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Sustainable Colouration and Functional Finishing of Textiles

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (10 February 2023) | Viewed by 5490

Special Issue Editors


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Guest Editor
College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China
Interests: flame retardant; eco-textile; natural extract; colouration; functionalisation; cleaner production
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China
Interests: flame retardant; functional modification; surface coating; biomass; textiles
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Sustainable colouration and functional finishing of textiles has received tremendous attention, both from academia and industry. With the increasing concern on human health and environmental issues related to textiles, as well as the growing demand for multifuntional and customized textiles, a variety of advanced and sustainable materials and technologies are incorporated to the production of textiles. The materials, including bio-degradable reagents and polymers, nanomaterials, catalysts, conductive composites, etc., impart textiles with safety and new functions. The sustainable technologies involving inkjet printing, supercritical carbon dioxide, microwave, ultrasound, UV irradiation, etc., enables higher processing efficiency, with reduced energy, water, and time consumption, and also promotes the performance of materials. However, how to enchance the compatibility of these advanced materials and technologies for textiles processing towards optimal performances, remains in-depth, comprehensive, and interdisciplinary studies. This Special Issue covers these topics and focuses on the establishment of material–process–performance relationships with high expectations for the scaling-up of production of textiles in the near future.

Dr. Yuyang Zhou
Dr. Xian-Wei Cheng
Guest Editors

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Keywords

  • sustainable production
  • smart and functional textile
  • dyeing and finishing mechanism
  • safety and ecology of textile

Published Papers (4 papers)

