Environments

DBP and DEHP are two of the most common plasticisers used in modern industries, which have aroused a major concern over their ubiquitous occurrence and hazardous environmental effects. This study presents the first data of phthalates occurrence and distribution in Maltese shoreline sand. DBP and DEHP occurrence was investigated in three busy and secluded beaches, respectively. Analytical determination involved quantifying DBP and DEHP from 75 samples using UPLC–MS/MS through triple repeatability. The concentrations ranged between 0.0095 and 0.07034 µg/g and <LOQ and 0.0977 µg/g for DBP and DEHP, respectively. Statistical analysis of the comparison of phthalates in different beaches demonstrated that the occurrence of DBP and DEHP in Maltese shoreline sand varies. The differences in the occurrence of phthalates were attributed to the beach topography and anthropogenic pressures. Analysis of the effects of anthropogenic activities on the occurrence of phthalates showed a positive association. Distribution analysis showed that DBP and DEHP exhibit an uneven distribution along the shoreline. Conversely, different distributions were observed at distances away from the sea. The uneven distributions observed were associated with anthropogenic activities, different chemodynamic properties and wave action. Cluster analysis was performed to prove the interactions between the phthalates concentrations and the characteristics of the beaches. Full article

Water treatment, such as disinfection, is an integral stage of its use for human life. The use of plasma technology with high-voltage electric discharge in a liquid for obtaining a bactericidal effect is discussed. It has been experimentally shown that among the factors accompanying a high-voltage electric discharge in a liquid and affecting the viability of bacteria, cavitation is the main one. Simultaneous use of electric discharge in the special cavitation mode and oxidizing agents makes it possible to achieve stable disinfection of water. At the same time, bactericidal doses of the oxidizing agent are reduced by a factor of 10 relative to existing standards, and the energy costs for electric discharge exposure, enhanced by small doses of an oxidizing agent, are reduced by 6 times compared to the costs of disinfection by only an electric discharge. Full article

The discharge of untreated oily wastewater into the environment has serious impacts on human health, living nature, and ecosystems and leads to significant economic losses. Many engineering techniques have been proposed and applied to treat oily wastewater, but limited studies have investigated low-cost and effective techniques using by-products and waste/scrap materials from the construction industry. Materials to treat oily wastewater are needed not only to mitigate environmental pollution but also to promote the reuse and recycling of industrial by-products, especially in developing countries. This study, therefore, examined the sorption capacity of dispersed oil in wastewater (dispersed soybean oil in water; initial oil concentrations, C_i = 10–1000 mg/L; oil droplet size in water <2 μm) onto the hydrophobized/oleophilized autoclaved porous aerated concrete (AAC) grains made from waste scrap in Vietnam by using batch sorption tests in the laboratory. The AAC grains (sizes 0.106–0.25, 0.25–0.85, and 0.85–2.00 mm) were hydrophobized/oleophilized using oleic and stearic acids (coating concentrations of 1.0, 5.0, and 10 g/kg), and two sands (0.18–2.00 and 0.30–2.00 mm) were used as control samples. The results showed that the hydrophobized/oleophilized AAC grains had high sorption capacity for dispersed oil (i.e., high oil removal efficiency) compared to the control sands. Especially, the removal of AAC grains coated with stearic acid was >80% in high oil concentration solutions (C_i = 100 and 1000 mg/L), indicating that the hydrophobized/oleophilized AAC grains have high potential as useful adsorbents to trap dispersed oil in oily wastewater. Moreover, adsorption isotherms were drawn to examine the sorption characteristics of dispersed oil onto AAC grains. For all tested samples, the sorption of dispersed oil increased linearly with increasing equilibrium concentration. The commonly used Langmuir model, on the other hand, did not capture the measured isotherms. Full article

