Noble Metal-Based Nanostructures: Optical Properties and Applications

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Nanophotonics Materials and Devices".

Deadline for manuscript submissions: 10 August 2024 | Viewed by 1123

Special Issue Editors


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Department of Electrical and Computer Engineering, Nanotechnology Imaging and Detection Laboratory University of Cyprus, Nicosia, Cyprus
Interests: metallic nanoparticles with applications in sensing; catalysis; biomedicine; SERS
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LAQV-REQUIMTE—Chemistry Department, NOVA School of Science and Technology, NOVA University Lisbon, Caparica, Portugal
Interests: chalcogenide materials; green methodologies; iron and nobel nanoparticles; rods and quantum dots
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Noble metal-based nanostructures delve into the fascinating realm of nanotechnology, specifically focusing on gold, silver, palladium, platinum, ruthenium, rhodium, and iridium. These noble metals exhibit unique optical properties at the nanoscale, making them pivotal in various applications.

Gold nanostructures are renowned for their exceptional optical properties, particularly the surface plasmon resonance phenomenon. This property is exploited in applications such as biosensing and medical diagnostics, where the interactions of gold nanoparticles with biological molecules enable sensitive detection.

Silver nanostructures likewise possess remarkable optical characteristics, including strong plasmonic responses. These properties find applications in diverse fields, such as catalysis, sensing, and imaging. Silver nanoparticles, with their tunable plasmonic resonance, contribute to advancements in medical diagnostics and therapeutics.

Palladium nanostructures showcase distinct optical properties that enhance their catalytic activity. This is crucial in catalysis applications, including environmental remediation and industrial processes. The utilization of palladium nanostructures in catalysis demonstrates their significance in sustainable and efficient chemical transformations.

Platinum nanostructures, with their unique optical signatures, play a crucial role in various applications, including fuel cells and catalysis. The exploration of their optical properties contributes to the design of efficient and stable catalysts for energy conversion and storage.

Ruthenium, rhodium, and iridium nanostructures, although less explored, exhibit promising optical properties. These metals hold potential in catalysis, sensing, and emerging technologies. The study of their optical characteristics opens avenues for novel applications in areas such as electronics and photonics.

In summary, this Special Issue underscores the significance of noble metal-based nanostructures in leveraging their optical properties for a spectrum of applications. The comprehensive exploration of gold, silver, palladium, platinum, rhodium, and iridium nanostructures provides insights into their diverse roles, paving the way for advancements in fields ranging from medicine to sustainable energy. We would like to invite specialists in the field to submit both original research papers as well as review articles on basic aspects of and future directions in this fantastic field.

Prof. Dr. Carlos Lodeiro
Dr. Adrián Fernández Lodeiro
Dr. Javier Fernandez Lodeiro
Guest Editors

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Keywords

  • noble metal-based nanostructures
  • gold nanoparticles
  • silver nanoparticles
  • optical properties

Published Papers (1 paper)

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Research

15 pages, 3212 KiB  
Article
Tryptophanhydroxamic Acid-Stabilized Ultrasmall Gold Nanoclusters: Tuning the Selectivity for Metal Ion Sensing
by Gyöngyi Gombár, Ditta Ungor, István Szatmári, Ádám Juhász and Edit Csapó
Nanomaterials 2024, 14(5), 434; https://doi.org/10.3390/nano14050434 - 27 Feb 2024
Viewed by 711
Abstract
Sub-nanometer-sized gold nanoclusters (Au NCs) were prepared via the spontaneous reduction of [AuCl4]- ions with a hydroxamate derivative of L-tryptophan (Trp) natural amino acid (TrpHA). The prepared TrpHA-Au NCs possess intense blue emission (λem = 470 nm; [...] Read more.
Sub-nanometer-sized gold nanoclusters (Au NCs) were prepared via the spontaneous reduction of [AuCl4]- ions with a hydroxamate derivative of L-tryptophan (Trp) natural amino acid (TrpHA). The prepared TrpHA-Au NCs possess intense blue emission (λem = 470 nm; λex = 380 nm) with a 2.13% absolute quantum yield and 1.47 ns average lifetime. The Trp-stabilized noble metal NCs are excellent metal ion sensors for Fe3+, but in this work, we highlighted that the incorporation of the hydroxamate functional group with an excellent metal ion binding capability can tune the selectivity and sensitivity of these NCs, which is a promising way to design novel strategies for the detection of other metal ions as well. Moreover, their simultaneous identification can also be realized. By decreasing the sensitivity of our nano-sensor for Fe3+ (limit of detection (LOD) ~11 µM), it was clearly demonstrated that the selectivity for Cu2+-ions can be significantly increased (LOD = 3.16 µM) in an acidic (pH = 3–4) condition. The surface-bounded TrpHA molecules can coordinate the Cu2+ confirmed by thermodynamic data, which strongly generates the linking of the NCs via the Cu2+ ions in acidic pH, and a parallel fluorescence quenching occurs. In the case of Fe3+, the degree of quenching strongly depends on the metal ion concentration, and it only occurs when the NCs are not able to bind more Fe3+ (~10 µM) on the surface, causing the NCs’ aggregation. Full article
(This article belongs to the Special Issue Noble Metal-Based Nanostructures: Optical Properties and Applications)
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