Minerals

Dongcao muscovite granite, as the product of the second stage of the magmatic intrusion of the Ganfang composite pluton, is closely related to the mineralization of Li–Nb–Ta rare metals in the Yifeng area. This paper aims to discuss the diagenetic age, evolutionary process, and relationship with the rare metal mineralization of Dongcao muscovite granite by using petrographic, cassiterite U–Pb dating and geochemical analyses. Petrographic analysis shows that the lithology of the Dongcao muscovite granite is medium– to fine–grained muscovite monzogranite. The cassiterite U–Pb dating results show that the diagenetic age of the Dongcao muscovite granite is 139.7 ± 6.7 Ma, which is Early Cretaceous. The geochemical analysis indicates that the rock is characterized by high Si, abundant aluminum alkalis, low Ca and Fe, and low Mg, which indicates that this granite is a strongly peraluminous rock. Moreover, the Dongcao muscovite granite is enriched with Rb, U, Ta, Pb, P, and Hf and depleted of Ba, Sr, Ti, and rare earth elements (REEs), with a tetrad effect of REEs. Based on this analysis, the Dongcao muscovite granite is a highly differentiated granite that formed in the tectonic transition from continental collisional to post–collisional settings related to the subduction of the Paleo–Pacific plate. A high degree of crystallization differentiation occurred at the early stage of magmatic evolution, resulting in the initial enrichment of Li–Nb–Ta–Sn. The melt–fluid interaction in the late stage is significant to the high enrichment of Li–Nb–Ta–Sn until the final mineralization. Full article

The organic-rich shales found in the Wufeng–Longmaxi Formation are typically deposited in oxygen-deficient reducing environments. One of the primary sources of debate revolves around the question of whether the anoxic bottom water found in these shales is either euxinic or ferruginous, and this matter remains unresolved. Previous studies have mostly focused on the Wufeng–Longmaxi Formation as a whole in order to understand the key factors that control organic matter accumulation (OMA). However, research on OMA for each member, including the Wufeng Formation (WF), the lower Longmaxi Formation (LLM), and the upper Longmaxi Formation (ULM), has been insufficient. This paper aims to investigate the palaeoenvironmental conditions and OMA mechanisms of the Wufeng–Longmaxi shales in western Hubei by integrating data on total organic carbon (TOC) content, mineral compositions, major and trace elements, and iron speciation. The results indicate that the Wufeng–Longmaxi shales were deposited under highly restricted hydrographic conditions, except for relatively open and upwelling conditions in the upper WF. Silica in the upper WF was primarily biogenic origin and not hydrothermal. Ferruginous conditions were the primary redox conditions for organic-rich shales except for minor formations in the lower LLM that were deposited under euxinic conditions. Due to the tectonic uplift caused by the Kwangsian Orogeny in the upper LLM, the palaeoenvironment was characterized by a warmer and wetter climate, high terrigenous influx, oxic conditions, and low productivity as the result of the insufficient nutrients caused by the weak upwelling, leading to the turnover of graptolite biozones from LM5 to LM6. The factors influencing OMA changed vertically. TOC contents have a highly positive correlation with Al content, indicating that terrigenous influx was the main factor affecting OMA in the WF, which significantly differed from patterns found in other regions. This suggests that the sedimentation rate of organic matter was higher than the terrigenous dilution rate during the WF stage. The combination of redox conditions and productivity were the main factors affecting OMA in the LLM, while terrigenous influx was the key factor controlling OMA in the ULM, resulting in the dilution of organic matter. Regions in the eastern Yiling block, which are close to the Qinling Ocean, show better prospects for shale gas exploration. This research will further facilitate the development of shale gas in this area. Full article