People in coastal cities around the world harvest seafood from local bays despite well-documented health risks. In cities such as San Diego, California, USA, much information about contaminants and human consumption patterns exists for finfish but is largely lacking for shellfish. This study sought to better understand shellfish contamination risks and human vulnerability to inform management and advisories. In summer 2018 and winter 2019, we sampled crustaceans for chemical contaminants and anthropogenic debris and throughout the year surveyed people harvesting from three public fishing piers around San Diego Bay. Of the emerging contaminants found, pyrethroids, benzylbutyl phthalate, PFOS and anthropogenic debris were in differing concentrations in the muscle and viscera of the California spiny lobster and two species of crabs. Combined with previous metal and organic contaminant data from the lobster, 22 contaminants were detected with 5 exceeding consumption thresholds and 8 lacking defined thresholds. California spiny lobster was the main crustacean harvested from piers, attracting shellfishers from a range of ages, incomes, home locations and self-identified racial/ethnic groups. Consumption preferences (e.g., muscle or viscera) were non-discriminant, making lobster contamination a community-wide risk. More monitoring of emerging contaminants and different shellfish species (and tissues) of interest is recommended to capture the spatial and temporal dynamics of health risks, especially because the use of bivalves as sentinels may not reveal the same risks (e.g., PFAS, phosphate flame retardants). Full article

Due to rapid economic growth, the use of plastics in almost all areas of human life has significantly increased over recent decades, leading to massive pollution. Therefore, works dealing with sustainable and biodegradable polymer materials are vital now. Herein, sustainable Mater-Bi/poly(ε-caprolactone) (PCL)-based biocomposites, filled with diisocyanate-modified cellulose particles, were prepared and subjected to 12-week seawater degradation. Changes in the chemical structure and surface wettability pointed to the increasing hydrophilicity of materials over time, which was limited by diisocyanate modifications. Only minor changes in the thermal performance of analyzed materials have been observed, pointing to the limited biodegradation of the PCL phase. The most significant effects have been related to the composite yellowing due to the filler diisocyanate modifications and surface erosion increasing its roughness. Obtained results pointing to the low degradation rate bring into question the commonly-regarded biodegradable nature of PCL material. Full article

Nutrient loads must be reduced to safe levels to protect sensitive receiving environments. This work presents the results of a 15-month monitoring program of a surface flow-constructed wetland (SFCW) in Queensland, Australia. The SFCW reduced the influent TN concentration by 54% and was able to retain 80% of the TN load, mainly due to the efficient removal of NOx and ammonium (92–100%). TP removal was negative due to the unaccounted loads from wildlife activity. During occasions of high loads, the wetland reduced TP concentrations by 77%. The hydraulic loading rate (HLR) correlated poorly to the TSS and TVS loads (r < 0.55); however, when adjusted to account for precipitation and evapotranspiration, stronger correlations (r > 0.78) were revealed. Strong correlations were revealed between adjusted HLR and TP (r = 0.87) and TN (r = 0.93). TN removal was highly governed by the inflow of TN concentration. TN removal could be predicted from the inflow concentration using the first-order plug-flow model (R² = 0.72). The model suggests that the system has an irreducible threshold TN load of 0.115 kg-N per m² per month. This work shows that SFCW can be effective in managing the nutrient loads even in systems that receive low organic and nutrient loads. Full article

