Transition Metal-Based Nanomaterials for Energy Storage and Conversion

A special issue of Nanomaterials (ISSN 2079-4991).

Deadline for manuscript submissions: closed (31 March 2021) | Viewed by 3643

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National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
Interests: 2D materials; supercapacitors; Zn batteries
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School of Environmental Science and Technology, Nanjing University of Information Science and Technology (NUIST), Nanjing 210044, China
Interests: hydrogen evolution; catalysis; chemical science
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Special Issue Information

Dear Colleagues,

Powerful electrochemical energy conversion and storage devices are considered one of the greatest challenges for our society in the rapid development of science and technology today. Rechargeable lithium-ion batteries, supercapacitors, and fuel cells are three most promising candidates in terms of energy densities and power densities. Transition metal-based nanomaterials (TMNs) including metal oxides, metal carbide, metal nitride, and metal sulfide are currently of interest for these devices because of their eco-friendly, novel size effects, significantly enhanced kinetics, and so on. Therefore, rational design of earth-abundant transition metal-based nanomaterials and understanding of their electrochemical behavior are of great importance for developing next-generation electrocatalysts or electrode materials for electrochemical energy devices. We believe that this research topic has both academic and technological importance and could offer exciting new science for cross-disciplinary areas.

Prof. Dr. Liang Huang
Prof. Dr. Yunfei Bu
Guest Editors

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Keywords

  • transition metals-based nanomaterials
  • energy conversion
  • energy storage

Published Papers (1 paper)

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Research

10 pages, 13510 KiB  
Article
Experimental and Computational Analysis of MnO2@V2C-MXene for Enhanced Energy Storage
by Mahjabeen Fatima, Syedah Afsheen Zahra, Saleem Ayaz Khan, Deji Akinwande, Jan Minár and Syed Rizwan
Nanomaterials 2021, 11(7), 1707; https://doi.org/10.3390/nano11071707 - 29 Jun 2021
Cited by 19 | Viewed by 3230
Abstract
Herein, we studied the novel and emerging group of 2D materials namely MXene along with its nanocomposites. This work entails detailed experimental as well as computational study of the electrochemical behavior of vanadium carbide (V2CTx) MXene and MnO2 [...] Read more.
Herein, we studied the novel and emerging group of 2D materials namely MXene along with its nanocomposites. This work entails detailed experimental as well as computational study of the electrochemical behavior of vanadium carbide (V2CTx) MXene and MnO2-V2C nanocomposite with varying percentages of MnO2. A specific capacitance of 551.8 F/g was achieved for MnO2-V2C nanocomposite in 1 M KOH electrolyte solution, which is more than two times higher than the gravimetric capacitance of 196.5 F/g obtained for V2C. The cyclic stability achieved for the MnO2-V2C nanocomposite resulted in a retentivity of 96.5% until 5000 cycles. The c-lattice parameter achieved for MXene is 22.6 Å, which was 13.01 Å for MAX phase. The nanocomposite resulted in a c-lattice parameter of 27.2 Å, which showed that the spatial distance between the MXene layers was efficiently obtained. The method of wet etching was used for the preparation of pristine MXene and the liquid phase precipitation method was opted for the synthesis of the MnO2-V2C nanocomposite. Density functional theory calculation was exercised so as to complement the experimental results and to understand the microscopic details, such as structure stability and electronic structure. The current report presents a comprehensive experimental and computational study on 2D MXenes for future energy storage applications. Full article
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