Ionic Liquids for Green Catalysis and Separation

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (30 November 2022) | Viewed by 6427

Special Issue Editors


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Guest Editor
Laboratório Associado para a Química Verde-Rede de Química e Tecnologia, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal
Interests: chemical engineering; green chemistry; supercritical fluid (CO2) technology; catalysis, alternative solvents; carbon dioxide utilization; biomass-derived platform chemicals
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Guest Editor
Chemical Engineering and Applied Chemistry, Energy and Bioproducts Research Institute, Aston University, Birmingham B4 7ET, UK
Interests: CO2 utilisation; downstream recovery; ionic liquids; biomass conversion; waste valorisation; sustainable chemistry
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Ionic liquids are essentially liquids made up of cations and anions. Although the first low melting salt, ethylammonium nitrate, was synthesised by Paul Walden in 1914, the golden age of ionic liquids only began in the late 1990s. Early investigations used ionic liquids mainly in the role of solvents/processing media, but investigations quickly entered the area of catalysis, where ionic liquids serve as, i.e., (co)-catalysts, promotors, ligands, or stabilising agents.

Indeed, some aspects of commercial production and the use of ionic liquids, i.e., toxicity and environmental impact, cost, and purity, remain untackled. However, in industry, the choice of a system depends on a specific process or application. It is less important how “green” a component of a system is in itself if it can make the overall process more sustainable. Green chemistry focuses on the development of economical and eco-friendly technologies that not only improve the yield or efficiency but also decrease or eliminate the generation of waste and pollution. Unquestionably, ionic liquids can create systems that lead to significant improvements beyond simply replacing hazardous conventional solvents. Their unique tuneable/designer nature allows for the optimisation of the given technology according to the requirements of the intended use.

With this Special Issue, we aim at presenting recent progress in the application of ionic liquids in the area of catalysis and separation that falls within the green chemistry and sustainable development framework. We seek submissions on recent advances in the new synthetic pathways of different types of homogeneous (task-specific, chiral, poly-, switchable polarity, bio-) and heterogenous (immobilised) ionic liquids and their applications in various transformations, including organic and organometallic as well as bio-, electro-, or photochemical catalytic processes.

For this Special Issue, we accept submissions of full research articles and comprehensive reviews, communications, or letters representing both experimental and theoretical studies that explore the involvement of ionic liquids in catalytic and separation processes.

Dr. Małgorzata E. Zakrzewska
Dr. Vesna Najdanovic
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • ionic liquids in catalytic processes
  • ionic liquids and catalyst recycling
  • supported ionic liquid catalysis
  • synthesis of ionic liquids
  • green aspects of ionic liquid catalysis
  • ionic liquids in separation processes
  • ionic liquid recyclability

Published Papers (3 papers)

