Metal-Based Nanomaterials: Fabrications, Optical Properties, and Ultrafast Photonics

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Inorganic Materials and Metal-Organic Frameworks".

Deadline for manuscript submissions: 25 September 2024 | Viewed by 2714

Special Issue Editors

School of Instrumentation and Optoelectronic Engineering, Beihang University, Beijing 100191, China
Interests: ultrafast lasers; frequency combs; laser absorption spectrum; nanophotonics; laser medicine; laser photonics
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Guest Editor
Dipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale A. Doria 6, 95125 Catania, Italy
Interests: plasmonic; metamaterials; sensing; photonics; optoelectronics; nonlinear optical properties; nanomedicine
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Metal-based nanomaterials have promising applications in ultrafast photonics due to their broadband operation, large third-order nonlinearity, and ultrafast recovery time. Metal-based nanomaterials, mainly divided into metal and metal oxide nanoparticles, are also gradually being considered for ultrafast photonics applications due to their outstanding optical properties. The optical properties of metal nanoparticles can be enhanced by the interaction between conduction electrons with electric fields that is called surface plasmon resonance. As for metal oxide nanoparticles, optical properties are closely related to bandgap structures. When it comes to transition metal oxides, other phenomena also play important roles in optical absorption such as spin inversion and excitons of iron. Moreover, the preparation methods of materials are also crucial for their properties and further applications. This Special Issue aims at presenting an informative and inspiring collection of articles on fabrications, optical properties, ultrafast photonics and applications of metal-based nanomaterials. Research reports and reviews are both welcomed. Researchers are invited to submit their contributions to this Special Issue.

Dr. Bo Fu
Dr. Vittorio Scardaci
Guest Editors

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Keywords

  • metal-based nanomaterials
  • metal oxide nanoparticles
  • fabrications, optical properties
  • ultrafast photonics
  • nonlinear optics
  • nanophotonics
  • laser photonics
  • ultrafast optics

Published Papers (3 papers)

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Research

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13 pages, 8859 KiB  
Communication
The Spin–Orbit Effect on the Electronic Structures, Refractive Indices, and Birefringence of X2PO4I (X = Pb, Sn, Ba and Sr): A First-Principles Investigation
by Xudong Leng, Mei Hu, Qun Jing, Haiming Duan, Henglei Chen and Xiuhua Cui
Nanomaterials 2024, 14(7), 617; https://doi.org/10.3390/nano14070617 - 01 Apr 2024
Viewed by 469
Abstract
Introducing post-transition metal cations is an excellent strategy for enhancing optical properties. This paper focuses on four isomers, namely the X2PO4I (X = Pb, Sn, Ba, and Sr) series. For the first time, the paper’s attention is paid to [...] Read more.
Introducing post-transition metal cations is an excellent strategy for enhancing optical properties. This paper focuses on four isomers, namely the X2PO4I (X = Pb, Sn, Ba, and Sr) series. For the first time, the paper’s attention is paid to the changes in electronic structure, as well as refractive indices and birefringence, with and without the inclusion of spin–orbit effects in this series. The first-principles results show that spin–orbit effects of the 5p and 6p states found in these compounds lead to splitting of the bands, narrowing of the band gap, enhancement of the lone-pair stereochemistry, and enhancement of the refractive indices and birefringence. Moreover, a comparison of the lone-pair electron phosphates, X2PO4I (X = Pb and Sn), and the isomeric alkaline earth metal phosphates, X2PO4I (X = Ba and Sr), reveals that changes in the band structure have a greater effect on the enhancement of the birefringence than the slight enhancement of the lone-pair stereochemical activity. This study has important implications for a deeper understanding of the optical properties of crystals and the design of novel optical materials. Full article
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16 pages, 1054 KiB  
Article
Nanoscatterer-Assisted Fluorescence Amplification Technique
by Sylvain Bonnefond, Antoine Reynaud, Julie Cazareth, Sophie Abélanet, Massimo Vassalli, Frédéric Brau and Gian Luca Lippi
Nanomaterials 2023, 13(21), 2875; https://doi.org/10.3390/nano13212875 - 30 Oct 2023
Viewed by 993
Abstract
Weak fluorescence signals, which are important in research and applications, are often masked by the background. Different amplification techniques are actively investigated. Here, a broadband, geometry-independent and flexible feedback scheme based on the random scattering of dielectric nanoparticles allows the amplification of a [...] Read more.
Weak fluorescence signals, which are important in research and applications, are often masked by the background. Different amplification techniques are actively investigated. Here, a broadband, geometry-independent and flexible feedback scheme based on the random scattering of dielectric nanoparticles allows the amplification of a fluorescence signal by partial trapping of the radiation within the sample volume. Amplification of up to a factor of 40 is experimentally demonstrated in ultrapure water with dispersed TiO2 nanoparticles (30 to 50 nm in diameter) and fluorescein dye at 200 μmol concentration (pumped with 5 ns long, 3 mJ laser pulses at 490 nm). The measurements show a measurable reduction in linewidth at the emission peak, indicating that feedback-induced stimulated emission contributes to the large gain observed. Full article
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Review

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38 pages, 5421 KiB  
Review
Nanocomposite Photoanisotropic Materials for Applications in Polarization Holography and Photonics
by Dimana Nazarova, Lian Nedelchev, Nataliya Berberova-Buhova and Georgi Mateev
Nanomaterials 2023, 13(22), 2946; https://doi.org/10.3390/nano13222946 - 14 Nov 2023
Cited by 1 | Viewed by 932
Abstract
Photoanisotropic materials, in particular azodyes and azopolymers, have attracted significant research interest in the last decades. This is due to their applications in polarization holography and 4G optics, enabling polarization-selective diffractive optical elements with unique properties, including circular polarization beam-splitters, polarization-selective bifocal lenses, [...] Read more.
Photoanisotropic materials, in particular azodyes and azopolymers, have attracted significant research interest in the last decades. This is due to their applications in polarization holography and 4G optics, enabling polarization-selective diffractive optical elements with unique properties, including circular polarization beam-splitters, polarization-selective bifocal lenses, and many others. Numerous methods have been applied to increase the photoinduced birefringence of these materials, and as a result, to obtain polarization holographic elements with a high diffraction efficiency. Recently, a new approach has emerged that has been extensively studied by many research groups, namely doping azobenzene-containing materials with nanoparticles with various compositions, sizes, and morphologies. The resulting nanocomposites have shown significant enhancement in their photoanisotropic response, including increased photoinduced birefringence, leading to a higher diffraction efficiency and a larger surface relief modulation in the case of polarization holographic recordings. This review aims to cover the most important achievements in this new but fast-growing field of research and to present an extensive comparative analysis of the result, reported by many research groups during the last two decades. Different hypotheses to explain the mechanism of photoanisotropy enhancement in these nanocomposites are also discussed. Finally, we present our vision for the future development of this scientific field and outline its potential applications in advanced photonics technologies. Full article
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