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Bio-Based Aluminosilicates: From Waste to Precursor in Medical & Biotech Applications

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".

Deadline for manuscript submissions: closed (31 January 2023) | Viewed by 2759

Special Issue Editors


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Guest Editor
Department of Chemical Engineering, Faculty of Chemical Engineering and Environmental Protection, “Gheorghe Asachi” Technical University of Iasi, D. Mangeron, 73, 700050 Iasi, Romania
Interests: new materials synthesis and characterization; photocatalysis; nanomaterials; geopolymers
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Special Issue Information

Dear Colleagues,

The reduction of greenhouse gas emissions from fossil C and promoting bio-renewables has resulted in an increase of co-generated mineral waste (ash) enriched with valuable aluminosilicates. Various technologies have been applied to recycle bio-based aluminosilicates such as low-cost and eco-friendly by-products for environmental and health protection, such as the production of bio-based geopolymers for toxins removal, adsorbents for CO2 capturing, O2 carriers, and decomposition of industrial contaminants. Moreover, due to their porous nature, high adsorption capacity and ion exchange properties, nanocrystalline structures made of Al(III)/Si(IV)O4 units are excellent precursors for medical, pharmaceutical and biotechnological applications, especially for drug carrier and delivery systems, bone tissue engineering, biosensors, hemodialysis and some therapeutics. However, the separation and purification of valuable Si/Al constituents from complex and diverse matrices remains a technical challenge; thus, further research is urgently needed to ensure their deserved end-to-waste criteria. This Special Issue aims to present an overview of the most recent molecular research advances in bio-based aluminosilicates, their purification, synthesis, characterization and applications, especially in medicine, biotechnology and bioengineering.

Potential topics include, but are not limited to:

  • Mining of aluminosilicates from waste matrices;
  • Ash fractions as a source of aluminosilicates;
  • Synthesis of aluminosilicates;
  • Aluminosilicates in medical applications;
  • Aluminosilicates as drug carriers and drug suppliers;
  • Aluminosilicates as precursors for bone tissue;
  • Aluminosilicates as precursors for biosensors;
  • Aluminosilicates in hemodialysis;
  • Aluminosilicates in therapeutics;
  • Aluminosilicates as antioxidants;
  • Aluminosilicates as antimicrobial agents;
  • Aluminosilicates as adsorbents for toxins.

Prof. Dr. Gabrijel Ondrasek
Dr. Maria Harja
Guest Editors

Manuscript Submission Information

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Keywords

  • nanostructured aluminosilicates
  • composite materials
  • functional materials
  • ash matrices
  • adsorbents
  • drug carrier
  • drug delivery
  • bone tissue engineering
  • biosensors
  • biomarkers
  • ecoengineering
  • bioengineering
  • waste management
  • end-to-waste point
  • circular bioeconomy

Published Papers (1 paper)

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Research

15 pages, 4864 KiB  
Article
Development and Characterization of a Novel Soil Amendment Based on Biomass Fly Ash Encapsulated in Calcium Alginate Microspheres
by Marko Vinceković, Suzana Šegota, Slaven Jurić, Maria Harja and Gabrijel Ondrasek
Int. J. Mol. Sci. 2022, 23(17), 9984; https://doi.org/10.3390/ijms23179984 - 01 Sep 2022
Cited by 5 | Viewed by 1882
Abstract
Biomass fly ash (BFA) from a biomass cogeneration plant was encapsulated into calcium alginate microspheres (ALG/Ca) and characterized. An FTIR analysis indicated that BFA loading weakened molecular interactions between ALG/Ca constituents (mainly hydrogen bonding and electrostatic interactions), thus changing the crosslinking density. SEM [...] Read more.
Biomass fly ash (BFA) from a biomass cogeneration plant was encapsulated into calcium alginate microspheres (ALG/Ca) and characterized. An FTIR analysis indicated that BFA loading weakened molecular interactions between ALG/Ca constituents (mainly hydrogen bonding and electrostatic interactions), thus changing the crosslinking density. SEM and AFM analyses revealed a wrinkled and rough surface with elongated and distorted granules. The in vitro release of BFA’s main components (K, Ca, and Mg) was controlled by diffusion through the gel-like matrix, but the kinetics and released amounts differed significantly. The smaller released amounts and slower release rates of Ca and Mg compared to K resulted from the differences in the solubility of their minerals as well as from the interactions of divalent cations with alginate chains. The physicochemical properties of the novel microsphere formulation reveal significant potential for the prolonged delivery of nutrients to crops in a safe manner. Full article
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