The present research provides data on the density (ρ), viscosity (η) and ability to absorb carbon dioxide of systems containing amine, molecular solvent (MS) and choline chloride (ChCl), with the investigation of the physical properties of both neat amine/MS/ChCl mixtures and their samples after complete CO₂ saturation. The effect of the mixture composition was studied by varying amine from primary (monoethanolamine, MEA) to secondary (diethanolamine, DEA) and tertiary (triethanolamine, TEA) amine, and the degree of its substitution from a mono- (MEA, DEA and TEA) to a doubly-substituted (ethylenediamine, EDA) compound. The role of an MS was investigated via the exchange of ethylene glycol (EG) with water and dimethylsulfoxide (DMSO). In addition, the influence of the CO₂ absorption promoters present in the ternary MEA/EG/ChCl mixture at an amount of 5 wt. % was also investigated. We show that an increase in ρ and η in the amine/EG/ChCl mixture affects the properties of neat amines. This suggests that in the studied ternary mixtures, the nature of the interspecies interactions is very similar to those in the previously studied MEA/EG/ChCl system. When EG was exchanged for H₂O or DMSO, a decrease in ρ and an increase in η were observed. A comparison of the data with the corresponding properties of the systems composed of each pair of the mixture components indicates that the intensity and/or number of interspecies interactions in the present ternary mixtures were stronger than those in pure H₂O, DMSO and MEA. While in the presence of promoters no significant changes in the studied properties were found, for the corresponding CO₂-saturated samples, the ρ and η increased proportionally to the amount of absorbed gas. This was also the case for all the systems studied in the present research. The overall CO₂ absorption of the EG-based mixtures decreased when going from primary to secondary and tertiary amines; it was 21% higher for the MEA/H₂O/ChCl system compared to the mixtures containing EG and DMSO, which, in turn, showed similar absorption capacities. When the promoters were added to the MEA/EG/ChCl mixture, the highest capacity was found for the piperazine-containing system. Full article

The planning and management of water resources are being impacted by climate change, and are in need of comprehensive adaptation strategies to respond to future projections. The goal of this study is to support those strategies with a new decision-making paradigm that employs a probabilistic-nonstationary hydroclimatic scenario to examine the long-term system resilience for multiple dam objectives. The modified approach to examine resilience was applied, and uses a bottom-up approach with a modified resilience concept to achieve the long-term operation targets. The approach integrates Global Circulation Models (GCMs) with a statistical weather generator (SWG) to produce a range of future scenarios. Then, the system response is evaluated against those scenarios. The study utilizes a pre-developed SWG to synthesize different trajectories by altering three weather variables: the precipitation amount, temperature mean, and wind-speed magnitude. The proposed has four staged phases: (1) identification of the future climate exposure using different GCMs; (2) future water supply estimation for scenarios using hydrological models; (3) future water demand estimation for scenarios of all system stakeholders; and (4) evaluation of system performance resilience for the dam operational purposes. The Diyala River Basin in Iraq was selected as a case study, to apply the suggested paradigm. The analysis of the GCM outputs revealed that the rainfall mean varies between −37% and +31%; temperature mean varies between +0.4 °C and 5.1 °C; and the mean wind speed varies between −22% and 11%. Based on these ranges, the future climate trajectories were simulated. According to the examination of the system’s response to those weather changes, the precipitation is the most effective parameter, followed by the temperature change, and lastly the wind speed. Furthermore, the findings show that the existing system operating rules are reliable in terms of flood protection but vulnerable in terms of drought management. The analysis of system resilience to manage the drought was found to be 0.74 for the future trajectories, while it was 0.91 for flood protection. This indicates that project managers should prioritize the drought and water scarcity management, due to climate change impact and upstream country development. The study also shows that the suggested resilience paradigm is capable of measuring the negative effects of climate change and able to provide long-term adaptation guidance for water resources management. Full article

Solar parks are currently considered a new source of carbon-free energy. At the same time, they encroach on our landscape and create new conditions for flora and fauna. Vegetation responds to changes in living conditions. The aim of this study was to evaluate the changes in soil conditions induced by solar parks using vegetation bioindicators. A vegetation assessment was carried out in a solar park located in the cadastral territory of the municipality of Unín (Czech Republic). Among the soil conditions observed, this study focused on soil moisture, pH, nitrogen availability, phosphorus availability, and salinity. A total of 77 taxa of vascular plants were identified. Based on the bioindication of vegetation, it can be concluded that there are changes in the conditions between sites under photovoltaic panels (PV) and between rows of PV panels. Under PV panels, species with extreme values of the monitored soil criteria have a higher representation. These species can tolerate salinity, deficiency, or excess nitrogen and phosphorus. Different conditions under PV panels lead to diversity in species composition. This results in significant fragmentation of solar couplet vegetation. However, extreme conditions may create room for invasive plant species to establish themselves. Thus, it is necessary to monitor changes in vegetation, especially under PV panels, in the following years. The characterization of environmental conditions based on vegetation biomonitoring shows the diversity of solar park conditions. Diverse conditions are also important for landscape fragmentation. Full article

