Polymer Micro- and Nanocapsules: Current Status, Challenges and Opportunities

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Biomacromolecules, Biobased and Biodegradable Polymers".

Deadline for manuscript submissions: closed (28 February 2023) | Viewed by 2062

Special Issue Editors


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Guest Editor
Department of Materials Science and Engineering, University of Ioannina, Ioannina, Greece
Interests: nanomodified capsules; self-healing epoxies; mechanical behaviour of materials; carbon nanotubes; composite materials; nanocomposites; structural health monitoring; additive manufacturing

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Guest Editor
Department of Manufacturing and Civil Engineering, Faculty of Engineering, Norwegian University of Science and Technology, 7491 Gjøvik, Norway
Interests: polymer composites; natural (green) materials; recycling; sustainability and durability aspects in aerospace; energy; automotive; infrastructure and building applications
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Special Issue Information

Dear Colleagues,

Inspired by the remarkable wound-healing functionality of living organisms, a self-healing material/structure can repair small or medium-scale damage; thus, restoring the impaired functionalities, potentially being capable of significantly increasing the lifetime of a structure, paving the way for a more sustainable and smart future.

Self-healing materials and, more specifically, polymers, can be categorized into three conceptual approaches: the intrinsic, the vascular and the capsule-based. The intrinsic self-healing approach exploits the inherent ability of a composite to restore its initial properties at the molecular level through physical or chemical reversible bonding. An alternative, extrinsic route towards developing self-healing polymers is by mimicking the blood vessels of living organisms. This approach involves the fabrication of a vascular network composed of micro-channels or hollow fibres, whereby the healing agent is manually or automatically introduced into the material. Finally, the capsule-based self-healing strategy concept is of high importance, involving the embedment of micro- or nano-capsules containing an active liquid, i.e., the healing agent, within the host material. When the polymer sustains damage, the capsules rupture, releasing the liquid agent at the damage site; thus, healing the polymer.

Capsule-based self-healing systems, incorporating micro- or nano-sized capsules, have attracted considerable attention in the research society due to their minimal reduction in mechanical properties after the incorporation of self-healing, the potential for mass production and high healing efficiency values. Numerous attempts have been presented every year, focusing on the development of different capsule-based self-healing systems (healing agent chemistry, encapsulation methods, etc.), as well as their integration to large-scale production with the best possible property–cost relationship, indicating the increased interest of the research community towards this filed.

The scope of this Special Issue is to present and discuss the recent advancements, healing fundamentals and mechanisms in self-healing polymers which utilise micro- or nano-sized capsules, with emphasis given to developments in encapsulation methods and novel functional materials related to capsule-based self-healing polymers.

With great pleasure, we would like to invite you to submit a manuscript for publication in this Special Issue, full papers, communications and reviews all being welcome. In addition, the list of keywords is not exhaustive, but it may help prepare your submission. If you would like to go beyond it, please submit a paper whose topic is not mentioned in this list.

Dr. Dimitrios Bekas
Prof. Sotirios Grammatikos
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • self-healing
  • capsules
  • healing agents
  • healing efficiency
  • encapsulation methods
  • micro-capsules
  • nano-capsules
  • smart materials
  • sustainability

Published Papers (1 paper)

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Research

16 pages, 5665 KiB  
Article
Capsule-Based Self-Healing and Self-Sensing Composites with Enhanced Mechanical and Electrical Restoration
by Georgios Foteinidis, Maria Kosarli, Pantelis Nikiphorides, Kyriaki Tsirka and Alkiviadis S. Paipetis
Polymers 2022, 14(23), 5264; https://doi.org/10.3390/polym14235264 - 02 Dec 2022
Cited by 2 | Viewed by 1666
Abstract
In this work, we report for the first time the manufacturing and characterization of smart multifunctional, capsule-based self-healing and self-sensing composites. In detail, neat and nanomodified UF microcapsules were synthesized and incorporated into composites with a nanomodified epoxy matrix for the restoration of [...] Read more.
In this work, we report for the first time the manufacturing and characterization of smart multifunctional, capsule-based self-healing and self-sensing composites. In detail, neat and nanomodified UF microcapsules were synthesized and incorporated into composites with a nanomodified epoxy matrix for the restoration of the mechanical and electrical properties. The electrical properties were evaluated with the use of the impedance spectroscopy method. The self-healing composites were subjected to mode-II fracture toughness tests. Additionally, the lap strap geometry that can simulate the mechanical behavior of a stiffened panel was used. The introduction of the nanomodified self-healing system improved the initial mechanical properties in the mode-II fracture toughness by +29%, while the values after the healing process exceeded the initial one. At lap strap geometry, the incorporation of the self-healing system did not affect the initial mechanical properties that were fully recovered after the healing process. Full article
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