Metal, and Alloys Based Thin Films and Nanocomposites: Synthesis and Applications

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Nanocomposite Materials".

Deadline for manuscript submissions: closed (31 March 2023) | Viewed by 5304

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Scientific Practical Materials Research Centre of National Academy of Sciences of Belarus, Minsk, Belarus
Interests: chemistry and physics of complex transition metal alloys and oxides in micro-, meso-, and nanoforms; crystal and magnetic structures; phase transitions; magnetic state; colossal magnetoresistance; magnetoelectric effect; multiferroics; microwave absorption; microwave magnetodielectric materials for 5G technology; functional composite materials for microwave absorption
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Special Issue Information

Dear Colleagues,

The obtainment of pure metals and alloys based on their nanoscale state and the study of their properties is of paramount importance for modern science and technology and, therefore, is a priority in the development of materials science. Thin metal films with a thickness of up to several tens of nanometers on substrates of various natures, mainly dielectric ones, are of considerable scientific and practical interest. Gold attracts great interest, which is explained by its high corrosion resistance and high electrical conductivity. Such properties have led to its wide application in various areas of electronic instrumentation as conductive coatings. Gold thin films are capable of transmitting more than half of the incident light flux while absorbing only 10-20%. This allows them to be used as transparent ohmic contacts, transparent protective layers, electrodes in multilayer metal structures, etc. Another wide area of application for these materials is related to the possibility of the excitation of elementary oscillations such as plasmons, excitons, and magnons. The interaction between these excitations and electromagnetic waves makes it possible to create artificial media with unusual properties, such as metamaterials, which opens up opportunities for the development of plasmonic, nanophotonic, and magnetoplasmonic devices. In addition, nanocomposites, which are nanometer metal particles dispersed in an oxide matrix, have enhanced physical and chemical properties. Nanocomposites consisting of noble metals and a matrix of metal oxides are considered promising materials for use in catalysis, electronics, fuel cells, and gas sensors. Within the films of these materials, various additional technological applications exist, such as use in coated medical devices, magnetic recording media, electro-optical systems, photocatalytic coatings, or gas sensing devices. Additionally, nanoscale metals and their alloys can serve as the best materials for shielding electromagnetic interference. The creation and application of flexible polymer nanocomposites based on metals and metal alloys with the addition of carbon nanoforms can replace the materials already used for electromagnetic interference protection due to their unique characteristics, such as their lightweight, excellent corrosion resistance, and excellent electrical, dielectric, thermal, mechanical, and magnetic properties that are very useful in the suppression of electromagnetic interference.

Prof. Dr. Sergei Trukhanov
Guest Editor

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Keywords

  • metals and alloys
  • thin films
  • nanocomposites
  • electromagnetic shielding
  • metamaterials
  • electro-optical systems
  • medical devices, magnetic recording media, electro-optical systems
  • solar cells

Published Papers (3 papers)

