New Insights into Catalysis for Hydrogen Production and Fuel Conversion

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Industrial Catalysis".

Deadline for manuscript submissions: 15 February 2025 | Viewed by 3452

Special Issue Editors


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Guest Editor
State Key Laboratory of Metastable Materials Science and Technology (MMST), Hebei Key Laboratory of Applied Chemistry, Yanshan University, Qinhuangdao 066004, China
Interests: hydrogen production; fuel conversion; CO2 reduction and utilization; photothermal coupling catalysis; catalytic mechanism

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Guest Editor
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
Interests: design and synthesis of new fuels; hydrogen production; theoretical calculations and machine learning; high-density endothermic fuels; precious metal hydrogenation catalysts

Special Issue Information

Dear Colleagues,

In recent years, energy and environmental issues have become increasingly prominent worldwide. The efficient catalytic conversion of fuels to prepare various energy chemicals and hydrogen is an important way to solve energy and environmental problems and has received widespread attention. There are various forms of hydrogen production through fuel catalytic conversion, including the commonly used heterogeneous fuel steam/oxygen reforming for hydrogen production, biomass gasification for hydrogen production, cracking for hydrogen production, boron ammonia/formic acid decomposition to produce hydrogen, propane dehydrogenation for hydrogen production, and fuel homogeneous conversion for hydrogen production. Catalysts/catalytic materials play a crucial role in the catalytic conversion of fuel to hydrogen. Therefore, it is necessary to provide a platform for researchers and engineers to discuss the mechanisms and current state of catalysts in the application of such a conversion.

This Special Issue "New Insights into Catalysis for Hydrogen Production and Fuel Conversion" focuses on the preparation, characterization, performance, and mechanism analysis of heterogeneous and homogeneous catalysts in the conversion of fuel to hydrogen. All research (experiment and theory) within the scope of this Special Issue, including original research and review articles, short exchanges and opinion articles, is welcome.

Dr. Zhourong Xiao
Dr. Guozhu Li
Guest Editors

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Keywords

  • fuel conversion
  • energy conversion
  • hydrogen production
  • energy conversion
  • homogeneous catalysis
  • heterogeneous catalysis
  • steam reforming
  • cracking
  • dehydrogenation
  • biomass gasification
  • catalytic mechanism
  • theoretical calculations

Published Papers (2 papers)

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Research

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16 pages, 6434 KiB  
Article
Perovskite-Derivative Ni-Based Catalysts for Hydrogen Production via Steam Reforming of Long-Chain Hydrocarbon Fuel
by Kai Guo, Hui Zhang, Changxuan Zhang, Xining Guo, Huiying Li and Zhourong Xiao
Catalysts 2024, 14(3), 186; https://doi.org/10.3390/catal14030186 - 08 Mar 2024
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Abstract
Large-scale hydrogen production by the steam reforming of long-chain hydrocarbon fuel is highly desirable for fuel-cell application. In this work, LaNiO3 perovskite materials doped with different rare earth elements (Ce, Pr, Tb and Sm) were prepared by a sol-gel method, and the [...] Read more.
Large-scale hydrogen production by the steam reforming of long-chain hydrocarbon fuel is highly desirable for fuel-cell application. In this work, LaNiO3 perovskite materials doped with different rare earth elements (Ce, Pr, Tb and Sm) were prepared by a sol-gel method, and the derivatives supported Ni-based catalysts which were successfully synthesized by hydrogen reduction. The physicochemical properties of the as-prepared catalysts were characterized by powder X-ray diffraction, high-resolution transmission electron microscopy, N2 adsorption–desorption isotherms, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy. The catalytic performance of the as-prepared catalysts for hydrogen production was investigated via the steam reforming of n-dodecane. The results showed that the catalyst forms perovskite oxides after calcination with abundant mesopores and macropores. After reduction, Ni particles were uniformly distributed on perovskite derivatives, and can effectively reduce the particles’ sizes by doping with rare earth elements (Ce, Pr, Tb and Sm). Compared with the un-doped catalyst, the activity and hydrogen-production rate of the catalysts are greatly improved with rare earth element (Ce, Pr, Tb and Sm)-doped catalysts, as well as the anti-carbon deposition performance. This is due to the strong interaction between the uniformly distributed Ni particles and the support, as well as the abundant oxygen defects on the catalyst surface. Full article
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Review

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24 pages, 1424 KiB  
Review
Heterogeneous Catalysts for Carbon Dioxide Methanation: A View on Catalytic Performance
by Mazhar Ahmed Memon, Yanan Jiang, Muhammad Azher Hassan, Muhammad Ajmal, Hong Wang and Yuan Liu
Catalysts 2023, 13(12), 1514; https://doi.org/10.3390/catal13121514 - 15 Dec 2023
Cited by 1 | Viewed by 2139
Abstract
CO2 methanation offers a promising route for converting CO2 into valuable chemicals and energy fuels at the same time as hydrogen is stored in methane, so the development of suitable catalysts is crucial. In this review, the performance of catalysts for [...] Read more.
CO2 methanation offers a promising route for converting CO2 into valuable chemicals and energy fuels at the same time as hydrogen is stored in methane, so the development of suitable catalysts is crucial. In this review, the performance of catalysts for CO2 methanation is presented and discussed, including noble metal-based catalysts and non-noble metal-based catalysts. Among the noble metal-based catalysts (Ru, Rh, and Pd), Ru-based catalysts show the best catalytic performance. In the non-noble metal catalysts, Ni-based catalysts are the best among Ni-, Co-, and Fe-based catalysts. The factors predominantly affecting catalytic performance are the dispersion of the active metal; the synergy of the active metal with support; and the addition of dopants. Further comprehensive investigations into (i) catalytic performance under industrial conditions, (ii) stability over a much longer period and (iii) activity enhancement at low reaction temperatures are anticipated to meet the industrial applications of CO2 methanation. Full article
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