Advanced Electrode Materials for Emerging Post-lithium Metal-Ion Batteries

A special issue of Batteries (ISSN 2313-0105). This special issue belongs to the section "Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others".

Deadline for manuscript submissions: closed (20 January 2023) | Viewed by 258314

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Department of Materials Science and Engineering, Chonnam National University, Gwangju 61186, Republic of Korea
Interests: batteries; electrochemistry; first-principles calculations
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Dear Colleagues,

As a potential replacement for lithium-ion batteries, post-lithium-ion battery chemistries such as Na+, K+, Mg2+, Ca2+, Zn2+, and Al3+ with high energy densities have promised to meet the increasing demand for safe and sustainable energy storage applications. Discovering new cathode materials, unraveling their electrochemical mechanisms, and improving their performances are of great interest. Therefore, we are inviting papers in this Special Issue of Batteries which endorse current progress on this topic that focus on the development, improvement, and characterization of cathode materials for emerging post-lithium metal-ion batteries. We accept original research articles and reviews presenting experimental and computational studies of cathode materials for post-lithium metal-ion batteries.

Dr. Muhammad Hilmy Alfaruqi
Guest Editor

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Batteries is an international peer-reviewed open access monthly journal published by MDPI.

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Keywords

  • cathode materials
  • surface coating
  • defect chemistry
  • post-lithium metal-ion batteries (Na+, K+, Mg2+, Ca2+, Zn2+, Al3+)
  • characterization techniques
  • density functional theory

Published Papers (1 paper)

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Research

14 pages, 3618 KiB  
Article
Pom-Pom Flower-like Morphology of δ-MnO2 with Superior Electrochemical Performances for Rechargeable Aqueous Zinc Ion Batteries
by Priya Yadav, Dimas Putro, Jaekook Kim and Alok Kumar Rai
Batteries 2023, 9(2), 133; https://doi.org/10.3390/batteries9020133 - 14 Feb 2023
Cited by 3 | Viewed by 2134
Abstract
A rechargeable aqueous zinc-ion battery is an encouraging alternative for grid-scale energy storage applications, owing to its advantages of high safety, low cost, and environmental benignity. Since MnO2 is found to be one of the most efficient intercalation cathode materials for ZIBs, [...] Read more.
A rechargeable aqueous zinc-ion battery is an encouraging alternative for grid-scale energy storage applications, owing to its advantages of high safety, low cost, and environmental benignity. Since MnO2 is found to be one of the most efficient intercalation cathode materials for ZIBs, the layered type δ-MnO2 polymorph exhibits reversible intercalation/de-intercalation of Zn2+ ions with a high capacity. Unfortunately, the δ-MnO2 cathode suffers from poor cyclability, low-rate capability, and structural degradation during charge–discharge cycles. Therefore, δ-MnO2 with Pom-Pom Flower-like morphology have been synthesized using a facile hydrothermal method. The unique morphology of δ-MnO2 provides a high surface area with numerous reaction sites, leading to excellent electrochemical performance. The obtained results revealed that the δ-MnO2 electrode retained ~99% of its initial capacity even after 250 cycles, which can be ascribed to the reversible Zn2+ insertion/de-insertion from the current unique morphology of the layered δ-MnO2 nanostructure. In addition, the electrochemical and structural investigation also indicates a two-step co-insertion of H+ and Zn2+ ions into the interlayer of δ-MnO2 during the discharge process. Thus, the superior electrochemical performances of the δ-MnO2 cathode paves a way for the high capacity and a long lifespan of zinc-ion batteries. Full article
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