Porphyry copper ore is a vital strategic mineral resource. It is often associated with significant hydrothermal alteration, which alters the original mineralogical properties of the rock. Extracting alteration information from remote sensing data is crucial for porphyry copper exploration. However, the current method of extracting hydrothermal alteration information from ASTER remote sensing data does not consider the influence of disturbing factors, such as topography, and ignores the weak report of surface minerals, which has significant limitations. Therefore, this paper selects the Gondwana region of the East Tethys–Himalayan tectonic domain as the study area, combines waveform calculation with principal component analysis methods, proposes a spectral feature-enhanced principal component analysis (EPCA) method, and constructs a model to complete the automatic selection of principal components for each scene image. The results show that the etching information extracted by the EPCA method is significantly better than the traditional Crosta method in terms of etching area and spatial aggregation and discovers several prospective mineralization areas that have not yet been explored and exploited, such as Sakya and Xietongmen counties in Rikaze, providing theoretical support for subsequent mineralization exploration and large-scale mineral extraction. Meanwhile, obtaining the alteration information of the whole area can help to understand the distribution of mineralizing elements from a macroscopic perspective in the future, which is of great scientific significance in order to deeply analyze the formation process of metal deposits in mineralizing areas and improve the theory of porphyry mineralization. Full article

The shear mechanical properties of rock joints are crucial in assessing the stability and safety of rock structures, including slopes, rock dams, and tunnels. The yield stress serves as a pivotal point that distinguishes the linear and non-linear mechanical characteristics of rock joints. Due to its significance in risk monitoring and safety evaluation, this paper first provides an overview of the commonly employed methods for identifying the yield stress. Then, a novel displacement reduction method based on the displacement reduction coefficient is proposed and systemically examined. The comparison between the proposed method and existing methods based on shear experimental data suggests that the former is more adept at accurately determining the yield stress without subjective interference. Finally, this innovative method is employed to estimate the effects of external environmental factors on the yield stress of rock joints. Full article

Terra rossa is a reddish clay soil which is often present on the surface of limestone in regions with a Mediterranean-type climate. Its genesis is a controversial subject in terms of the origin of the parent material, from the residuum of underlying (carbonate/dolomite) bedrock in the absence/presence of an external silicate contribution (e.g., aeolian dust). Within this context the main goal of the present work was the understanding of the geochemical processes leading to the formation of the terra rossa starting from the carbonate bedrock. We report the results of a multi-method analysis on a terra rossa deposit occupying the bottom of a Quaternary karst depression on Mesozoic limestones exposed in the Murge area (Apulia Foreland, southern Italy). Geological, petrographic, textural, and chemical data were collected on karst products (reddish calcite incrustations and nodules, and fine-grained portion of terra rossa) by a detailed field mapping, optical microscopy, XRF and fusion ICP/MS analyses and by scanning electron microscope. New collected data show that the mineralogical composition of reddish incrustations and nodules is comparable, consisting of fibrous and impure calcite, detrital fragments of quartz, K-feldspar, zircon and authigenic minerals as (Mn, Ba, Ca) phases, (Al, Si, Mn, Fe, Mg, Ba, Ca) minerals, Fe-kaolinite and anatase. The prevailing minerals, instead, in the fine-grained portion of terra rossa are hematite, kaolinite, and goethite. Based on the chemical composition, and especially on REE patterns, a progressive interaction of silicate aqueous solutions (with Al, Si, Fe), containing pelite material, with the calcareous bedrock, as a source of carbonic acid, was the process driving the formation of terra rossa. Obtained results add new elements to the definition of the long-lasting question about the genetic processes responsible for the formation of terra rossa, corroborating their polygenetic origin, as result of limestone alteration in conjunction with the chemical interaction with allochthonous siliciclastic material. Full article

This paper follows up on a series of reference papers that inspired MDPI’s Topic “Stochastic Geomechanics: From Experimentation to Forward Modeling”, where global and local deformation effects on sand specimens are fully described from high-resolution boundary displacement fields, as supported by a comprehensive experimental database (which includes varying degrees of specimen’s heterogeneity) that is available to the scientific community for further study. This paper presents an elasto-plastic comparative analysis of different finite element models reproducing different sand specimen heterogeneity configurations as follows: loose, dense, and half-dense half-loose specimens. The experimental conditions for these specimens’ heterogeneity configurations were simulated with an axisymmetric finite element model. To characterize the stress-strain response obtained from the experiments, an elasto-plastic constitutive model with strain-hardening and softening laws was adopted to reproduce the sand specimens’ mechanistic response. An expert-based calibration of the numerical models accounted for both global and local effects by making use of global observations captured by the triaxial point sensors (i.e., axial force and displacement) and by local observations captured by 3D digital image correlation analysis (i.e., 3D boundary displacement fields). Results show that predictions of the proposed numerical models are in good agreement with the experimental observations, both global and local responses. The combined use of global and local observations to calibrate sand triaxial specimens sets the basis for a more comprehensive parameterization process. For the first model set, three experiments were assumed with homogeneous materials. While both dense and loose models showed good agreement with the experiments, the displacement field prediction of the half-dense half-loose layered model identified limitations in reproducing heterogeneous configurations. Afterward, the second set compared and analyzed the half-dense half-loose layered models by implementing a heterogeneous model, showing significantly better model predictions (i.e., after the implementation of the heterogeneous model, which accounts for a transition zone between the upper and lower segments). Full article