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Research

14 pages, 4316 KiB  
Article
Features of Galvanostatic Electrodeposition of NiFe Films with Composition Gradient: Influence of Substrate Characteristics
by Tatiana I. Zubar, Tatsiana I. Usovich, Daria I. Tishkevich, Oleg D. Kanafyev, Vladimir A. Fedkin, Anna N. Kotelnikova, Maria I. Panasyuk, Alexander S. Kurochka, Alexander V. Nuriev, Abubakr M. Idris, Mayeen U. Khandaker, Sergei V. Trukhanov, Valery M. Fedosyuk and Alex V. Trukhanov
Nanomaterials 2022, 12(17), 2926; https://doi.org/10.3390/nano12172926 - 25 Aug 2022
Cited by 50 | Viewed by 1802
Abstract
NiFe films with a composition gradient are of particular interest from the point of view of fundamental science and practical applications. Such gradient magnetic structures may exhibit unique functional properties useful for sensory applications and beyond. The issue surrounds the anomaly concerning the [...] Read more.
NiFe films with a composition gradient are of particular interest from the point of view of fundamental science and practical applications. Such gradient magnetic structures may exhibit unique functional properties useful for sensory applications and beyond. The issue surrounds the anomaly concerning the compositional gradient formed near the substrate in electrolytically deposited binary and ternary iron-containing alloys, which has not previously been clearly explained. In this work, light is shed on this issue, and a clear relationship is found between the structure and surface properties of the substrate, the initially formed NiFe layers and the film composition gradient. Full article
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14 pages, 3533 KiB  
Article
Flowery ln2MnSe4 Novel Electrocatalyst Developed via Anion Exchange Strategy for Efficient Water Splitting
by Sumaira Manzoor, Sergei V. Trukhanov, Mohammad Numair Ansari, Muhammad Abdullah, Atalah Alruwaili, Alex V. Trukhanov, Mayeen Uddin Khandaker, Abubakr M. Idris, Karam S. El-Nasser and Taha AbdelMohaymen Taha
Nanomaterials 2022, 12(13), 2209; https://doi.org/10.3390/nano12132209 - 28 Jun 2022
Cited by 47 | Viewed by 2552
Abstract
Oxygen and hydrogen generated by water electrolysis may be utilized as a clean chemical fuel with high gravimetric energy density and energy conversion efficiency. The hydrogen fuel will be the alternative to traditional fossil fuels in the future, which are near to exhaustion [...] Read more.
Oxygen and hydrogen generated by water electrolysis may be utilized as a clean chemical fuel with high gravimetric energy density and energy conversion efficiency. The hydrogen fuel will be the alternative to traditional fossil fuels in the future, which are near to exhaustion and cause pollution. In the present study, flowery-shaped In2MnSe4 nanoelectrocatalyst is fabricated by anion exchange reaction directly grown on nickel foam (NF) in 1.0 M KOH medium for oxygen evolution reaction (OER). The physiochemical and electrical characterization techniques are used to investigate the chemical structure, morphology, and electrical properties of the In2MnSe4 material. The electrochemical result indicates that synthesized material exhibits a smaller value of Tafel slope (86 mV/dec), lower overpotential (259 mV), and high stability for 37 h with small deterioration in the current density for a long time. Hence, the fabricated material responds with an extraordinary performance for the OER process and for many other applications in the future. Full article
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14 pages, 5851 KiB  
Article
Isostatic Hot Pressed W–Cu Composites with Nanosized Grain Boundaries: Microstructure, Structure and Radiation Shielding Efficiency against Gamma Rays
by Daria I. Tishkevich, Tatiana I. Zubar, Alexander L. Zhaludkevich, Ihar U. Razanau, Tatiana N. Vershinina, Anastasia A. Bondaruk, Ekaterina K. Zheleznova, Mengge Dong, Mohamed Y. Hanfi, M. I. Sayyed, Maxim V. Silibin, Sergei V. Trukhanov and Alex V. Trukhanov
Nanomaterials 2022, 12(10), 1642; https://doi.org/10.3390/nano12101642 - 11 May 2022
Cited by 52 | Viewed by 2314
Abstract
The W–Cu composites with nanosized grain boundaries and high effective density were fabricated using a new fast isostatic hot pressing method. A significantly faster method was proposed for the formation of W–Cu composites in comparison to the traditional ones. The influence of both [...] Read more.
The W–Cu composites with nanosized grain boundaries and high effective density were fabricated using a new fast isostatic hot pressing method. A significantly faster method was proposed for the formation of W–Cu composites in comparison to the traditional ones. The influence of both the high temperature and pressure conditions on the microstructure, structure, chemical composition, and density values were observed. It has been shown that W–Cu samples have a polycrystalline well-packed microstructure. The copper performs the function of a matrix that surrounds the tungsten grains. The W–Cu composites have mixed bcc-W (sp. gr. Im 3¯ m) and fcc-Cu (sp. gr. Fm 3¯ m) phases. The W crystallite sizes vary from 107 to 175 nm depending on the sintering conditions. The optimal sintering regimes of the W–Cu composites with the highest density value of 16.37 g/cm3 were determined. Tungsten–copper composites with thicknesses of 0.06–0.27 cm have been fabricated for the radiation protection efficiency investigation against gamma rays. It has been shown that W–Cu samples have a high shielding efficiency from gamma radiation in the 0.276–1.25 MeV range of energies, which makes them excellent candidates as materials for radiation protection. Full article
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