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Multiscale and Multidisciplinary Studies of Gas Hydrate Formation, Dissociation and Dissolution Processes

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "H: Geo-Energy".

Deadline for manuscript submissions: 21 August 2024 | Viewed by 325

Special Issue Editors


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Guest Editor
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Xindu Road No.8, Chengdu 610500, China
Interests: non-equilibrium and equilibrium thermodynamics; statistical mechanics; quantum mechanics; multiscale modelling; hydrate phase transition dynamics; theoretical prediction of hydrate properties; CO2 for combined hydrate production and safe CO2 storage

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Guest Editor
European Way, Hampshire, National Oceanography Centre, Southampton, UK
Interests: geophysical characterisation of sediment and fluid flow with gas and gas hydrates; multiscale studies ranging from the micro scale to lab and field scale; how pore fluid affects the bulk properties of host sediments; reducing the uncertainties in the inversion of field data; reservoir characterisation; geophysical

Special Issue Information

Dear Colleagues,

Natural gas hydrates and their associated free gas accumulations represent a significant source of natural gas. Hydrates have the potential to help underpin the transition to cleaner energy, either as a source of energy by itself, or as a target for CO2 storage combined with the release of natural gas. The combination of the latter option with known technology for steam cracking of hydrocarbons allows for H2 to be delivered energy. Natural hydrate dissociation also plays a role in climate change due to complex feedback, and has implications for submarine geo-hazards.  

Natural gas hydrates are found in shallow marine sediments and permafrost around the world. Hydrates form in specific thermodynamic conditions and when enough natural gas and water is available. Hydrates dissociate due to changes in independent variables that control hydrate stability, such as increases in ocean temperature. Hydrates also dissociate continuously around the world due to fracture systems that bring seawater (containing almost no CH4) into hydrate-bearing sediments.

The implications of hydrate dissociation are that it contributes to the carbon content in the oceans, and in many cases, also causes direct leaks through the water column and potentially into the atmosphere. Occasional sub-sea landslides that cause tsunamis (tidal waves) are another effect of hydrate destabilisation.

There are still several knowledge gaps in our understanding of gas hydrate systems. Typically, hydrate formation in the sediments affects the geophysical, hydro-mechanical and geochemical properties of the host sediments. Generally, remote geophysical methods are used to quantify gas hydrates and determine changes in these geophysical properties. The extent of changes in geophysical properties due to hydrates depends, however, on the amount (saturation) and distribution (morphology) of the hydrates. Moreover, there are complex thermodynamic interactions between hydrates (solid phase), water (liquid phase), gas (free or in solution) and mineral surfaces. Molecular interactions and phase transitions are, by nature, nanoscale processes on a volumetric scale. Dynamic multiscale couplings from the pore scale to macroscopic scale still lead to many challenges and several effects that cannot be directly interpreted from field data with the current level of methods used in geophysics and geochemistry. A fundamental challenge is the lack of proper modelling of the dynamic couplings between a flowing multiphase system, including hydrates, and the inversion of geophysical responses. As an example, seismic responses are essentially responses due to changes in density and elasticity of the medium, which again is a function of all the coexisting phases in the sediments and flow on a different level, ranging from molecular flow (diffusion) to various levels of hydrodynamics. Even the coupling to flow dynamics in individual pores is complex, and this complexity increases with additional flow couplings between pores, and with macroscopic effects on a reservoir scale and field scale such as geological heterogeneities, local dynamic effects of fractures, and many other effects. Further progress will require developments in specific sub-topics on different scales, including the nanoscale and upwards. It is, however, difficult to make substantial further progress without a higher degree of interdisciplinary scientific work than what has been achieved up to now.  

There is also a need for a deeper understanding on how the technical feasibility of the various hydrate dissociation methods are controlled by thermodynamic laws, and on couplings to various levels of flow. The primary goal is the safe and sustainable production of energy from hydrates at commercially feasible costs.

Prof. Dr. BjØrn Kvamme
Dr. Sourav Sahoo
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Energies is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • gas hydrate
  • multiscale and multidisciplinary
  • seismic
  • laboratory elastic and electrical drilling systems
  • swapping or exchange of CO2 and CH4 hydrates
  • field-validated coupled models
  • high-resolution imaging of hydrates
  • integrated petrophysical, geological and geophysical data analyses

Published Papers (1 paper)

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Research

17 pages, 1112 KiB  
Article
Experimental Study on the Effect of Mixed Thermodynamic Inhibitors with Different Concentrations on Natural Gas Hydrate Synthesis
by Hengjie Luan, Mingkang Liu, Qinglin Shan, Yujing Jiang, Peng Yan and Xiaoyu Du
Energies 2024, 17(9), 2078; https://doi.org/10.3390/en17092078 - 26 Apr 2024
Viewed by 149
Abstract
Natural gas hydrate (NGH) is a potential future energy resource. More than 90% of NGH resources exist in the pore medium of seafloor sediments. During the development of deep-sea oil and gas fields, wellbore pipelines are often clogged due to the synthesis of [...] Read more.
Natural gas hydrate (NGH) is a potential future energy resource. More than 90% of NGH resources exist in the pore medium of seafloor sediments. During the development of deep-sea oil and gas fields, wellbore pipelines are often clogged due to the synthesis of gas hydrates, and the addition of thermodynamic inhibitors is a common solution to prevent hydrate synthesis. In this paper, the effects of two single inhibitors, sodium chloride and ethylene glycol, as well as hybrid inhibitors combining these two inhibitors on the synthesis of methane hydrates were investigated using the self-developed one-dimensional gas hydrate exploitation simulation test apparatus. The effects of single and hybrid inhibitors were investigated in terms of the hydrate synthesis volume and gas–water two-phase conversion rate. The results show that the hybrid inhibitor has a better inhibitory effect on hydrate synthesis with the same initial synthesis driving force. When the concentration of inhibitors is low, salt inhibitors can have a better inhibitory effect than alcohol inhibitors. However, in the mixed inhibitor experiment, increasing the proportion of ethylene glycol in the mixed inhibitor can more effectively inhibit the synthesis of hydrates than increasing the proportion of sodium chloride in the mixed inhibitor. Full article
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