The target of this study was the tungsten Regoufe mine, whose exploitation stopped in the 1970s. When the mine closed, an unacceptable legacy constituted of mining waste tailings and the ruins of infrastructure was left behind. This work assessed the soil, plants, and water contamination in the mining area; namely their content in potentially toxic elements (PTEs). The global impact of PTEs in the Regoufe mine surface soil points to a very high to ultrahigh degree of contamination of the area having a serious ecological risk level, mainly related to As and Cd contributions. However, establishing the direct relation between As contamination and the anthropogenic effects caused by the mining process cannot be carried out in a straightforward manner, since the soils were already enriched in metals and metalloids as a result of the geological processes that gave origin to the mineral deposits. The studies performed on the plants revealed that the PTE levels in the plants were lower than in the soil, but site-specific soil concentrations in As and Pb positively influence bioaccumulation in plants. The magnetic studies showed the presence of magnetic technogenic particles concentrated in the magnetic fraction, in the form of magnetic spherules. The magnetic technogenic particles probably result from temperature increases induced by some technological process related to ore processing/mining activity. The PTEs in the surface and groundwater samples were similar and relatively low, being unlikely to pose potential health and environmental risks. Arsenic (As) constituted the exception, with levels above reference for drinking water purposes. Full article

This paper presents data on the geological position, geochemical features, main mineral composition (micas, feldspars), and melt and fluid inclusions in quartz from Aba high-silica leucocratic granitoids in the western part of the Talitsa batholith, Russian Altai. According to these new geochemical data, the granitoids are classified as S-type, meaning they are formed via the partial melting of metasedimentary source rocks. Geological data and oxygen isotope composition analysis indicate that major-phase granitoid magma evolution took place at the level of intrusion formation, whereas the parent melt of late-phase leucogranite evolved in a deeper chamber. The geochemical features (HFSE and REE, and REE spectra) of the granitoids indicate significantly higher differentiation in the late leucocratic phase. The presence of coexisting syngenetic melt and fluid inclusions shows that leucogranite magma was already saturated with volatiles in the early crystallization stages. Based on the new data presented in this work, the Aba rock formation is associated with the volatile saturation of magmatic melts, the exsolution of a fluid phase, and magma degassing. Full article

The Fule deposit is a typical Cd-, Ge- and Ga-enriched Pb-Zn deposit located in the southeast of the Sichuan–Yunnan–Guizhou Pb-Zn polymetallic ore province in China. Zoned, euhedral cubic and pentagonal dodecahedral and anhedral pyrites were observed, and they are thought to comprise two generations. First generation pyrite (Py1) is homogeneous and entirely confined to a crystal core, whereas second generation pyrite (Py2) forms bright and irregular rims around the former. Second generation pyrite also occurs as a cubic and pentagonal dodecahedral crystal in/near the ore body or as an anhedral crystal generally closed to the surrounding rock. The content of S, Fe, Co, and Ni in Py1 are from 52.49 to 53.40%, 41.91 to 44.85%, 0.19 to 0.50% and 0.76 to 1.55%, respectively. The values of Co/Ni, Cu/Ni and Zn/Ni are from 0.22 to 0.42, 0.02 to 0.08 and 0.43 to 1.49, respectively, showing that the Py1 was formed in the sedimentary diagenetic stage. However, the contents of S, Fe, Co, and Ni in Py2 are in the range from 51.67 to 54.60%, 45.01 to 46.52%, 0.03 to 0.07% and 0.01 to 0.16%, respectively. The Co/Ni, Cu/Ni and Zn/Ni values of Py2 are from 0.40 to 12.33, 0.14 to 13.70 and 0.04 to 74.75, respectively, which is characterized by hydrothermal pyrite (mineralization stage). The different δ³⁴S values of the Py1 (−34.9 to −32.3‰) and the Py2 (9.7 to 20.5‰) indicate that there are at least two different sources of sulfur in the Fule deposit. The sulfur in Py1 was derived from the bacterial sulfate reduction (BSR), whereas the sulfur in the ore-forming fluids (Py2) was derived from the thermochemical sulfate reduction (TSR). The main reasons for the different morphologies of pyrite in the regular spatial distribution in the Fule deposit are temperature and sulfur fugacity. Full article

