Research

17 pages, 9733 KiB

Open AccessArticle

Adsorption of an Anionic Surfactant (Sodium Dodecyl Sulfate) from an Aqueous Solution by Modified Cellulose with Quaternary Ammonium

by Ming Zou, Haixin Zhang, Naoto Miyamoto, Naoki Kano and Hirokazu Okawa

Polymers 2022, 14(7), 1473; https://doi.org/10.3390/polym14071473 - 05 Apr 2022

Cited by 2 | Viewed by 2643

Abstract

In this study, a method of removing an anionic surfactant sodium dodecyl sulfate (SDS) from an aqueous solution by cellulose modified with quaternary ammonium cation was discussed. Cellulose, as the adsorbent, was obtained from medical cotton balls, and the quaternary ammonium cation (synthesized [...] Read more.

In this study, a method of removing an anionic surfactant sodium dodecyl sulfate (SDS) from an aqueous solution by cellulose modified with quaternary ammonium cation was discussed. Cellulose, as the adsorbent, was obtained from medical cotton balls, and the quaternary ammonium cation (synthesized from dodecyl dimethyl tertiary amine and epichlorohydrin) was grafted onto the sixth hydroxyl group of D-glucose in the cellulose by the Williamson reaction under alkaline conditions. The modified cellulose was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS); and the zeta potential of the material was also measured after confirmation of the synthesis of quaternary ammonium salts by nuclear magnetic resonance (NMR). From these analyses, a peak of the quaternary ammonium group was observed at 1637 cm⁻¹; and it was found that the surface of the material exhibited a positive charge in pH 2–7. The optimal conditions for SDS adsorption by modified cellulose were pH of 7, contact time of 3 h, and temperature of 60 °C in this study. Typical adsorption isotherms (Langmuir and Freundlich) were determined for the adsorption process, and the maximal adsorption capacity was estimated as 32.5 mg g⁻¹. The results of adsorption kinetics were more consistent with the pseudo-second-order equation, indicating that the adsorption process was mainly controlled by chemical adsorption. Furthermore, thermodynamic analysis indicated that the adsorption process of SDS on the modified cellulose was endothermic and spontaneous and that an increasing temperature was conducive to adsorption. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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16 pages, 4823 KiB

Open AccessArticle

Fabrication and Characterization of Polysaccharide Metallohydrogel Obtained from Succinoglycan and Trivalent Chromium

by Dajung Kim, Seonmok Kim and Seunho Jung

Polymers 2021, 13(2), 202; https://doi.org/10.3390/polym13020202 - 08 Jan 2021

Cited by 12 | Viewed by 2531

Abstract

In the present study, a polysaccharide metallohydrogel was successfully fabricated using succinoglycan and trivalent chromium and was verified via Fourier transform infrared spectroscopy, differential scanning calorimetry analysis, thermogravimetric analysis (TGA), field emission scanning electron microscopy, and rheological measurements. Thermal behavior analysis via TGA [...] Read more.

In the present study, a polysaccharide metallohydrogel was successfully fabricated using succinoglycan and trivalent chromium and was verified via Fourier transform infrared spectroscopy, differential scanning calorimetry analysis, thermogravimetric analysis (TGA), field emission scanning electron microscopy, and rheological measurements. Thermal behavior analysis via TGA indicated that the final mass loss of pure succinoglycan was 87.8% although it was reduced to 65.8% by forming a hydrogel with trivalent chromium cations. Moreover, succinoglycan-based metallohydrogels exhibited improved mechanical properties based on the added concentration of Cr³⁺ and displayed a 10 times higher compressive stress and enhanced storage modulus (G′) of 230% at the same strain. In addition, the pore size of the obtained SCx could be adjusted by changing the concentration of Cr³⁺. Gelation can also be adjusted based on the initial pH of the metallohydrogel formulation. This was attributed to crosslinking between chromium trivalent ions and hydroxyl/carboxyl groups of succinoglycan, each of which exhibits a specific pH-dependent behavior in aqueous solutions. It could be used as a soft sensor to detect Cr³⁺ in certain biological systems, or as a soft matrix for bioseparation that allows control of pore size and mechanical strength by tuning the Cr³⁺ concentration. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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20 pages, 5939 KiB