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Research

16 pages, 2510 KiB  
Article
A Facile and Rapid Strategy for Quantifying PCBs in Cereals Based on Dispersive Solid-Phase Extraction and Gas Chromatography–Mass Spectrometry: A Reference for Safety Concerns in Sustainable Textiles
by Tengfei Liu, Ying Song, Xiangyun Wang, Linlin Shi and Minghui Dong
Materials 2023, 16(4), 1698; https://doi.org/10.3390/ma16041698 - 17 Feb 2023
Viewed by 1319
Abstract
Cereals and their derivative products such as starch and cyclodextrin are significant natural materials for sustainable textile processing (e.g., sizing, dispersing, etc.). However, the contamination of cereals with polychlorinated biphenyls (PCBs) is often neglected, which has led to increasing concerns due to the [...] Read more.
Cereals and their derivative products such as starch and cyclodextrin are significant natural materials for sustainable textile processing (e.g., sizing, dispersing, etc.). However, the contamination of cereals with polychlorinated biphenyls (PCBs) is often neglected, which has led to increasing concerns due to the adverse effects on end users. Therefore, monitoring PCBs in cereals is of great importance in preventing health risks. However, high starch, protein, and fat contents make cereals a complicated matrix and can challenge the analysis of PCBs in cereals. This work describes a facile and rapid strategy for quantifying 18 PCBs in cereals that included corn, wheat, and rice through dispersive solid-phase extraction and gas chromatography with mass spectrometry. Importantly, this was the first time that carboxyl-modified, multi-walled carbon nanotubes were incorporated in the detection of PCBs in cereals. The influences of several parameters on the extraction and clean-up efficiency were investigated; these included the type and volume of extraction solvent, sonication time, and the type and dosage of the adsorbent. The matrix effects on quantification were also evaluated. This approach exhibited a better clean-up performance. All the analytes showed weak matrix effects, and thus a solvent standard plot could be prepared for their quantification. Spiking experiments in the selected matrices at three concentration levels from 0.5 to 10 μg/kg resulted in satisfactory recoveries that ranged from 79.2% to 110.5% with relative standard deviations (RSDs; n = 6) less than 10.3%. The limits of detection (LODs) and quantification (LOQs) ranged from 0.04 to 0.1 μg/kg and 0.1 to 0.4 μg/kg, respectively. The practical application of this method was investigated by analyzing actual cereal samples, which demonstrated that the proposed approach was a facile and efficient strategy for PCB determination and provided a reference for the safety evaluation of sustainable textiles. The method also could be generalized to other troublesome samples for testing of multiple PCBs. Full article
(This article belongs to the Special Issue Sustainable Colouration and Functional Finishing of Textiles)
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10 pages, 7715 KiB  
Article
Fabrication of P/N/B-Based Intumescent Flame-Retardant Coating for Polyester/Cotton Blend Fabric
by Wei-Lin He, Yi-Ting Huang, Liang Gu, Ji-Cheng Shen, Xian-Wei Cheng and Jin-Ping Guan
Materials 2022, 15(18), 6420; https://doi.org/10.3390/ma15186420 - 15 Sep 2022
Cited by 6 | Viewed by 1564
Abstract
Polyester/cotton (T/C) blend fabrics are highly flammable due to the particular “scaffolding effect”. In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds [...] Read more.
Polyester/cotton (T/C) blend fabrics are highly flammable due to the particular “scaffolding effect”. In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds were deposited onto a T/C blend fabric by the surface-coating route. The chemical structure of IFR agent and its potential cross-linking reactions with T/C fibers were characterized. The morphology, thermal stability, heat-release ability, flame retardancy, and mechanism of coated T/C blend fabrics were explored. The self-extinguishing action was observed for the coated T/C blend fabric with a weight gain of 13.7%; the limiting oxygen index (LOI) value increased to 27.1% versus 16.9% for a pristine one. Furthermore, the intumescent flame retardant (IFR) coating imparted T/C blend fabrics with high thermal stability and significantly suppressed heat release by nearly 50%. The char residue analyses on morphology and element content confirmed the intumescent FR action for coated T/C blend fabrics. The prepared IFR coating has great potential to serve as an eco-friendly approach for improving the flame retardancy of T/C blend textiles. Full article
(This article belongs to the Special Issue Sustainable Colouration and Functional Finishing of Textiles)
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17 pages, 4947 KiB  
Article
Energy-Saving One-Step Pre-Treatment Using an Activated Sodium Percarbonate System and Its Bleaching Mechanism for Cotton Fabric
by Qing Li, Run Lu, Yan Liang, Kang Gao and Huiyu Jiang
Materials 2022, 15(17), 5849; https://doi.org/10.3390/ma15175849 - 25 Aug 2022
Cited by 2 | Viewed by 1974
Abstract
The traditional pre-treatment of cotton fabric hardly meets the requirement of low carbon emissions due to its large energy consumption and wastewater discharge. In this study, a low-temperature and near-neutral strategy was designed by establishing a tetraacetylethylenediamine (TAED)-activated sodium percarbonate (SPC) system. First, [...] Read more.
The traditional pre-treatment of cotton fabric hardly meets the requirement of low carbon emissions due to its large energy consumption and wastewater discharge. In this study, a low-temperature and near-neutral strategy was designed by establishing a tetraacetylethylenediamine (TAED)-activated sodium percarbonate (SPC) system. First, the effects of SPC concentration, temperature and duration on the whiteness index (WI) and capillary effect of cotton fabrics were investigated. Particularly, excess SPC’s ability to create an additional bleaching effect was studied. The optimized activated pre-treatment was compared with the traditional pre-treatment in terms of the bleaching effect and energy consumption. Further, the degradation of morin, which is one of the natural pigments in cotton, was carried out in a homogeneous TAED/SPC system to reveal the bleaching mechanism. Lastly, the application performance of the treated cotton was evaluated by characterizing the dyeability, mechanical properties, morphology, etc. The research results showed that temperature had a significant influence on both the WI and capillary effect, followed by the SPC concentration and duration. The WI was positively correlated with the SPC concentration, but excess SPC could not produce an obvious additional effect. The WI of the fabric increased by 67.6% after the optimized activated bleaching using 10 mmol/L SPC and 15 mmol/L TAED at 70 °C for 30 min. Compared with the traditional process performed at 95 °C for 45 min, the activated process produced approximately 39.3% energy savings. Research on the bleaching mechanism indicated that the reactive species that participated in degrading the morin were the hydroxyl radical and superoxide radical, and the contribution degree of the former was larger than that of the latter. Two degradation components with molecular weights of 180 and 154 were detected using mass spectroscopy. Based on this, the bleaching mechanism of the TAED/SPC system was proposed. Moreover, the fabric after the activated pre-treatment had a suitable dyeability and strength, a lower wax residual and a smoother and cleaner fiber surface. The encouraging results showed that TAED/SPC is a promising bleaching system that is conducive to the sustainable advance of the textile industry. Full article
(This article belongs to the Special Issue Sustainable Colouration and Functional Finishing of Textiles)
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12 pages, 8639 KiB  
Article
Ultrasonic-Aided Co-Precipitation of Tannins and Chitosan Ammonium Salt on Cotton Fabric for Antimicrobial and Ultraviolet-Shielding Properties: An Efficient, Colourless, and Eco-Finishing Strategy
by Yuyang Zhou, Feiyang Zheng and Jingjing Wang
Materials 2022, 15(12), 4367; https://doi.org/10.3390/ma15124367 - 20 Jun 2022
Cited by 2 | Viewed by 1557
Abstract
Sustainable fabrication of protective cotton, using bio-extracts, is becoming increasingly attractive. However, many shortcomings—including the introduction of potentially hazardous mordants or modifiers to cotton, annoying colour changes after finishing, and low processing efficiency—require further melioration. Therefore, an efficient ultrasonic-assisted colourless finishing process was [...] Read more.
Sustainable fabrication of protective cotton, using bio-extracts, is becoming increasingly attractive. However, many shortcomings—including the introduction of potentially hazardous mordants or modifiers to cotton, annoying colour changes after finishing, and low processing efficiency—require further melioration. Therefore, an efficient ultrasonic-assisted colourless finishing process was developed in this study, to fabricate ultraviolet-proof and antimicrobial cotton. A pair of oppositely charged bio-based substances, i.e., tannin acid (TA) and hydroxypropyltrimethyl ammonium chloride chitosan (HACC) were introduced during the ultrasonic process. The results reveal that cationic HACC significantly promotes the adsorption of TA to cotton. The apparent colour of the cotton remained almost unchanged after finishing. Based on Pesudo first-/second-order kinetic models, chemisorption was verified as the dominant mechanism. Efficiency under ultrasound was enhanced by 5.3% (70 °C) and 27% (90 °C), respectively. A mathematical modelling study established the factors to be in the following order of significance: concentration > pH > temperature. Under optimal conditions, a theoretical maximum UPF of 380.8 was achieved. TA (8 g/L)-treated cotton deactivated up to 98% of Escherichia coli, and also provided excellent UV-shielding performance. In general, the ultrasonic-assisted eco-dyeing and finishing process for cotton was explored in depth from practical and theoretical perspectives, which should push forward the development of the sustainable textile industry. Full article
(This article belongs to the Special Issue Sustainable Colouration and Functional Finishing of Textiles)
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