Eight stratigraphic sections from well-exposed outcrops of the Early to Middle Miocene Tanjong Formation in the Kalabakan area, southeast Sabah, were investigated using an integrated approach, in which a comprehensive sedimentological facies analysis was linked with bulk geochemistry and palynological analyses. The integration of facies analysis, elemental CHNS, Fourier-transform infrared spectroscopy (FTIR), and palynological data provided a refined evaluation of the origin of organic matter (OM) and the reconstruction of the paleodepositional model. Seven facies associations were classified in the studied Tanjong Formation from 12 lithofacies components, interpreted as environments ranging from fluvial-deltaic to shallow marine: FA1—Floodplain, FA2—Fluvial channel, FA3—Coastal peat mires, FA4—Tidal flat, FA5—Delta front, FA6—Mouth bar, and FA7—Upper shoreface. Evaluation of the C/N ratio ranged between 4 and 48, and the total sulfur content ranged from 0.5 to 3. Elemental CHNS analysis suggests that the organic matter extracted from the coal and mudstone originated from terrestrial plants and fresh marine plankton. Accordingly, the three most prevalent FTIR spectra from the coal and mudstone samples were the OH- functional group stretching, the absorption spectrum of aromatic C=C stretching, and aromatic in-plane/out-of-plane C-H bending. Terrestrially derived organic matter within the examined samples was further validated by the predominance of aromatic compounds, and the palynological analysis indicated a back-mangrove freshwater pollen assemblage and a lower coastal plain setting proximal to the marine environment. The integrated findings from this research are vital in reconstructing a paleodepositional environment model that will improve the predictability of the petroleum system mechanisms and the future hydrocarbon potential for conventional petroleum exploration. Full article

Large-scale Mesozoic granitoids are exposed in the Greater Khingan Mountains. Their relationship with the Mongolia–Okhotsk and the Paleo-Pacific Ocean is still under discussion and a matter of debate. In this study, field observations were made and a total of 18 granitoids exposed in the vicinity of the Heihe–Baishilazi area in the northern part of the Greater Khingan Mountains were sampled for petrological, geochronological, and geochemical research. In addition, to complement this study, 90 granitic samples from the Xinghua, Dajinshan, Yili, Chabaqi, and Sankuanggou areas in the Greater Khingan Mountains were compiled in order to reveal rock assemblages, magma sources, and then inquire into the tectonic background. Zircon LA–ICP–MS U–Pb dating indicates that two samples from the Heihe area were formed in the Early Jurassic period (194.2 ± 1.4 Ma and 183.1 ± 1.3 Ma), and the εHf(t) values and TDM₂ of the zircons were mainly +5.8 to +10.7 and 528 Ma to 834 Ma, respectively, with a large variation range. The intrusive rocks from the Greater Khingan Mountains (108 in total) belonging to the T₁T₂G₁G₂ assemblage contained tonalites (T₁), trondhjemites (T₂), granodiorites (G₁), and granites (G₂). These granitoids are presented as subalkaline series in a plot of total alkali versus SiO₂ (TAS diagram), medium-K calc-alkaline and high-K calc-alkaline series on SiO₂ versus K₂O diagram, with metaluminous to peraluminous characteristics on an A/CNK versus A/NK diagram. These are shown as a MA (magnesium andesite) series and LMA (lower (or non) magnesium andesite) series on a SiO₂ versus MgO diagram, which can be further divided into the higher-pressure TTG subtype of the MA (corresponding to high-SiO₂ adakite (HSA)) series and the lower-pressure TTG subtype of LMA (corresponding to typical calc-alkaline suprasubduction zone rocks). In addition, granitoids were enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depleted in heavy rare earth elements (HREEs) and high-field-strength elements (HFSEs), corroborating a suprasubduction zone environment. Regional correlations as well as geochemical characteristics indicate that the rocks from the Greater Khingan Mountains formed in a subduction zone environment during the Early Jurassic; primary magma had presumably originated from the melting of young and hot oceanic crust under eclogite to amphibolite facies conditions. According to the spatial variation in rock assemblages (T₁T₂G₁ to G₁G₂ and G₂), we speculate that the northeastern Heihe, Baishilazi, and Xinghua areas as well as the westward Dajinshan area were adjacent to the ocean and formed an outer subduction zone, whereas the southwestward Sankuanggou, Yili, and Chabaqi areas were adjacent to the continent, forming an inner subduction zone. The distribution sites of the inner and outer subduction zones indicate southward and southwestward ocean subduction. Therefore, we propose a direct connection with southward subduction of the Mongolia–Okhotsk Ocean. Full article