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Research

17 pages, 13271 KiB  
Article
Ionothermal Crystallization of SAPO-11 Using Novel Pyridinium Ionic Liquid and Its Catalytic Activity in Esterification of Levulinic Acid into Ethyl Levulinate
by Al Issa Jehad Moh’dFathi Mohammad, Vinithaa Saminathan, Zeinhom M. El-Bahy, Laure Michelin, Tau Chuan Ling and Eng-Poh Ng
Catalysts 2023, 13(2), 433; https://doi.org/10.3390/catal13020433 - 17 Feb 2023
Viewed by 1634
Abstract
A study using a novel pyridinium ionic liquid, namely 1-propylpyridinium bromide ([PPy]Br), to crystallize SAPO-11 under ionothermal conditions is reported. By carefully following the crystallization process, SAPO-11 can readily be crystallized in the presence of [PPy]Br, which serves as a synthesis solvent and [...] Read more.
A study using a novel pyridinium ionic liquid, namely 1-propylpyridinium bromide ([PPy]Br), to crystallize SAPO-11 under ionothermal conditions is reported. By carefully following the crystallization process, SAPO-11 can readily be crystallized in the presence of [PPy]Br, which serves as a synthesis solvent and structure-directing agent, at 150 °C after 133 h of heating. The study also focuses on manipulating other synthesis parameters (e.g., crystallization temperature, phosphorous content, silicon amount and [PPy]Br concentration) and investigating their respective effects on the formation of SAPO-11. The crystallized SAPO-11 has an acidic nature and a high surface area. Under conductive instant heating conditions, the SAPO-11 catalyst is very active in the conversion of levulinic acid into ethyl levulinate; 93.4% conversion and 100% selectivity of ethyl levulinate are recorded at 180 °C after 30 min of reaction. This result is comparable to or even better than those of conventional homogeneous catalysts. Full article
(This article belongs to the Special Issue Ionic Liquids for Green Catalysis and Separation)
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10 pages, 619 KiB  
Article
Studies toward the Use of Ionic Liquids and Supercritical CO2 for the Recovery and Separation of Praseodymium from Waste Streams
by Rene Rodriguez, Donna Baek, Mary Case and Robert Fox
Catalysts 2022, 12(3), 335; https://doi.org/10.3390/catal12030335 - 16 Mar 2022
Viewed by 1520
Abstract
Waste streams from the incineration of metal-containing materials like such as computer processor boards and batteries may contain critical rare earth elements like praseodymium. Data on the solubility of Pr compounds and on their distribution coefficients in supercritical CO2/ionic liquid two-phase [...] Read more.
Waste streams from the incineration of metal-containing materials like such as computer processor boards and batteries may contain critical rare earth elements like praseodymium. Data on the solubility of Pr compounds and on their distribution coefficients in supercritical CO2/ionic liquid two-phase systems are important to determine if an ionic liquid/supercritical CO2 two-phase approach is feasible toward the recovery of a particular metal. This work provides data on the solubility of various praseodymium compounds in butyl-methyl-pyrrolidinium bis(trifluoromethylsulfonyl)imide (BMPyTf2N) ionic liquid and on the distribution coefficients of these praseodymium compounds in the supercritical CO2 phase of the two-phase BMPyTf2N ionic liquid/supercritical CO2 system, with and without a tributyl phosphate additive. Full article
(This article belongs to the Special Issue Ionic Liquids for Green Catalysis and Separation)
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16 pages, 7056 KiB  
Article
A Bio-Based Alginate Aerogel as an Ionic Liquid Support for the Efficient Synthesis of Cyclic Carbonates from CO2 and Epoxides
by Ana B. Paninho, Ana N. Mustapa, Kamran T. Mahmudov, Armando J. L. Pombeiro, M. Fátima C. Guedes da Silva, María D. Bermejo, Ángel Martín, María J. Cocero and Ana V. M. Nunes
Catalysts 2021, 11(8), 872; https://doi.org/10.3390/catal11080872 - 21 Jul 2021
Cited by 6 | Viewed by 2338
Abstract
In this work, the ionic liquid [Aliquat][Cl] was supported into alginate and silica aerogel matrices and applied as a catalyst in the cycloaddition reaction between CO2 and a bio-based epoxide (limonene oxide). The efficiency of the alginate aerogel system is much higher [...] Read more.
In this work, the ionic liquid [Aliquat][Cl] was supported into alginate and silica aerogel matrices and applied as a catalyst in the cycloaddition reaction between CO2 and a bio-based epoxide (limonene oxide). The efficiency of the alginate aerogel system is much higher than that of the silica one. The method of wet impregnation was used for the impregnation of the aerogel with [Aliquat][Cl] and a zinc complex. The procedure originated a well-defined thin solvent film on the surface of support materials. Final materials were characterised by Fourier Transform Infrared Spectroscopy, N2 Adsorption–Desorption Analysis, X-ray diffraction, atomic absorption and Field Emission Scanning Microscopy. Several catalytic tests were performed in a high-pressure apparatus at 353.2 K and 4 MPa of CO2. Full article
(This article belongs to the Special Issue Ionic Liquids for Green Catalysis and Separation)
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