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Advances in Water Electrolysis Technology

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Electrochemistry".

Deadline for manuscript submissions: 31 July 2024 | Viewed by 976

Special Issue Editor


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Guest Editor
Guangdong Provincial Key Laboratory of Fuel Cell Technology, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China
Interests: energy materials including electrocatalysts for HER/OER/ORR and novel porous materials for electrochemical applications; electrochemical devices and engineering including water electrolyzer and proton exchange membrane fuel cells; lithium batteries and solid-state electrolytes
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Special Issue Information

Dear Colleagues,

Water electrolysis is the process of electrolyzing water (H2O) by employing a direct current to produce hydrogen and oxygen. Notably, due to its distinct feature of being pollution-free, hydrogen generation from water electrolysis is widely acknowledged as a sustainable technique for producing hydrogen. Unfortunately, the practical use of water electrolysis is constrained by the sluggish kinetics of the HER and OER. Currently, effective electrocatalysts are required to enhance the process, such as noble metals (Pt and Ir/RuO2). Nevertheless, the broad industrial use of hydrogen generation from electrolytic water is constrained by its high cost. Furthermore, despite significant advances in water electrolysis technology, industrial water electrolyzers are still confronting performance and durability challenges from key electrocatalysts. For the rational development of appropriate electrocatalysts, it is imperative to assess the performance of water electrolysis in industrial settings with various pH levels and high current densities.

This Special Issue concentrates on the design of electrocatalysts for electrolyzing water from the perspectives of physical chemistry and materials chemistry, such as electron orbitals, surface chemistry and nano-dimension. Moreover, experimental methodologies such as electron spectroscopy and spectroscopy with in situ observation and theoretical methods such as DFT calculation and molecular dynamic simulations are needed to explore the electrolysis reaction mechanism and ultimately realize a high-performance water electrolyzer.

Prof. Dr. Li Du
Guest Editor

Manuscript Submission Information

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Keywords

  • water electrolysis
  • design of electrocatalysts
  • physical chemistry
  • materials chemistry
  • electron orbitals
  • surface chemistry
  • nano-dimension
  • experimental methodologies
  • electron spectroscopy
  • spectroscopy
  • theoretical methods
  • DFT calculation
  • molecular dynamic simulations
  • electrolysis reaction mechanism
  • water electrolyzer

Published Papers (1 paper)

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Research

11 pages, 1583 KiB  
Article
Stabilizing Highly Active Ru Sites by Electron Reservoir in Acidic Oxygen Evolution
by Jiayan Wu, Zhongjie Qiu, Jiaxi Zhang, Huiyu Song, Zhiming Cui and Li Du
Molecules 2024, 29(4), 785; https://doi.org/10.3390/molecules29040785 - 08 Feb 2024
Viewed by 711
Abstract
Proton exchange membrane water electrolysis is hindered by the sluggish kinetics of the anodic oxygen evolution reaction. RuO2 is regarded as a promising alternative to IrO2 for the anode catalyst of proton exchange membrane water electrolyzers due to its superior activity [...] Read more.
Proton exchange membrane water electrolysis is hindered by the sluggish kinetics of the anodic oxygen evolution reaction. RuO2 is regarded as a promising alternative to IrO2 for the anode catalyst of proton exchange membrane water electrolyzers due to its superior activity and relatively lower cost compared to IrO2. However, the dissolution of Ru induced by its overoxidation under acidic oxygen evolution reaction (OER) conditions greatly hinders its durability. Herein, we developed a strategy for stabilizing RuO2 in acidic OER by the incorporation of high-valence metals with suitable ionic electronegativity. A molten salt method was employed to synthesize a series of high-valence metal-substituted RuO2 with large specific surface areas. The experimental results revealed that a high content of surface Ru4+ species promoted the OER intrinsic activity of high-valence doped RuO2. It was found that there was a linear relationship between the ratio of surface Ru4+/Ru3+ species and the ionic electronegativity of the dopant metals. By regulating the ratio of surface Ru4+/Ru3+ species, incorporating Re, with the highest ionic electronegativity, endowed Re0.1Ru0.9O2 with exceptional OER activity, exhibiting a low overpotential of 199 mV to reach 10 mA cm−2. More importantly, Re0.1Ru0.9O2 demonstrated outstanding stability at both 10 mA cm−2 (over 300 h) and 100 mA cm−2 (over 25 h). The characterization of post-stability Re0.1Ru0.9O2 revealed that Re promoted electron transfer to Ru, serving as an electron reservoir to mitigate excessive oxidation of Ru sites during the OER process and thus enhancing OER stability. We conclude that Re, with the highest ionic electronegativity, attracted a mass of electrons from Ru in the pre-catalyst and replenished electrons to Ru under the operating potential. This work spotlights an effective strategy for stabilizing cost-effective Ru-based catalysts for acidic OER. Full article
(This article belongs to the Special Issue Advances in Water Electrolysis Technology)
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