Advanced Pd Composite Membranes

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Inorganic Membranes".

Deadline for manuscript submissions: closed (31 October 2020) | Viewed by 2269

Special Issue Editor


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Guest Editor
Clean Energy Institute, Korea Institute of Science and Technology, Seoul 136-791, Korea
Interests: hydrogen separation; ultrathin dense Pd composite membrane; vacuum electroless plating; renewable hydrogen; sputtering system; membrane reactors; LOHC

Special Issue Information

Dear Colleagues,

An alternative energy carrier, namely hydrogen (H2), is easily produced from the chemical reagents by using a proper catalyst via a dehydrogenation reaction and H2 facilitates the production of electricity using H2 fuel cells. Generally, H2-fuel cells need high purity H2 (>99.999%) with less than 1 ppm of CO.

Therefore, it is important to develop efficient and continuous hydrogen separation and purification techniques for the upcoming ‘hydrogen economy’. A potential technique corresponds to membrane separation that does not require a regeneration procedure. Furthermore, a membrane reactor is also applied in various catalytic reaction processes to shift thermodynamic equilibrium via Le Chatelier’s principle.

Palladium is the material that is the most examined as a H2 selective membrane due to its relatively fast and unique permeation mechanism. However, Pd membranes are limited in terms of practical industrial applications because of the high material cost and H2 embrittlement issues at low temperature under H2 atmosphere. In order to solve the problems, porous substrates and Pd-alloying schemes are employed to fabricate composite membranes that avoid H2-embrittlement under targeted operation temperatures.

Dr. Sun Hee Choi
Guest Editor

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Keywords

  • palladium composite membranes
  • ultrathin palladium membranes
  • electroless plating
  • sputtering
  • membrane reactor
  • renewable hydrogen

Published Papers (1 paper)

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Research

17 pages, 4989 KiB  
Article
Thermodynamic Analysis of Methylcyclohexane Dehydrogenation and Solar Energy Storage via Solar-Driven Hydrogen Permeation Membrane Reactor
by Hongsheng Wang, Bingzheng Wang, Hui Kong, Xiaofei Lu and Xuejiao Hu
Membranes 2020, 10(12), 374; https://doi.org/10.3390/membranes10120374 - 27 Nov 2020
Cited by 12 | Viewed by 2065
Abstract
A novel methylcyclohexane (MCH) dehydrogenation system driven by solar energy with a hydrogen permeation membrane (HPM) reactor is proposed in this study. It is a promising method, via this novel system, to generate pure hydrogen and store intermittent solar energy. In this research, [...] Read more.
A novel methylcyclohexane (MCH) dehydrogenation system driven by solar energy with a hydrogen permeation membrane (HPM) reactor is proposed in this study. It is a promising method, via this novel system, to generate pure hydrogen and store intermittent solar energy. In this research, the thermodynamic analysis of MCH dehydrogenation via the HPM reactor was conducted based on numerical simulation. The conversion rates and thermodynamic efficiencies under different temperatures (150–350 °C), permeate pressures from 0.001 to 0.5 bar, and solar irradiation in the four seasons were studied and analyzed. Under a hydrogen partial pressure difference, HPM can separate hydrogen and shift the reaction equilibrium forward for a higher conversion rate of MCH, which can reach nearly 99.7% in this system. The first-law of thermodynamic efficiency, the solar-to-fuel efficiency, and the exergy efficiency are up to 95.58%, 38.65%, and 94.22%, respectively. This study exhibits the feasibility and potential of MCH dehydrogenation via the HPM reactor driven by solar energy and provides a novel approach for solar energy storage. Full article
(This article belongs to the Special Issue Advanced Pd Composite Membranes)
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