Small- and large-scale accidents often occur in workplaces handling hazardous chemical substances. These accidents are usually caused by leaks, explosions, fires and complex chemicals; a large proportion of these chemical accidents are caused by leaks. A chemical release accident that injured four people occurred during an optical film-manufacturing process. This report analyzes the causes of this accident and provides effective measures for accident prevention. This accident was caused by an abnormal reaction during the input of raw materials prior to their heating. Tertiary butyl alcohol (t-BuOH), distilled water (DW), and potassium permanganate (KMnO₄) were mainly used in this process. We found that this mixture reacted with unknown impurities. After KMnO₄ was added to the mixture of t-BuOH and DW, a large amount of heat was suddenly released from the reactor for one minute. In particular, a small amount of methanol (4%), which could have entered the mixture during the cleaning process, and seal oil containing glycerin (13%) were suspected to be the key materials influencing the rapid reaction. Given the significant findings about this accident, the precautionary technical/administrative measures we provide herein may help prevent such accidents in future. Full article

Streambank erosion is a major contributor to watershed suspended sediments and phosphorus exports in many regions, but in Iowa and other midwestern states, the load contribution from streambanks is not considered by state nutrient reduction strategies. The study’s objectives were to evaluate the annual bank erosion rates measured in Iowa using erosion pins and aerial imagery and assess how recession rates vary across space, time, and stream order. The overall goal was to determine whether there are global similarities to these streambank recession rates that could be generalized and scaled up for regional assessments using data from Iowa-based erosion pin studies and original research on stream migration rates. At the erosion pin sites, the recession rates averaged approximately 11 cm yr⁻¹ in third-order streams and, when combined with stream migration analyses, we observed scaling associated with bank recession rates at longer time scales across a range of stream orders. More bank recession occurs in larger streams and rivers with greater discharge from larger watershed areas and an increase in stream power. Variations in these bank recession rates were observed in Iowa landform regions mainly due to differences in geology and the composition of the streambank sediments. The study’s results provide a temporal and spatial context for evaluating streambank recession in Iowa and the glaciated Midwest. Full article

The implementation of a protocol for supporting a reliable soil C market is needed. This paper aims to propose a methodology for evaluating soil organic C (SOC) stock changes for the C credit market. A 15-year-old chestnut orchard (CO) and a chestnut coppice (CC) as reference land were selected in the northern part of the Apennine chain (Italy). The CO is the result of the CC conversion carried out in 2005. The soil sampling by pedogenetic horizons till parent material was carried out in 2005, 2010, 2015 and 2020 in CO and in 2005 and 2020 in CC. For each sample, the concentration and stock of the total SOC and of the most recalcitrant SOC form were estimated. Unlike the CC, in CO, an increase over time of SOC stocks was observed throughout the entire soil profile indicating the suitability of CO for C credit gaining. Most of the SOC was stored within the deepest soil horizon. The methodology can be considered eligible for the C credit market because, replicable, the CO was intentionally realized by humans after 1990, and the additionality was evaluated. Moreover, soil functionality was considered through the evaluation of SOC forms and of the pedogenetic horizons. Full article

