Sintering Behavior in Steels

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Powder Metallurgy".

Deadline for manuscript submissions: closed (30 April 2022) | Viewed by 5216

Special Issue Editor


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Guest Editor
Research Group Powder Metallurgy (Head), Division Chemical Technologies, Institute of Chemical Technologies, TU Wien, 1060 Vienna, Austria
Interests: sintering of steels; thermal analysis for process control; sintering of special PM materials (aluminum alloys, heavy metal, copper alloys); additive manufacturing with binder-based methods

Special Issue Information

Dear Colleagues,

The sintering of PM steels has become increasingly challenging over the last 20 years. With the market entry of chromium alloyed steels, a new era in PM steels has started and moved from easy-to-sinter alloys Fe-Cu-Ni-Mo to more advanced systems alloyed with chromium and manganese. Basic scientific work has proven to be essential for understanding and establishing these alloys in industrial practice. However, the development must not stop now. There are still many questions open when these materials have to be sintered. Furthermore, there are still interesting alloying elements used in wrought metallurgy that are barely used in PM: silicon and vanadium, just to name the most prominent ones. These alloying elements show interesting properties, but their oxygen affinity makes them difficult to handle during the sintering process.

Apart from maximum mechanical properties, PM steels are also faced with other demands from the end-users.

  • Low-cost alloys require the development of lean alloy concepts, and their sintering behavior has to be studied;
  • Precision of parts is of extreme importance to reduce the costs of mechanical working after the sintering process, which means that the knowledge about dimensional behavior gains more and more importance to predict the changes during sintering. This becomes even more important when high-temperature sintering is applied.
  • High-temperature sintering needs new furnace concepts to reach all the properties that are offered by the new alloying systems. Existing furnace concepts have to be developed further to obtain better control of the sintering process.
  • Modelling tools for the sintering process are necessary to predict the dimensional behavior and the final mechanical properties.

Prof. Christian Gierl-Mayer
Guest Editor

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Keywords

  • sintering behavior
  • sintering of new alloy concepts
  • parts precision
  • high-temperature sintering
  • modelling of sintering process
  • lean alloy concepts
  • furnace control

Published Papers (2 papers)

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Research

19 pages, 7962 KiB  
Article
Mechanical and Physical Properties of Differently Alloyed Sintered Steels as a Function of the Sintering Temperature
by Milad Hojati, Herbert Danninger and Christian Gierl-Mayer
Metals 2022, 12(1), 13; https://doi.org/10.3390/met12010013 - 22 Dec 2021
Cited by 8 | Viewed by 2884
Abstract
In this paper, the effect of processes occurring during the sintering of four powder metallurgy steel grades on the resulting properties were investigated. This included three grades prepared from plain iron powder with admixed graphite, one grade alloyed also with elemental copper and [...] Read more.
In this paper, the effect of processes occurring during the sintering of four powder metallurgy steel grades on the resulting properties were investigated. This included three grades prepared from plain iron powder with admixed graphite, one grade alloyed also with elemental copper and another with Fe-Mn-Si masteralloy. One further grade was prepared from Cr-Mo pre-alloyed powder with admixed graphite. The effect of the sintering processes was examined in the temperature range of 700–1300 °C in an inert atmosphere (Ar). In order to study oxygen removal, DTA/TG runs linked with mass spectrometry (MS) as well as C/O elemental analysis were performed. Charpy impact tests and fractography studies were performed to study the effect of the temperature on the formation and growth of sintering contacts. Characterization also included metallography, dimensional change, sintered density, and hardness measurements to describe the dissolution of carbon and alloying elements during the process. Physical properties that were measured were electrical conductivity and coercive force. The results showed that, in all steels, the reduction of oxides that occur during the heating stage plays a key role in the formation and growth of the sintering contacts as well as in the completion of alloying processes. In the chromium alloy steel, the presence of the stable chromium oxides delays these processes up to higher temperatures, while in the other steels that are based on plain iron powder, these processes take place earlier in the heating stage, at lower temperatures. Compared to the standard Fe-C and Fe-Cu-C grades, the Cr-Mo steel requires more sophisticated sintering to ensure oxygen removal, but on the other hand it offers the best properties. The masteralloy variant, finally, can be regarded as a highly attractive compromise between manufacturing requirements, alloy element content, and product properties. Full article
(This article belongs to the Special Issue Sintering Behavior in Steels)
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16 pages, 100458 KiB  
Article
Transient Liquid Phase Sintering of PM Steel—A Matter of the Heating Rate
by Stefan Geroldinger, Raquel de Oro Calderon, Christian Gierl-Mayer and Herbert Danninger
Metals 2021, 11(10), 1662; https://doi.org/10.3390/met11101662 - 19 Oct 2021
Cited by 3 | Viewed by 1598
Abstract
Powder metallurgy (PM) offers several variants to introduce alloying elements for establishing the desired final composition. One route is the master alloy (MA) approach. The composition and the elements contained in the MA can be adjusted to obtain a liquid phase that penetrates [...] Read more.
Powder metallurgy (PM) offers several variants to introduce alloying elements for establishing the desired final composition. One route is the master alloy (MA) approach. The composition and the elements contained in the MA can be adjusted to obtain a liquid phase that penetrates through the interconnected pore network and thus enhances the distribution of the alloying elements and the homogenization of the microstructure. Such a liquid phase is often of a transient character, and therefore the amount of liquid formed and the time the liquid is present during the sintering are highly dependent on the heating rates. The heating rate has also an impact on the reaction temperatures, and therefore, by properly adjusting the heating rate, it is possible to sinter PM-steels alloyed with Fe-Cr-Si-C-MA at temperatures below 1250 °C. The present study shows the dependence of the melting regimes on the heating rate (5, 10, 20, 120 K/min) represented by “Kissinger plots”. For this purpose, liquid phase formation and distribution were monitored in quenching dilatometer experiments with defined heating up to different temperatures (1120 °C, 1180 °C, 1250 °C, 1300 °C) and subsequent quenching. Optimum sintering conditions for the materials were identified, and the concept was corroborated by C and O analysis, CCT diagrams, metallographic sections, and hardness measurements. Full article
(This article belongs to the Special Issue Sintering Behavior in Steels)
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