Advances in Wood Composites V

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Biomacromolecules, Biobased and Biodegradable Polymers".

Deadline for manuscript submissions: 30 June 2024 | Viewed by 3609

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Laboratory of Wood Science, Chemistry and Technology, Department of Forestry and Natural Environment, School of Geotechnical Sciences, International Hellenic University, Thermi, Greece
Interests: wood; wood composites; lignocellulosic materials; chemical and thermal modification technologies; nanotechnology and nanomaterilas; adhesives
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Dear Colleagues,

The fibrous nature of wood has made it one of the most appropriate and versatile raw materials for various uses. However, two properties restrict its much wider use, namely its dimensional changes when subjected to fluctuating humidity and its susceptibility to biodegradation by micro-organisms. Wood can be modified chemically or thermally so that selected properties are enhanced in a more or less permanent fashion. Another option to improve these properties is to exploit the solutions that nanotechnology can offer. The nanoparticles of nanotechnology compounds are small enough to deeply penetrate the wood, effectively altering its surface chemistry and resulting in a high protection against moisture and decay. In addition, the use of lignocellulosic materials for the production of advanced wood composites is an innovative avenue for research. This collection seeks high-quality works and topics focusing on (among others) the latest approaches to the protection of wood and wood composites with chemical or thermal modification technologies, the application of nanomaterials to wood science, the application of carbon fiber fabrics, and the use of lignocellulosic materials for the production of advanced wood composites.

Prof. Dr. Antonios Papadopoulos
Guest Editor

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Keywords

  • wood
  • wood composites
  • lignocellulosic composites
  • chemical or thermal modification
  • nanotechnology and nanomaterials

Published Papers (2 papers)

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21 pages, 4307 KiB  
Article
Eco-Friendly Tannin-Based Non-Isocyanate Polyurethane Resins for the Modification of Ramie (Boehmeria nivea L.) Fibers
by Manggar Arum Aristri, Rita Kartika Sari, Muhammad Adly Rahandi Lubis, Raden Permana Budi Laksana, Petar Antov, Apri Heri Iswanto, Efri Mardawati, Seng Hua Lee, Viktor Savov, Lubos Kristak and Antonios N. Papadopoulos
Polymers 2023, 15(6), 1492; https://doi.org/10.3390/polym15061492 - 16 Mar 2023
Cited by 9 | Viewed by 1590
Abstract
This study aimed to develop tannin-based non-isocyanate polyurethane (tannin-Bio-NIPU) and tannin-based polyurethane (tannin-Bio-PU) resins for the impregnation of ramie fibers (Boehmeria nivea L.) and investigate their mechanical and thermal properties. The reaction between the tannin extract, dimethyl carbonate, and hexamethylene diamine produced [...] Read more.
This study aimed to develop tannin-based non-isocyanate polyurethane (tannin-Bio-NIPU) and tannin-based polyurethane (tannin-Bio-PU) resins for the impregnation of ramie fibers (Boehmeria nivea L.) and investigate their mechanical and thermal properties. The reaction between the tannin extract, dimethyl carbonate, and hexamethylene diamine produced the tannin-Bio-NIPU resin, while the tannin-Bio-PU was made with polymeric diphenylmethane diisocyanate (pMDI). Two types of ramie fiber were used: natural ramie without pre-treatment (RN) and with pre-treatment (RH). They were impregnated in a vacuum chamber with tannin-based Bio-PU resins for 60 min at 25 °C under 50 kPa. The yield of the tannin extract produced was 26.43 ± 1.36%. Fourier-transform infrared (FTIR) spectroscopy showed that both resin types produced urethane (-NCO) groups. The viscosity and cohesion strength of tannin-Bio-NIPU (20.35 mPa·s and 5.08 Pa) were lower than those of tannin-Bio-PU (42.70 mPa·s and 10.67 Pa). The RN fiber type (18.9% residue) was more thermally stable than RH (7.3% residue). The impregnation process with both resins could improve the ramie fibers’ thermal stability and mechanical strength. The highest thermal stability was found in RN impregnated with the tannin-Bio-PU resin (30.5% residue). The highest tensile strength was determined in the tannin-Bio-NIPU RN of 451.3 MPa. The tannin-Bio-PU resin gave the highest MOE for both fiber types (RN of 13.5 GPa and RH of 11.7 GPa) compared to the tannin-Bio-NIPU resin. Full article
(This article belongs to the Special Issue Advances in Wood Composites V)
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17 pages, 4826 KiB  
Article
The Role of Drying Schedule and Conditioning in Moisture Uniformity in Wood: A Machine Learning Approach
by Sohrab Rahimi, Vahid Nasir, Stavros Avramidis and Farrokh Sassani
Polymers 2023, 15(4), 792; https://doi.org/10.3390/polym15040792 - 04 Feb 2023
Cited by 6 | Viewed by 1469
Abstract
Monitoring the moisture content (MC) of wood and avoiding large MC variation is a crucial task as a large moisture spread after drying significantly devalues the product, especially in species with high green MC spread. Therefore, this research aims to optimize kiln-drying and [...] Read more.
Monitoring the moisture content (MC) of wood and avoiding large MC variation is a crucial task as a large moisture spread after drying significantly devalues the product, especially in species with high green MC spread. Therefore, this research aims to optimize kiln-drying and provides a predictive approach to estimate and classify target timber moisture, using a gradient-boosting machine learning model. Inputs include three wood attributes (initial moisture, initial weight, and basic density) and three drying parameters (schedule, conditioning, and post-storage). Results show that initial weight has the highest correlation with the final moisture and possesses the highest relative importance in both predictive and classifier models. This model demonstrated a drop in training accuracy after removing schedule, conditioning, and post-storage from inputs, emphasizing that the drying parameters are significant in the robustness of the model. However, the regression-based model failed to satisfactorily predict the moisture after kiln-drying. In contrast, the classifying model is capable of classifying dried wood into acceptable, over-, and under-dried groups, which could apply to timber pre- and post-sorting. Overall, the gradient-boosting model successfully classified the moisture in kiln-dried western hemlock timber. Full article
(This article belongs to the Special Issue Advances in Wood Composites V)
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