Hydrogen is one of the main energy carriers playing a prominent role in the future decarbonization of the economy. However, several aspects regarding the transport and storage of this gas are challenging. The intermediary conversion of hydrogen into high-density energy molecules may be a crucial step until technological conditions are ready to attain a significant reduction in fossil fuel use in transport and the industrial sector. The process of transforming hydrogen into methane by anaerobic digestion is reviewed, showing that this technology is a feasible option for facilitating hydrogen storage and transport. The manuscript focuses on the role of anaerobic digestion as a technology driver capable of fast adaptation to current energy needs. The use of thermophilic systems and reactors capable of increasing the contact between the H₂-fuel and liquid phase demonstrated outstanding capabilities, attaining higher conversion rates and increasing methane productivity. Pressure is a relevant factor of the process, allowing for better hydrogen solubility and setting the basis for considering feasible underground hydrogen storage concomitant with biological methanation. This feature may allow the integration of sequestered carbon dioxide as a relevant substrate. Full article

Meiofauna (body size within 30–1000 µm) are the community of microscopic invertebrates that live at the bottom of marine and freshwater ecosystems and play a key role in the food webs of these environments. Several studies have addressed the adverse effects of anthropic stressors on meiofauna; however, data on the presence and impact of plastic debris in wild meiofaunal organisms are scant. Since the amount of microplastic waste in sediments may surge rapidly, ascertaining the ingestion of these xenobiotics by the abundant micrometazoan community is necessary to understand their potential accumulation in aquatic food webs and their hazard to the health of the ecosystem. The absence of documentation in this regard may be due to the difficulty in detecting the small size of the plastic fragments meiofauna may potentially ingest. To overcome this difficulty, we developed an integrated approach based on different microscopic/spectroscopic techniques suitable for detecting plastic particles of sizes down to 200 nm. Full article

Incorporating native perennial grasses adjacent to annual row crop systems managed on marginal lands can increase system resiliency by diversifying food and energy production. This study evaluated (1) soil organic C (SOC) and total N stocks (TN) under warm-season grass (WSG) monocultures and a low diversity mixture compared to an adjacent no-till continuous-corn system, and (2) WSG total above-ground biomass (AGB) in response to two levels of N fertilization from 2012 to 2017 in eastern Nebraska, USA. The WSG treatments consisted of (1) switchgrass (SWG), (2) big bluestem (BGB), and (3) low-diversity grass mixture (LDM; big bluestem, Indiangrass, and sideoat grama). Soils were sampled at fixed depth increments (0–120 cm) in the WSG plots and in the adjacent corn experiment in 2012 and 2017. Soil stocks (Mg ha⁻¹) of SOC and TN were calculated on an equivalent soil mass (ESM) basis and compared within the three WSG treatments as well as between experiments (corn compared to the mean of all WSGs). Soil organic C and TN stocks within soil layers and cumulative stocks responded to the main effect of WSG (P_WSG < 0.05) but were no different when comparing the WSGs to corn (P_expt = NS). Both SOC/TN stocks and cumulative stocks were generally greater in the LDM compared to the BGB. Neither SOC nor TN changed over time under either the WSGs or corn. Warm-season grass AGB responded to a three-way interaction of year, N rate, and WSG (p = 0.0007). Decreases in AGB over time were significant across WSGs and N levels except for SWG at 56 kg N ha⁻¹ and LDM at 112 kg N ha⁻¹. Above-ground biomass was generally greater in the LDM after the first harvest year (2013). Results suggest that incorporating WSGs into marginal cropland can maintain SOC and TN stocks while providing a significant source of biomass to be used in energy production or in integrated livestock systems. Full article

Establishing new protected areas (PAs) is one of the first steps needed to reduce habitat loss and fragmentation, protect ecosystems that are of vital importance to conserve biodiversity, and even protect traditional cultures. The correct management of a PA can be beneficial for the different forms of life found within it and can provide multiple benefits to humanity and to the continued functioning of productive ecosystems. Protected Areas act as buffers for life while serving as sanctuaries and strongholds for species in the face of climate change. Within these areas, genetic diversity is enabled to evolve in response to the pressures of natural selection. The causes of biodiversity loss include changes in land use due to agriculture and urbanization, invasive species, overexploitation, and pollution. As stipulated, the current study aims to update the National System of Protected Areas (SNAP) by applying a review of scientific and gray literature. This review presents updated information; Ecuador currently has 74 protected areas, with state, decentralized autonomous, community, and private subdivisions. The main social and environmental impacts found in the protected areas included in the SNAP are presented in a review of the existing literature. Finally, strategies are proposed to improve the management of the protected areas of the SNAP focused on strengthening the conservation of their different life forms and the responsible use of their ecosystem services through more efficient and productive spaces. Full article

