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Sensor Chemical Reactions in Nanocomposites

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Materials Science".

Deadline for manuscript submissions: closed (30 December 2023) | Viewed by 1970

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N.N. Semenov Federal Research Center for Chemical Physics of RAS, Moscow 119991, Russia
Interests: physico-chemical and electrophysical processes in nanosystems; chemical reactions in solid phase; cryochemical reactions
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Special Issue Information

Dear Colleagues,

In recent years, due to the increase in the content of various harmful impurities in the atmosphere, the number of studies on metal oxide sensors used to detect such impurities has increased significantly. The most common and promising means of detecting harmful and explosive substances in the surrounding atmosphere is semiconductor metal oxide sensors. The detection process is based on the chemical reaction of the analyzed compounds with oxygen chemisorbed on the surface of the semiconductor. As a result of this reaction, electrons captured by the chemisorbed oxygen return to the conduction band of the semiconductor, which leads to an increase in the conductivity of the sensor.

A promising direction for increasing the selectivity and sensitivity of metal oxide sensors is the use of mixed metal oxide systems, which combine metal oxides with various electronic characteristics and chemical properties. Varying the nature and content of components in such systems opens up new possibilities for controlling the intensity and selectivity of the sensory response in the detection of various substances in air. In this regard, the review considers and discusses studies of the structure and sensory properties of nanostructured binary composites consisting of semiconductor metal oxides of various natures as well as various physicochemical processes, including chemical reactions that occur when such sensors detect reducing gases.

Prof. Dr. Leonid I. Trakhtenberg
Guest Editor

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Published Papers (1 paper)

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Review

23 pages, 4860 KiB  
Review
Synthesis, Structural and Sensor Properties of Nanosized Mixed Oxides Based on In2O3 Particles
by Mariya I. Ikim, Genrikh N. Gerasimov, Vladimir F. Gromov, Olusegun J. Ilegbusi and Leonid I. Trakhtenberg
Int. J. Mol. Sci. 2023, 24(2), 1570; https://doi.org/10.3390/ijms24021570 - 13 Jan 2023
Cited by 5 | Viewed by 1725
Abstract
The paper considers the relationship between the structure and properties of nanostructured conductometric sensors based on binary mixtures of semiconductor oxides designed to detect reducing gases in the environment. The sensor effect in such systems is determined by the chemisorption of molecules on [...] Read more.
The paper considers the relationship between the structure and properties of nanostructured conductometric sensors based on binary mixtures of semiconductor oxides designed to detect reducing gases in the environment. The sensor effect in such systems is determined by the chemisorption of molecules on the surface of catalytically active particles and the transfer of chemisorbed products to electron-rich nanoparticles, where these products react with the analyzed gas. In this regard, the role is evaluated of the method of synthesizing the composites, the catalytic activity of metal oxides (CeO2, SnO2, ZnO), and the type of conductivity of metal oxides (Co3O4, ZrO2) in the sensor process. The effect of oxygen vacancies present in the composites on the performance characteristics is also considered. Particular attention is paid to the influence of the synthesis procedure for preparing sensitive layers based on CeO2–In2O3 on the structure of the resulting composites, as well as their conductive and sensor properties. Full article
(This article belongs to the Special Issue Sensor Chemical Reactions in Nanocomposites)
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