Sulfide mining wastes may lead to severe environmental and human health risks. This study aims to use geochemical and ecotoxicological indicators for the assessment of the ecological risks of potentially toxic elements (PTEs) in the San Quintín mining group to categorize wastes prior to mining restoration. Ecotoxicity was evaluated using crustacean (Dahpnia magna, Thamnocephalus platyurus) and algae (Raphidocelis subcapitata) bioassays. The geochemical and mineralogical results suggested that the mining residues underwent intense weathering processes, with active processes of acidity generation and metal mobility. Total PTEs concentrations indicated that the mining materials were extremely polluted, with Pb, Zn and Cd geoaccumulation index (I_geo) values higher than 5 in more than 90% of the samples. The pollution load index (PLI) showed average values of 18.1, which classifies them as very highly polluted. The toxicity tests showed a higher toxicity for plants than crustaceans, being the highest values of toxicity related to toxic elements (Pb, Cd and Zn), electrical conductivity and to pH. This paper presents for the first time the combination of indices in the categorization of mining waste prior to its restoration. The combination of them has made it possible to categorize the waste and adapt the restoration and remediation procedures. Full article

Machine learning provides solutions to a diverse range of problems in high-dimensional datasets in geosciences. However, machine learning is generally criticized for being an enigmatic black box as it focusses on results but ignores the processes. To address this issue, we used supervised decision boundary maps (SDBM) to visually illustrate and interpret the machine learning process. We constructed a SDBM to classify the ore genetics from 1551 trace element data of apatite in various types of deposits. Attribute-based visual explanation of multidimensional projections (A-MPs) was introduced to SDBM to further demonstrate the correlation between features and machine learning process. Our results show that SDBM explores the interpretability of machine learning process and the A-MPs approach reveals the role of trace elements in machine learning classification. Combining SDBM and A-MPs methods, we propose intuitive and accurate discrimination diagrams and the most indicative elements for ore genetic types. Our work provides novel insights for the visualization application of geo-machine learning, which is expected to be a powerful tool for high-dimensional geochemical data analysis and mineral deposit exploration. Full article

Mechanical activation is known to greatly influence the reactivity of fly ashes. In this paper, we report a comparative study of the properties of alkali-activated geopolymer materials prepared using both ball-milled and attrition-milled fly ashes. Ball milling was carried out for 30 min and 60 min while attrition milling was carried out continuously in a high-speed attritor. The surface area of the raw fly ash decreased from 4017 cm²/g to 3999 cm²/g and 3912 cm²/g after ball milling for 30 min and 60 min, respectively. By contrast, the surface area of the continuously attrition-milled fly ash increased to 5545 cm²/g. Fly ash processed by continuous attrition milling showed a 50% particle size reduction to 25–38 μm, whereas fly ash ball-milled for 30 and 60 min was reduced in size by 33.4 and 42.9%. The milled fly ash samples were activated with 8 M NaOH solution and cured at 40 °C for 68 h. After curing, the samples were maintained at room temperature, and their 7-, 14-, and 28-day compressive strengths were measured. The compressive strength of the attrition-milled 28-day geopolymer paste was 24.6 MPa; that of the geopolymers ball-milled for 30 and 60 min was 23.37 MPa and 17.58 MPa, respectively; and that of the unmilled control geopolymer fly-ash-based paste was 17 MPa. The improvement in the mechanical properties is attributed to the increased gel formation resulting from the increased surface area (decreased particle size) in the fly ash glass starting material. Full article

