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New Oxidative States for Metal Nanoclusters: Applications, Characteristics and Synthesis

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Nanochemistry".

Deadline for manuscript submissions: closed (31 August 2021) | Viewed by 4379

Special Issue Editor

Department of Medical, Oral and Biotechnological Sciences, University “G. d'Annunzio” of Chieti-Pescara, Via dei Vestini, 66100 Chieti, Italy
Interests: green synthesis; metal nanoclusters; microbiological application; biochemistry
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue aims to highlight that the chemical and physical properties of metals’ nanoparticles and nanoclusters seem to be related to their peculiar oxidative state, as suggested by high-resolution techniques (TEM, SEM, XRD) analyses.

Over the last decade, the range of applications of metals’ nanoparticles has been continuously developing given their unusual properties and features. Metals nanoclusters have been already successfully employed in many different areas, including catalysts, electronic, magnetic and optical nanomaterials, antibacterial agents, thermally conductive nanofluids, up to their inclusion into textile and cosmetics products. Recently, a strong antibiotic activity of metal nanoclusters against both planktonic and biofilm phenotypes of microorganisms and associated bacterial pathogens has also been observed. In general, the size shape and morphology of metal nanoparticles are strongly affected by the experimental conditions in which their synthesis occurs, strongly affecting the size, shape, and morphology of metal nanoparticles, as well as their physical and chemical properties.

The ultra-nanoclusters of metals are tiny particles a few nanometers in size, having optical and electronic properties that differ from larger particles due to quantum mechanics. The applications are a central topic in nanotechnology. The excited electron of metal can drop back into the valence band, releasing its energy via the emission of light (IR and FL band). The large applications of nanoclusters and nanoparticles in the last few decades serve as evidence of the potential for various field applications, such as drug delivery, antibiotics, semiconductors, and histological applications (embedding) for cell ultrastructure.

Dr. Luca Scotti
Guest Editor

Manuscript Submission Information

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Keywords

  • Nanoclusters
  • Nanoparticles
  • Metals oxidation states
  • Citotoxicity on nanoparticles
  • Hight resolution techniques
  • Electronics and biomedical field applications

Published Papers (2 papers)

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Research

9 pages, 2814 KiB  
Article
Structure and Properties of Electrochemically Synthesized Silver Nanoparticles in Aqueous Solution by High-Resolution Techniques
by Carla Gasbarri, Maurizio Ronci, Antonio Aceto, Roshan Vasani, Gianluca Iezzi, Tullio Florio, Federica Barbieri, Guido Angelini and Luca Scotti
Molecules 2021, 26(17), 5155; https://doi.org/10.3390/molecules26175155 - 25 Aug 2021
Cited by 5 | Viewed by 1822
Abstract
The aim of this work was to deeply investigate the structure and properties of electrochemically synthesized silver nanoparticles (AgNPs) through high-resolution techniques such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), Zeta Potential measurements, and matrix-assisted laser desorption/ionization time of flight mass [...] Read more.
The aim of this work was to deeply investigate the structure and properties of electrochemically synthesized silver nanoparticles (AgNPs) through high-resolution techniques such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), Zeta Potential measurements, and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF-MS). Strong brightness, tendency to generate nanoclusters containing an odd number of atoms, and absence of the free silver ions in solution were observed. The research also highlighted that the chemical and physical properties of the AgNPs seemed to be related to their peculiar oxidative state as suggested by X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction (XRPD) analyses. Finally, the MTT assay tested the low cytotoxicity of the investigated AgNPs. Full article
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13 pages, 2655 KiB  
Article
Removal of Cd(II) from Micro-Polluted Water by Magnetic Core-Shell Fe3O4@Prussian Blue
by Xinxin Long, Huanyu Chen, Tijun Huang, Yajing Zhang, Yifeng Lu, Jihua Tan and Rongzhi Chen
Molecules 2021, 26(9), 2497; https://doi.org/10.3390/molecules26092497 - 25 Apr 2021
Cited by 17 | Viewed by 2124
Abstract
A novel core-shell magnetic Prussian blue-coated Fe3O4 composites (Fe3O4@PB) were designed and synthesized by in-situ replication and controlled etching of iron oxide (Fe3O4) to eliminate Cd (II) from micro-polluted water. The core-shell [...] Read more.
A novel core-shell magnetic Prussian blue-coated Fe3O4 composites (Fe3O4@PB) were designed and synthesized by in-situ replication and controlled etching of iron oxide (Fe3O4) to eliminate Cd (II) from micro-polluted water. The core-shell structure was confirmed by TEM, and the composites were characterized by XRD and FTIR. The pore diameter distribution from BET measurement revealed the micropore-dominated structure of Fe3O4@PB. The effects of adsorbents dosage, pH, and co-existing ions were investigated. Batch results revealed that the Cd (II) adsorption was very fast initially and reached equilibrium after 4 h. A pH of 6 was favorable for Cd (II) adsorption on Fe3O4@PB. The adsorption rate reached 98.78% at an initial Cd (II) concentration of 100 μg/L. The adsorption kinetics indicated that the pseudo-first-order and Elovich models could best describe the Cd (II) adsorption onto Fe3O4@PB, indicating that the sorption of Cd (II) ions on the binding sites of Fe3O4@PB was the main rate-limiting step of adsorption. The adsorption isotherm well fitted the Freundlich model with a maximum capacity of 9.25 mg·g−1 of Cd (II). The adsorption of Cd (II) on the Fe3O4@PB was affected by co-existing ions, including Cu (II), Ni (II), and Zn (II), due to the competitive effect of the co-adsorption of Cd (II) with other co-existing ions. Full article
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