Novel Nanostructured Materials and Their Applications in Wastewater Treatment

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Environmental Nanoscience and Nanotechnology".

Deadline for manuscript submissions: 31 May 2024 | Viewed by 4811

Special Issue Editor


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Guest Editor
School of Materials Science & Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi’an 710021, China
Interests: nanomaterials; self-cleaning materials; catalysis; photothermal conversion

Special Issue Information

Dear Colleagues,

In recent decades, the greatest challenge in wastewater treatment has been to reduce its negative economic and environmental implications. Nanostructured materials have many unique properties, such as a large surface area, structural anisotropy, tunable bandgap, and high carrier mobility. As a result of these properties, they have attracted increasing research interest for their application in electronics, environmental pollution prevention, and catalysis, as well as in energy storage and energy conversion. Overall, nanomaterials have the potential to meet the higher effluent quality requirements and reduce the energy consumption in wastewater treatment.

This Special Issue focuses on the properties of nanostructured materials and their associated novel devices for wastewater treatment. We welcome submissions of original research-based articles and reviews related to nanostructured materials.

Dr. Yong Li
Guest Editor

Manuscript Submission Information

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Keywords

  • nanostructured materials
  • photocatalysis
  • novel device
  • wastewater treatment
  • photothermal conversion
  • interface evaporator

Published Papers (5 papers)

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Research

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18 pages, 1035 KiB  
Article
Biopolymer Meets Nanoclay: Rational Fabrication of Superb Adsorption Beads from Green Precursors for Efficient Capture of Pb(II) and Dyes
by Jie Qi, Xue Wang, Huan Zhang, Xiangyu Liu, Wenbo Wang, Qingdong He and Fang Guo
Nanomaterials 2024, 14(9), 766; https://doi.org/10.3390/nano14090766 - 26 Apr 2024
Viewed by 197
Abstract
Renewable, green, and safe natural biopolymer-derived materials are highly desired for the purification of pollutants, but significantly improving their performance without the introduction of additional harmful chemicals remains a huge challenge. Based on the concept of “structure optimization design,” environment-friendly composite beads (named [...] Read more.
Renewable, green, and safe natural biopolymer-derived materials are highly desired for the purification of pollutants, but significantly improving their performance without the introduction of additional harmful chemicals remains a huge challenge. Based on the concept of “structure optimization design,” environment-friendly composite beads (named SA/PASP/RE) with excellent adsorption performance and recyclability were rationally constructed through a green ionic crosslinking route, using the completely green biopolymer sodium alginate (SA), sodium salt of polyaspartic acid (PASP), and the natural nanoclay rectorite (RE) as starting materials. The nano-layered RE was embedded in the polymer matrix to prevent the polymer chain from becoming over-entangled so that more adsorption sites inside the polymer network were exposed, which effectively improved the mass transfer efficiency of the adsorbent and the removal rate of contaminants. The composite beads embedded with 0.6% RE showed high adsorption capacities of 211.78, 197.13, and 195.69 mg/g for Pb(II) and 643.00, 577.80, and 567.10 mg/g for methylene blue (MB) in Yellow River water, Yangtze River water, and tap water, respectively. And the beads embedded with 43% RE could efficiently adsorb Pb(II) and MB with high capacities of 187.78 mg/g and 586.46 mg/g, respectively. This study provides a new route to design and develop a green, cost-effective, and efficient adsorbent for the decontamination of wastewater. Full article
15 pages, 6906 KiB  
Article
Novel Effective Photocatalytic Self-Cleaning Coatings: TiO2-Polyfluoroalkoxy Coatings Prepared by Suspension Plasma Spraying
by Chunyan He, Jialin He, Sainan Cui, Xiujuan Fan, Shuanjian Li, Yaqi Yang, Xi Tan, Xiaofeng Zhang, Jie Mao, Liuyan Zhang and Changguang Deng
Nanomaterials 2023, 13(24), 3123; https://doi.org/10.3390/nano13243123 - 12 Dec 2023
Viewed by 831
Abstract
Photocatalytic coatings can degrade volatile organic compounds into non-toxic products, which has drawn the attention of scholars around the world. However, the pollution of dust on the coating adversely affects the photocatalytic efficiency and service life of the coating. Here, a series of [...] Read more.
Photocatalytic coatings can degrade volatile organic compounds into non-toxic products, which has drawn the attention of scholars around the world. However, the pollution of dust on the coating adversely affects the photocatalytic efficiency and service life of the coating. Here, a series of TiO2-polyfluoroalkoxy (PFA) coatings with different contents of PFA were fabricated by suspension plasma spraying technology. The results demonstrate that the hybrid coatings contain a large number of circular and ellipsoidal nanoparticles and a porous micron-nano structure due to the inclusion of PFA. According to the optimized thermal spraying process parameters, TiO2 nanoparticles were partially melted to retain most of the anatase phases, whereas PFA did not undergo significant carbonization. As compared to the TiO2 coating, the static contact angle of the composite coating doped with 25 wt.% PFA increased from 28.2° to 134.1°. In addition, PFA strongly adsorbs methylene blue, resulting in a greater involvement of methylene blue molecules in the catalyst, where the catalytic rate of hybrid coatings is up to 95%. The presented nanocomposite coatings possess excellent photocatalytic and self-cleaning properties and are expected to find wider practical applications in the field of photocatalysis. Full article
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16 pages, 5329 KiB  
Article
Carbon-in-Silicate Nanohybrid Constructed by In Situ Confined Conversion of Organics in Rectorite for Complete Removal of Dye from Water
by Qingdong He, Jie Qi, Xiangyu Liu, Huan Zhang, Yiwen Wang, Wenbo Wang and Fang Guo
Nanomaterials 2023, 13(19), 2627; https://doi.org/10.3390/nano13192627 - 23 Sep 2023
Viewed by 912
Abstract
The complete removal of low concentration organic pollutants from wastewater to obtain clean water has always been a highly desired but challenging issue. In response to this, we proposed a new strategy to fabricate a carbon-in-silicate nanohybrid composite by recycling dye-loaded layered clay [...] Read more.
The complete removal of low concentration organic pollutants from wastewater to obtain clean water has always been a highly desired but challenging issue. In response to this, we proposed a new strategy to fabricate a carbon-in-silicate nanohybrid composite by recycling dye-loaded layered clay adsorbent and converting them to new heterogeneous carbon-in-silicate nanocomposite through an associated calcination-hydrothermal activation process. It has been confirmed that most of the dye molecules were present in waste rectorite adsorbent using an intercalation mode, which can be in situ converted to carbon in the confined interlayer spacing of rectorite. The further hydrothermal activation process may further improve the pore structure and increase surface active sites. As expected, the optimal composite shows extremely high removal rates of 99.6% and 99.5% for Methylene blue (MB) and Basic Red 14 (BR) at low concentrations (25 mg/L), respectively. In addition, the composite adsorbent also shows high removal capacity for single-component and two-component dyes in deionized water and actual water (i.e., Yellow River water, Yangtze River water, and seawater) with a removal rate higher than 99%. The adsorbent has good reusability, and the adsorption efficiency is still above 93% after five regeneration cycles. The waste clay adsorbent-derived composite adsorbent can be used as an inexpensive material for the decontamination of dyed wastewater. Full article
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16 pages, 2611 KiB  
Article
Co-Carbonized Waste Polythene/Sugarcane Bagasse Nanocomposite for Aqueous Environmental Remediation Applications
by Moonis Ali Khan, Ayoub Abdullah Alqadami, Saikh Mohammad Wabaidur and Byong-Hun Jeon
Nanomaterials 2023, 13(7), 1193; https://doi.org/10.3390/nano13071193 - 27 Mar 2023
Cited by 5 | Viewed by 1076
Abstract
The conversion of worthless municipal solid wastes to valuables is a major step towards environmental conservation and sustainability. This work successfully proposed a technique to utilize the two most commonly available municipal solid wastes viz polythene (PE) and sugarcane bagasse (SB) for water [...] Read more.
The conversion of worthless municipal solid wastes to valuables is a major step towards environmental conservation and sustainability. This work successfully proposed a technique to utilize the two most commonly available municipal solid wastes viz polythene (PE) and sugarcane bagasse (SB) for water decolorization application. An SBPE composite material was developed and co-pyrolyzed under an inert atmosphere to develop the activated SBPEAC composite. Both SBPE and SBPEAC composites were characterized to analyze their morphological characteristics, specific surface area, chemical functional groups, and elemental composition. The adsorption efficacies of the composites were comparatively tested in the removal of malachite green (MG) from water. The SBPEAC composite had a specific surface area of 284.5 m2/g and a pore size of ~1.33 nm. Batch-scale experiments revealed that the SBPEAC composite performed better toward MG adsorption compared to the SBPE composite. The maximum MG uptakes at 318 K on SBPEAC and SBPE were 926.6 and 375.6 mg/g, respectively. The adsorption of MG on both composites was endothermic. The isotherm and kinetic modeling data for MG adsorption on SBPEAC was fitted to pseudo-second-order kinetic and Langmuir isotherm models, while Elovich kinetic and D-R isotherm models were better fitted for MG adsorption on SBPE. Mechanistically, the MG adsorption on both SBPE and SBPEAC composites involved electrostatic interaction, H-bonding, and π-π/n-π interactions. Full article
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Review