Gold-sulfide mineralization in the Abu Zawal (Fatira) mine area, North Eastern Desert of Egypt, is related to porphyritic felsite dikes and elongate silicification zones in granitic rocks. These felsite dikes and the host granitic rocks exhibit major and trace element geochemical features typical of calc-alkaline and metaluminous I-type granites, likely originated in a late-orogenic setting. Their geochemical characteristics along with their fractionated LREE relative to HREE patterns imply either formation in a subduction-related environment or generation from subduction-modified source materials. Partial melting of subduction-metasomatized lower crustal rocks during extension following the lithospheric thickening may account for the production of such fertile, high Sr/Y and La/Yb magmas. In the Abu Zawal (Fatira) area, NE-trending altered felsite dikes, hydrothermal breccias, quartz enclaves, and wall-rock replacements are characterized by disseminations of chalcopyrite, pyrite, and rare gold. Alteration mineralogy, dominated by sericite, drusy quartz, kaolinite, calcite, and specular hematite, combined with the available fluid inclusion data suggests moderate to low temperature and near neutral pH conditions. The geochemical data of the altered wallrocks and mass balance calculations indicate significant mass losses in the altered rocks consistent with fluid/wallrock ratios higher than unity and near neutral pH conditions. Considering that the silica-rich host rocks, hydrothermal alteration, and sulfide-bearing hydrothermal quartz breccia in Fatira mine area were intuitively related to sulfur-saturated, oxidized felsic magmatism and associated hydrothermal systems, they are most likely linked to the post-subduction felsite porphyries (post-Hammamat felsites ~ 607 Ma), or pertaining to the late phases of the subaerial high-K calc-alkaline volcanics (Dokhan Volcanics ≤ 620 Ma). Full article

Copper mineralization in the Lower Paleozoic sedimentary cover of the Anti-Atlas (Morocco) is continually being revised not only to improve its mining capacity, but also to determine its origin, which remains a matter of debate. As evidenced by the various models proposed, the related research is fragmented, localized, and confusing. The origin of the Anti-Atlas Lower Paleozoic copper mineralization is shared between synergistic and epigenetic processes or a superposition of the two processes. Based on new tectono-magmatic data and a reinterpretation of the ore structural arrangement, we propose a link between the last concentration of copper deposits and the Late Triassic–Early Liassic CAMP (Central Atlantic Magmatic Province) tectono-thermal event, as evidenced by the significant concentration of copper mineralization in the three NE–SW corridors affected by extensional faults, some of which are filled with dolerite CAMP magma. The heat flow generated by the mafic dykes within these reactivated corridors causes mineralized fluids to up well into the sedimentary layers, depositing material rich in juvenile or leached copper, or even a mixture of the two. In some cases, these fluids are trapped by fracture systems that accompany passive folds initiated on normal faults. In other cases, these fluids can infiltrate bedding planes, and even karst caves, formed during carbonate exhumation. Notably, extensive NE–SW faults systematically cover the early Hercynian structures, suggesting that they belong to a post-Hercynian extensional episode. During the Late Triassic, the global fragmentation of the Pangaea supercontinent was manifested by the stretching of the continental crust at the margin of northwest Africa, with the simultaneous opening of the Central Atlantic Ocean and emplacement of CAMP magmatism. This last and often overlooked tectonothermal event must be considered in the remobilization and reconcentration of copper mineralization and other mineralization in Morocco. Full article