Open AccessArticle

Synthesis, Characterization and Sorption Capacity Examination for a Novel Hydrogel Composite Based on Gellan Gum and Graphene Oxide (GG/GO)

by Cristina Modrogan, Andreea Mădălina Pandele, Constantin Bobirică, Dan Dobrotǎ, Annette Madelene Dăncilă, Gabriel Gârleanu, Oanamari Daniela Orbuleţ, Claudia Borda, Delia Gârleanu and Cristina Orbeci

Polymers 2020, 12(5), 1182; https://doi.org/10.3390/polym12051182 - 21 May 2020

Cited by 20 | Viewed by 3743

Abstract

A novel hydrogel composite based on gellan gum and graphene oxide (GG/GO) was synthesized, characterized and tested for sorption capacity in this work. The microstructural, thermogravimetric and spectroscopic analysis confirmed the formation of the GG/GO composite. Comparative batch sorption experiments revealed a sorption [...] Read more.

A novel hydrogel composite based on gellan gum and graphene oxide (GG/GO) was synthesized, characterized and tested for sorption capacity in this work. The microstructural, thermogravimetric and spectroscopic analysis confirmed the formation of the GG/GO composite. Comparative batch sorption experiments revealed a sorption capacity of the GG/GO composite for Zn (II) ions of approximately 2.3 higher than that of pure GG. The GG/GO composite exhibits a maximum sorption capacity of 272.57 mg/g at a pH of Zn (II) initial solution of 6. Generally, the sorption capacity of the sorbents is approximately 1.5 higher in slightly acidic conditions (pH 6) comparative with that for strong acidic conditions (pH 3). The sorption isotherms revealed that the sorption followed a monolayer/homogenous behavior. The sorption kinetic data were well fitted by the pseudo-second-order kinetic model, and were consistent with those derived from sorption isotherms. The intraparticle diffusion was considered to be the rate-determining step. Two main sorption mechanisms for Zn (II) were identified namely, ion exchange at low pH values, and both ion exchange and chemisorption in weekly acidic conditions. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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15 pages, 5004 KiB

Open AccessArticle

Biopolymer-Based Hybrids as Effective Admixtures for Cement Composites

by Agnieszka Ślosarczyk, Izabela Klapiszewska, Patryk Jędrzejczak, Łukasz Klapiszewski and Teofil Jesionowski

Polymers 2020, 12(5), 1180; https://doi.org/10.3390/polym12051180 - 21 May 2020

Cited by 10 | Viewed by 3821

Abstract

In the framework of this publication, silica-lignin hybrid materials were designed, obtained, characterized and then used as admixtures for cement composites. High-energy mechanical grinding of individual components was used to produce the systems that allowed ensuring adequate homogeneity of the final products. As [...] Read more.

In the framework of this publication, silica-lignin hybrid materials were designed, obtained, characterized and then used as admixtures for cement composites. High-energy mechanical grinding of individual components was used to produce the systems that allowed ensuring adequate homogeneity of the final products. As a result of the analysis of Fourier transform infrared spectroscopy, it has been confirmed that weak physical interactions occur between the components. This allowed classifying the resulting systems as I class hybrid materials. In addition, the efficiency of obtaining final products was also inferred on the basis of obtained porous structure parameters and colorimetric data. The achieved bio-admixture with different weight ratios of silica and lignin was added to cement pastes in the amount ranging from 0.5 to 1 wt.%. The study showed that increasing the ratio of lignin in the admixture from 0.15 to 1 wt.% had a positive effect on the rheological properties of the pastes, while the mechanical properties of the composite were deteriorated. In turn, a higher amount of silica in the admixture acted in reverse. The most favorable results were obtained for a silica-lignin bio-admixture with a weight ratio of components equal to 5:1 wt./wt. A significant increase in compressive strength was gained at satisfactory plasticity of the paste. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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15 pages, 13240 KiB

