High Temperature Oxidation Behavior of Alloys

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metallic Functional Materials".

Deadline for manuscript submissions: 15 July 2024 | Viewed by 1103

Special Issue Editor


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National Center for Metallurgical Research (CENIM, CSIC), Ave. Gregorio del Amo 8, 28040 Madrid, Spain
Interests: high temperature oxidation of metals and alloys
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Special Issue Information

Dear Colleagues,

One of the challenges facing many processes in the chemical, petro-chemical and pharmaceutical industries, energy conversion power plants, airplane turbines and waste treatment installations is an increase in the efficiency, a way for reducing emissions of polluting gases and waste. One way to achieve these goals is by increasing temperature and/or pressure. In all these applications, most of them working under hostile environments/atmospheres, the use of more resistant alloys, mainly regarding creep and oxidation resistance, working would result in the prolonged half-lives of the components. This would increase the productivity of the process and reduce the maintenance costs, extending the shutdown periods required for the inspection of installations.

This issue is dedicated to presenting new results, providing new advances in the field of high-temperature oxidation of metallic materials in different types of atmospheres, such as air, CO2, vapour-containing atmospheres, steam, as well as the oxidation behaviour under subcritical and supercritical applications involving high temperatures and high-pressure processes. Studies aiming to unveil the effect of compositional changes or microstructural changes associated with the processing route on the kinetics, the structure of the oxide scale, and the oxidation mechanism are welcome. Additionally, manuscripts evaluating the effect of variables related to the atmosphere (composition, temperature, pressure, etc.)  or those modelling the oxidation behaviour of the alloys match the scope of this Special Issue. Contributions are not limited to structural materials for high-temperature applications, such as superalloys, high/medium entropy alloys, refractory alloys, intermetallic-based alloys or multiprincipal complex alloys, but also could involve other applications and metallic materials, which could undergo degradation as a result of exposure to high temperatures.

Dr. Pablo Pérez Zubiaur
Guest Editor

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Keywords

  • high temperature oxidation
  • superalloys
  • high/medium entropy alloys
  • intermetallic based alloys
  • oxidation kinetics
  • oxidation modelling
  • oxidation mechanism

Published Papers (1 paper)

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Research

14 pages, 4052 KiB  
Article
Oxidation Behavior of Pure Iron under Hydrogen Combustion Environment
by Michihisa Fukumoto, Seiya Hara and Hiroki Takahashi
Metals 2023, 13(7), 1246; https://doi.org/10.3390/met13071246 - 08 Jul 2023
Viewed by 835
Abstract
The environmental resistance of pure iron was evaluated by an oxygen and hydrogen sensor installed after an oxidation furnace. The amount of introduced oxygen was precisely controlled by the oxygen pump sensor at the front stage of the oxidation furnace, and the reaction [...] Read more.
The environmental resistance of pure iron was evaluated by an oxygen and hydrogen sensor installed after an oxidation furnace. The amount of introduced oxygen was precisely controlled by the oxygen pump sensor at the front stage of the oxidation furnace, and the reaction with hydrogen was analyzed. Thus, when oxygen was supplied, a reaction between hydrogen and oxygen occurred; however, when the supplied oxygen was not sufficient, a hydrogen-vapor environment was created, and oxidation was not accelerated. Conversely, when the amount of supplied oxygen was excessive, the environment became an oxygen–steam environment, and oxidation was accelerated. Therefore, this explained how the oxidation caused by oxygen was dominant under the oxygen–water vapor environment, and the oxidation weight gain increased. In addition, the border of the region dominated by oxygen oxidation and steam oxygen was clarified by precisely controlling the amount of oxygen supplied by the oxygen pump sensor. Full article
(This article belongs to the Special Issue High Temperature Oxidation Behavior of Alloys)
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

Title: Experimental determination of multiple mechanisms of surface degradation at extreme oxidation condition
Authors: Simon N. Lekakh; Oleg Neroslavsky
Affiliation: Missouri University of Science and Technology
Abstract: Methodology of experimental determination of multiple mechanisms simultaneously involved in surface degradation, including development of oxide scale, scale spallation and species volatilization will be discussed. General problem will be formalized and specific cases will be presented. Experimental data for Cr/Ni austenitic steel and high alloyed by Si/Mo cast iron will be used to illustrate suggested approaches.

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