The present study aimed to investigate the feasibility of blended amine absorbents in improving the CO₂ alkanolamine-based absorption of multicycle integrated absorption–mineralization (multicycle IAM) under standard operating conditions (20–25 °C and 1 atm). Multicycle IAM is a promising approach that transforms CO₂ emissions into valuable products such as carbonates using amine solvents and waste brine. Previously, the use of monoethanolamine (MEA) as an absorbent had limitations in terms of CO₂ conversion and absorbent degradation, which led to the exploration of blended alkanolamine absorbents, such as diethanolamine, triethanolamine, and aminomethyl propanol (AMP) combined with MEA. The blended absorbent was evaluated in terms of the absorption performance and carbonate production in continuous cycles of absorption, precipitation/regeneration, and preparation. The results showed that the fourth cycle of the blend of 15 wt.% AMP and 5 wt.% MEA achieved high CO₂ absorption and conversion efficiency, with approximately 87% of the absorbed CO₂ being converted into precipitated carbonates in 43 min and a slight degradation efficiency of approximately 45%. This blended absorbent can improve the efficiency of capturing and converting CO₂ when compared to the use of a single MEA, which is one of the alternative options for the development of CO₂ capture and utilization in the future. Full article

Copper ore is a non-renewable resource with lower ore grades, which means that the extraction of more rock material is required to produce the same amount of copper, implying a greater consumption of materials, reagents, water, and energy. Since there is a greater amount of copper sulfide present in nature, concentration using the bubble flotation method will generate a greater number of tailings. This article discusses the environmental issues resulting from tailings dams and how multi-criteria decision analysis can help prioritize those sites in order to promote circular economy measures to compensate for and reduce the impacts of this type of waste generated by the copper mining industry. This work aims to contribute to this purpose by taking information from abandoned and non-active tailings, which are currently present as a result of the lack of regulations in times prior to environmental obligations and because they are metallurgical waste from old operations that had metal recovery rates that were much lower than the current rates. We propose a model based on the multi-criteria Promethee method to prioritize the tailings dams according to the commercial value of the existing materials in the deposits. A case study with an application of the model to 103 dams in the mining region of Coquimbo in northern Chile is shown. Full article

Deep shale gas (burial depth > 3500 m) in the Longmaxi Formation of southern Sichuan Province will be the primary target for exploration and development in China for a relatively long period. However, the lack of a physical basis for the “sweet-spots” seismic and well-logging prediction is caused by uncertainty in the rock physical properties of deep shale gas in the research area. Acoustic and hardness measurements were performed on shale samples from a deep layer of the Longmaxi Formation in southern Sichuan. Microtextural characteristics of the shale samples were also analyzed by conventional optical microscopy and scanning electron microscopy. Based on these measurements, the rock physical properties of the shale samples and control factors are discussed. It is shown that the deep shale samples have similar properties to the shallow shale in mineral composition, microtexture, and pore type. However, the organic pore in deep shale samples is relatively undeveloped, while the dissolved pores are more developed. For high-quality shale samples (total organic content > 2%), crystal quartz of biological origin forms the framework of rock samples, resulting in effective dynamic and static properties, reflecting the elastic behavior of rigid quartz aggregates. For organic-lean samples (total organic content < 2%), orientated detrital clay particles take the role of load-bearing grains. Therefore, these shale samples’ overall rock physical properties are mainly controlled by the elastic properties of “soft” clay. The load-bearing grain variation from organic-rich shale samples to organic-lean samples results in an overturned “V”-type change in terms of velocity versus content. Organic-rich shale samples also show an apparent low Poisson’s ratio. Organic-rich shale has a slight velocity–porosity trend, while organic-lean shale shows a significant velocity–porosity trend. In addition, due to the difference in rock microtexture between organic-rich and organic-lean shale, these two kinds of reservoir rocks can be discriminated in cross plots of P-wave impedance versus Poisson’s ratio and Young’s modulus versus Poisson’s ratio. Change in hardness also reflects the control of microtexture, and shale samples with biological-origin quartz as load-bearing grains show higher hardness and brittleness. However, the variation in quartz content has less of an impact on hardness and brittleness in shale samples with clay as the load-bearing grain. Our results provide an experimental basis for the geophysical identification and prediction of deep shale gas layers. Full article