Open AccessArticle

Collagen Scaffolds Containing Hydroxyapatite-CaO Fiber Fragments for Bone Tissue Engineering

by Shiao-Wen Tsai, Sheng-Siang Huang, Wen-Xin Yu, Yu-Wei Hsu and Fu-Yin Hsu

Polymers 2020, 12(5), 1174; https://doi.org/10.3390/polym12051174 - 20 May 2020

Cited by 16 | Viewed by 3010

Abstract

Collagen (COL) and hydroxyapatite (HAp) are the major components of bone, therefore, COL-HAp composites have been widely used as bone substitutes to promote bone regeneration. We have reported that HAp-CaO fibers (HANFs), which were fabricated by a sol-gel route followed by an electrospinning [...] Read more.

Collagen (COL) and hydroxyapatite (HAp) are the major components of bone, therefore, COL-HAp composites have been widely used as bone substitutes to promote bone regeneration. We have reported that HAp-CaO fibers (HANFs), which were fabricated by a sol-gel route followed by an electrospinning technique, possessed good drug-loading efficiency and limited the burst release of tetracycline. In the present study, we used HANF fragments to evaluate the effects of COL-HANF scaffolds on MG63 osteoblast-like cell behaviors. COL-HANF composite scaffolds in which the average diameter of HANFs was approximately 461 ± 186 nm were fabricated by a freeze-drying process. The alkaline phosphatase activity and the protein expression levels of OCN and BSP showed that compared with COL alone, the COL-HANF scaffold promoted the differentiation of MG63 osteoblast-like cells. In addition, the bone regeneration ability of the COL-HANF scaffold was examined by using a rabbit condylar defect model in vivo. The COL-HANF scaffold was biodegradable and promoted bone regeneration eight weeks after the operation. Hence, we concluded that the COL-HANF scaffold has potential as a bone graft for bone tissue engineering. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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15 pages, 4113 KiB

Open AccessArticle

Influence of MgO-Lignin Dual Component Additives on Selected Properties of Low Density Polyethylene

by Karol Bula, Grzegorz Kubicki, Adam Kubiak, Teofil Jesionowski and Łukasz Klapiszewski

Polymers 2020, 12(5), 1156; https://doi.org/10.3390/polym12051156 - 18 May 2020

Cited by 9 | Viewed by 2438

Abstract

The presented study describes the application of lignin-based dual component fillers into low-density polyethylene (LDPE) and an examination of their selected properties. The main experimental procedure was focused on the preparation of thin sheet films using polyethylene and its composites with 5% by [...] Read more.

The presented study describes the application of lignin-based dual component fillers into low-density polyethylene (LDPE) and an examination of their selected properties. The main experimental procedure was focused on the preparation of thin sheet films using polyethylene and its composites with 5% by wt. of fillers: MgO, MgO-lignin dual phase systems with varying amounts of lignin and pristine lignin. Analysis of morphology revealed that elongated voids appeared in the structure for hybrid filler with a higher content of lignin (min. 50% by wt. of lignin versus MgO) and also for pristine lignin. Moreover, the prepared sheets were subjected to the thermoforming process by using the positive forming method (male mold). The thermoforming ability of all composites was evaluated by means of a comparison of wall thickness distribution on thermoformed shapes. The most noticeable percentage of wall thinning occurred for films which consisted of LDPE/MgO-lignin (5:1 wt./wt.) composite. In contrast, the best material arrangement and the highest mean percentage wall thickness were observed in the case of the shape formed with LDPE/MgO-lignin (1:5 wt./wt.). In addition, as part of research studies, the measurements of the contact angle have been conducted. The analysed LDPE films, in particular LDPE/MgO-L, have been recognized as materials with high wettability. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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13 pages, 3503 KiB