Industrial control charts are used in manufacturing to quickly and robustly indicate the status of production and to prompt any necessary corrective actions. The library of tools available for these tasks has grown over time and many have been used in other disciplines with similar objectives, including environmental monitoring. While the utility of control charts in environmental monitoring has been recognized, and the tools have already been used in many individual studies, they may be underutilized in some types of programs. For example, control charts may be especially useful for reporting and evaluating data from regional surveillance monitoring programs, but they are not yet routinely used. The purpose of this study was to promote the use of control charts in regional environmental monitoring by surveying the literature for control charting techniques suitable for the various types of data available from large programs measuring multiple indicators at multiple locations across various physical environments. Example datasets were obtained for Canada’s Oil Sands Region, including water quality, air quality, facility production and performance, and bird communities, and were analyzed using univariate (e.g., x-bar) and multivariate (e.g., Hotelling’s T²) control charts. The control charts indicated multiple instances of unexpected observations and highlighted subtle patterns in all of the example data. While control charts are not uniquely able to identify potentially relevant patterns in data and can be challenging to apply in some monitoring analyses, this work emphasizes the broad utility of the tools for straightforwardly presenting the results from standardized and routine surveillance monitoring. Full article

Estimating various properties of soil, including moisture, carbon, and nitrogen, is crucial for studying their correlation with plant health and food production. However, conventional methods such as oven-drying and chemical analysis are laborious, expensive, and only feasible for a limited land area. With the advent of remote sensing technologies like multi/hyperspectral imaging, it is now possible to predict soil properties non-invasive and cost-effectively for a large expanse of bare land. Recent research shows the possibility of predicting those soil contents from a wide range of hyperspectral data using good prediction algorithms. However, these kinds of hyperspectral sensors are expensive and not widely available. Therefore, this paper investigates different machine and deep learning techniques to predict soil nutrient properties using only the red (R), green (G), and blue (B) bands data to propose a suitable machine/deep learning model that can be used as a rapid soil test. Another objective of this research is to observe and compare the prediction accuracy in three cases i. hyperspectral band ii. full spectrum of the visual band, and iii. three-channel of RGB band and provide a guideline to the user on which spectrum information they should use to predict those soil properties. The outcome of this research helps to develop a mobile application that is easy to use for a quick soil test. This research also explores learning-based algorithms with significant feature combinations and their performance comparisons in predicting soil properties from visual band data. For this, we also explore the impact of dimensional reduction (i.e., principal component analysis) and transformations (i.e., empirical mode decomposition) of features. The results show that the proposed model can comparably predict the soil contents from the three-channel RGB data. Full article

We view the history of the Columbia River Basin through a resilience lens from the point of view of salmonids, as keystone species for the river basin ecosystems and social systems. We rely on the concept of multiple stable states as depicted in a stability landscape, as a scientific theory, but equally as a metaphor and a mental model. Using evidence-based plausibility arguments concerning the existence, creation, and potential critical transitions between regimes, we describe change over centuries. We argue that a critical transition occurred taking the state of the system from its historic regime into a novel regime stabilized by new social feedbacks and institutional configurations. By using a state space defined by four variables used in policy deliberations for salmon recovery we tie our results to historical and contemporary management issues. Knowledge of (a) which regime is currently occupied and (b) which critical transitions between regimes are possible are both crucial to effective policy formation. We draw distinctions between positions held by federal agencies, tribal agencies, and civil society organizations as to the current state of affairs and policy recommendations, raising questions about the appropriate use of decision support systems in the public process for decision making. Full article