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23 pages, 5565 KiB  
Review
Superhydrophobic Flexible Strain Sensors Constructed Using Nanomaterials: Their Fabrications and Sustainable Applications
by Xiaodong Zhou, Hongxin Zang, Yong Guan, Shuangjian Li and Mingming Liu
Nanomaterials 2023, 13(19), 2639; https://doi.org/10.3390/nano13192639 - 26 Sep 2023
Cited by 1 | Viewed by 1381
Abstract
Superhydrophobic flexible strain sensors, which combine superhydrophobic coatings with highly sensitive flexible sensors, significantly enhance sensor performance and expand applications in human motion monitoring. Superhydrophobic coatings provide water repellency, surface self-cleaning, anti-corrosion, and anti-fouling properties for the sensors. Additionally, they enhance equipment durability. [...] Read more.
Superhydrophobic flexible strain sensors, which combine superhydrophobic coatings with highly sensitive flexible sensors, significantly enhance sensor performance and expand applications in human motion monitoring. Superhydrophobic coatings provide water repellency, surface self-cleaning, anti-corrosion, and anti-fouling properties for the sensors. Additionally, they enhance equipment durability. At present, many studies on superhydrophobic flexible sensors are still in the early research stage; the wear resistance and stability of sensors are far from reaching the level of industrial application. This paper discusses fundamental theories such as the wetting mechanism, tunneling effect, and percolation theory of superhydrophobic flexible sensors. Additionally, it reviews commonly used construction materials and principles of these sensors. This paper discusses the common preparation methods for superhydrophobic flexible sensors and summarizes the advantages and disadvantages of each method to identify the most suitable approach. Additionally, this paper summarizes the wide-ranging applications of the superhydrophobic flexible sensor in medical health, human motion monitoring, anti-electromagnetic interference, and de-icing/anti-icing, offering insights into these fields. Full article
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