Open AccessArticle

Unidirectional All-Cellulose Composites from Flax via Controlled Impregnation with Ionic Liquid

by Feng Chen, Daisuke Sawada, Michael Hummel, Herbert Sixta and Tatiana Budtova

Polymers 2020, 12(5), 1010; https://doi.org/10.3390/polym12051010 - 28 Apr 2020

Cited by 16 | Viewed by 3287

Abstract

Mechanically strong all-cellulose composites are very attractive in the terms of fully bio-based and bio-degradable materials. Unidirectional flax-based all-cellulose composites are prepared via facile room-temperature impregnation with an ionic liquid, 1-ethyl-3-methyl imidazolium acetate. To determine the optimal processing conditions, the kinetics of flax [...] Read more.

Mechanically strong all-cellulose composites are very attractive in the terms of fully bio-based and bio-degradable materials. Unidirectional flax-based all-cellulose composites are prepared via facile room-temperature impregnation with an ionic liquid, 1-ethyl-3-methyl imidazolium acetate. To determine the optimal processing conditions, the kinetics of flax dissolution in this solvent is first studied using optical microscopy. Composite morphology, crystallinity, density, the volume fraction of cellulose II and tensile properties are investigated, indicating that flax dissolution should be within certain limits. On the one hand, the amount of cellulose II formed through dissolution and coagulation should be high enough to “fuse” flax fibers, resulting in a density increase. On the other hand, only the surface layer of the fibers should be dissolved to maintain the strength provided by the inner secondary layer and avoid a detrimental decrease in crystallinity. The highest Young’s modulus and strength, 10.1 GPa and 151.3 MPa, respectively, are obtained with a crystallinity of 43% and 20 vol% of cellulose II. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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18 pages, 5174 KiB

Open AccessArticle

Triply Biobased Thermoplastic Composites of Polylactide/Succinylated Lignin/Epoxidized Soybean Oil

by Jianbing Guo, Jian Wang, Yong He, Hui Sun, Xiaolang Chen, Qiang Zheng and Haibo Xie

Polymers 2020, 12(3), 632; https://doi.org/10.3390/polym12030632 - 10 Mar 2020

Cited by 15 | Viewed by 3182

Abstract

Soybean oil is beneficial to improve the compatibility between polylactide (PLA) and succinylated lignin (SAL), which leads to the preparation of a host of biobased composites containing PLA, SAL, and epoxidized soybean oil (ESO). The introduction of SAL and ESO enables the relatively [...] Read more.

Soybean oil is beneficial to improve the compatibility between polylactide (PLA) and succinylated lignin (SAL), which leads to the preparation of a host of biobased composites containing PLA, SAL, and epoxidized soybean oil (ESO). The introduction of SAL and ESO enables the relatively homogeneous morphology and slightly better miscibility obtained from triply PLA/SAL/ESO composites after dynamic vulcanization compared with unmodified PLA. The rigidity of the composites is found to decline gradually due to the addition of flexible molecular chains. According to the reaction between SAL and ESO, the T_g of PLA/SAL/ESO composites is susceptible to the movement of flexible molecular chains. The rheological behaviors of PLA/SAL/ESO under different conditions, i.e., temperature and frequency, exhibit a competition between viscidity and elasticity. The thermal stability of the composites displays a slight decrease due to the degradation of SAL and then the deterioration of ESO. The elongation at break and notched impact strength of the composites with augmentation of ESO increase by 12% and 0.5 kJ/m², respectively. The triply biobased PLA/SAL/ESO composite is thus deemed as a bio-renewable and environmentally friendly product that may find vast applications. Full article

(This article belongs to the Special Issue Biopolymer-Based Composites: Current State of Knowledge and Future Perspectives)

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