Development of Novel Hydrogen Storage and Release Metal-Based Alloys and Composites

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metal Matrix Composites".

Deadline for manuscript submissions: closed (31 August 2023) | Viewed by 3685

Special Issue Editors


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Programa de Doctorado en Nanociencias y Nanotecnología, Cinvestav-IPN, Av. Instituto Politécnico Nacional 2508, Cd. de México 07360, México
Interests: hydrogen storage; HEAs; severe plastic deformation; scanning electron microscopy; X-ray spectrometry

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Department of Materials Engineering, Federal University of São Carlos, Via Washington Luiz, Km 235, São Carlos 13565-905, SP, Brazil
Interests: conventional thermomechanical processing; SPD processing (ECAP, HPT, ARB); amorphous and rapidly quenched materials; metastable and nanostructured alloys; amorphous coatings; materials for hydrogen storage; materials for implants; HEAs; physical and numerical simulation; corrosion, mechanical, and electrical properties; microstructural characterization of advanced and conventional materials by electron microscopy
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Morelia Unit of Materials Institute Research, UNAM, Antigua Carretera a Pátzcuaro No. 8701, Col. Ex. Hacienda de San José de la Huerta, Morelia C.P. 58190, México
Interests: hydrogen storage materials; cryogenic processing (ball-milling); characterization by synchrotron techniques

Special Issue Information

Dear Colleagues,

As a result of the drive to mitigate climate change and ensure energy security, technologies related to hydrogen generation, transportation, storage, and use are being keenly pursued in many different parts of the world. However, hydrogen storage has not seen remarkable advancement in the last decade compared to other technologies. Hydrogen storage materials based on metal and alloys have been the subject of research for many years. There is extensive literature on Mg-based alloys, different types of transition metal and rare-earth intermetallic compounds, and high-entropy alloys, which have shown exciting hydrogen storage properties. By now, however, it should be clear that it is unlikely that a unique material will be found to satisfy all the different requirements imposed by the multiple applications envisioned for hydrogen in the coming years. Consequently, continuing efforts to develop novel metal-based hydrogen-storage materials and bring them closer to practical applications are of interest to the scientific and engineering communities.

This Special Issue aims to highlight current research works which provide new insights into the synthesis, characterization, and properties of metallic alloys and metal-matrix composites under study and development for hydrogen storage applications. Contributions exploring the relationships between microstructure and storage capacity, hydrogenation and dehydrogenation kinetics, and cyclic and environmental stability are particularly welcome. In addition, computational methods for predicting phases in multicomponent systems, reaction kinetics, and alloy design are also of great importance for the progress in this research topic. Finally, studies focused on the scale-up of research experiences into pilot-plant developments will be highly useful for the overall assessment of state-of-the-art hydrogen storage. Therefore, we are pleased to invite submissions on recent research on hydrogen storage in metal-based alloys and composites, as well as critical reviews on the subject, which may help to guide future efforts on this significant technological challenge.

Dr. José Gerardo Cabañas-Moreno
Prof. Dr. Alberto Moreira Jorge Junior
Dr. Karina Suarez Alcantara
Guest Editors

Manuscript Submission Information

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Keywords

  • hydrogen storage
  • metals and alloys
  • metal-matrix composites
  • hydrogenation and dehydrogenation kinetics
  • Mg-based alloys
  • intermetallic compounds
  • high-entropy alloys
  • computational alloy design
  • enabling technologies

Published Papers (2 papers)

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Research

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14 pages, 4219 KiB  
Article
Analysis of the Use of Recycled Aluminum to Generate Green Hydrogen in an Electric Bicycle
by Xavier Salueña Berna, Marc Marín-Genescà and José María Dagà-Monmany
Metals 2023, 13(2), 357; https://doi.org/10.3390/met13020357 - 10 Feb 2023
Cited by 2 | Viewed by 1682
Abstract
This article proposes using recycled aluminum, generating hydrogen in situ at low pressure, to power a 250 W electric bicycle with a fuel cell (FC), to increase the average speed and autonomy compared to a conventional electric bicycle with a battery. To generate [...] Read more.
This article proposes using recycled aluminum, generating hydrogen in situ at low pressure, to power a 250 W electric bicycle with a fuel cell (FC), to increase the average speed and autonomy compared to a conventional electric bicycle with a battery. To generate hydrogen, the aluminum–water reaction with a 6 M NaOH solution is used as a catalyst. This article details the parts of the generation system, the electronic configuration used, the aluminum- and reagent-loading procedure and the by-products obtained, as well as the results of the operation without pedaling, with a resistance equivalent to a flat terrain and at maximum power of the accelerator for one and two loads of about 100 g of aluminum each. This allows us to observe different hybrid strategies, with a low-capacity battery in each case. The goal is to demonstrate that it is possible to store energy in a long-lasting, transportable, low-pressure, and sustainable manner, using recycled-aluminum test tubes, and to apply this to mobility. Full article
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Review

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32 pages, 9531 KiB  
Review
A Review on Oxygen-Deficient Titanium Oxide for Photocatalytic Hydrogen Production
by Yan Chen, Xiuli Fu and Zhijian Peng
Metals 2023, 13(7), 1163; https://doi.org/10.3390/met13071163 - 22 Jun 2023
Cited by 3 | Viewed by 1527
Abstract
Photocatalytic technology based on the specific band structure of semiconductors offers a promising way to solve the urgent energy and environmental issues in modern society. In particular, hydrogen production from water splitting over semiconductor photocatalysts attracts great attention owing to the clean source [...] Read more.
Photocatalytic technology based on the specific band structure of semiconductors offers a promising way to solve the urgent energy and environmental issues in modern society. In particular, hydrogen production from water splitting over semiconductor photocatalysts attracts great attention owing to the clean source and application of energy, which highly depends on the performance of photocatalysts. Among the various photocatalysts, TiO2 has been intensively investigated and used extensively due to its outstanding photocatalytic activity, high chemical stability, non-toxicity, and low cost. However, pure TiO2 has a wide band gap of approximately 3.2 eV, which limits its photocatalytic activity for water splitting to generate hydrogen only under ultraviolet light, excluding most of the inexhaustible sunlight for human beings. Fortunately, the band gap of semiconductors can be manipulated, in which introducing oxygen defects is one of the most effective measures to narrow the band gap of titanium oxides. This review considers the fundamentals of photocatalytic water splitting for hydrogen production over TiO2, discusses the latest progress in this field, and summarizes the various methods and strategies to induce oxygen defects in TiO2 crystals. Then, the next section outlines the modification approaches of oxygen-deficient titanium oxide (TiO2−δ) to further improve its photocatalytic performance. Finally, a brief summary and outlook of the studies on TiO2−δ photocatalysts for water splitting to produce hydrogen are presented. Full article
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