, and crosslinked SPI membrane were also characterized. The obtained gel polymer electrolyte based on crosslinked SPI and HEC may be useful for the design of advanced polymer electrolytes for energy devices. Full article

(This article belongs to the Special Issue Bio-Based Polymers: Synthesis and Properties)

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