Advanced Research on Thin-Film Composite Membranes

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Membrane Applications".

Deadline for manuscript submissions: closed (31 October 2022) | Viewed by 3056

Special Issue Editors


E-Mail Website
Guest Editor
Department of Chemical Engineering, Khwaja Fareed University of Engineering & Information Technology (KFUEIT), Rahim Yar Khan 64200, Pakistan
Interests: membrane technology; anion exchange membranes (AEMs) for fuel cell; synthesis of novel materials for aems; fuel cell; flow batteries; electrolysis

E-Mail Website
Guest Editor
School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China
Interests: fuel cell and secondary battery materials; functional polymer; nanomaterials and technology

E-Mail Website
Guest Editor
College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China
Interests: advanced metal and alloys; composite materials; microstructure characterizations and mechanical properties
Department of Chemical Engineering, Minhaj University Lahore, Lahore 54000, Pakistan
Interests: pervaporation membrane; molecular dynamics simulation; wastewater treatment

Special Issue Information

Dear Colleagues,

Thin-film composite membranes are semipermeable membranes designed to be used in water desalination and purification systems. They are also used in chemical processes as fuel cells and batteries. A thin film composite (TFC) membrane is a molecular sieve made up of two or more layered materials that are formed into a film. The three-layer structure provides strong rejection of unwanted elements (such as salts), a high filtering rate, and superior mechanical strength. The high rejection is due to the polyamide top layer, which was chosen for its water permeability and relative impermeability to different dissolved contaminants, such as salt ions and additional tiny, un-filterable molecules.

The invention of thin film composite membranes, which consist of a very thin (barrier) layer polymerized in situ atop a porous polymeric support membrane, was a major milestone in the area of membrane separations. Although TFC is a registered trademark of Koch Membrane Systems, Inc. in the United States and other countries, these membranes are commonly referred to as “interfacial composites”, “composites”, or “TFC” membranes. The chemistry, and hence the performance, of the top selective layer and the porous support layer may be individually chosen to improve composite membrane performance, which is a key benefit of TFC membranes over integrally skinned asymmetric membranes.

Furthermore, because the selective layer only accounts for a tiny part of the entire material, more expensive monomers may be employed to produce it without significantly raising the cost. The search of high-selectivity, high-flux RO membranes for the desalination of seawater was one of the primary drivers driving the development of TFC membrane materials during the last 40–50 years. Low-pressure RO membranes for desalting brackish water and purifying wastewater to near-ultrapure levels were developed along the way, as were NF membranes, which are today mostly employed for dissolved organic removal and water softening.  

This Special Issue focuses on advanced fabrication methods of “Thin Film Composite Membranes”, such as interlayer deposition, layer-by-layer deposition, thin film nanocomposite fabrications by various nanomaterials, and other novel methods for the synthesis of thin-film selective layers on porous substrates for a variety of applications, i.e., separation, fuel cell. etc. Authors are encouraged to submit their most recent findings and conclusions, including original articles and reviews.

Dr. Naeem Akhtar Qaisrani
Prof. Dr. Fengxiang Zhang
Dr. Muhammad Abubaker Khan
Dr. Ali Ahmad
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Membranes is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • thin film composite membrane
  • membrane for fuel cell
  • AEM or PEM
  • nanomaterials
  • layer-by-layer deposition
  • interlayer deposition
  • novel synthesis approaches
  • novel polymeric material

Published Papers (2 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

12 pages, 3265 KiB  
Communication
Synthesis and Characterization of Electrical and Thermal Conductive Vinyltriethoxysilane Functionalized Graphene Oxide/Poly (Methyl Methacrylate) Nanocomposite Films
by Srosh Fazil, Khurram Liaqat, Wajid Rehman and Magda H. Abdellatif
Membranes 2023, 13(6), 609; https://doi.org/10.3390/membranes13060609 - 20 Jun 2023
Cited by 1 | Viewed by 1091
Abstract
The present study is an attempt to improve thermal, mechanical and electrical properties of poly (methyl methacrylate) (PMMA). For this purpose, vinyltriethoxysilane (VTES) was grafted covalently on the surface of graphene oxide (GO). This VTES functionalized graphene oxide (VGO) was dispersed in the [...] Read more.
The present study is an attempt to improve thermal, mechanical and electrical properties of poly (methyl methacrylate) (PMMA). For this purpose, vinyltriethoxysilane (VTES) was grafted covalently on the surface of graphene oxide (GO). This VTES functionalized graphene oxide (VGO) was dispersed in the PMMA matrix using the solution casting method. The morphology of the resultant PMMA/VGO nanocomposites was analyzed by SEM indicating well-dispersed VGO in the PMMA matrix. Thermal stability, tensile strength and thermal conductivity increased by 90%, 91% and 75%, respectively, whereas volume electrical resistivity and surface electrical resistivity reduced to 9.45 × 105 Ω/cm and 5.45 × 107 Ω/cm2, respectively. Full article
(This article belongs to the Special Issue Advanced Research on Thin-Film Composite Membranes)
Show Figures

Figure 1

11 pages, 1453 KiB  
Article
Antimicrobial Properties of a Copper/Silicone Composite Membrane Prepared Using a Two-Step Immersion Process in Iodine and Copper Sulfate Solutions
by Junpei Takeshita, Shiho Aoki, Risei Wada, Ayako Osawa and Jun Sawai
Membranes 2022, 12(11), 1049; https://doi.org/10.3390/membranes12111049 - 27 Oct 2022
Cited by 1 | Viewed by 1447
Abstract
Silicone (polydimethylsiloxane) materials are widely used in various applications. Due to microbe adherence and biofilm formation at the surface of silicone materials, silicone materials must possess antibacterial properties. To achieve this, we prepared copper (Cu)–silicone composite membranes using a simple two-step process of [...] Read more.
Silicone (polydimethylsiloxane) materials are widely used in various applications. Due to microbe adherence and biofilm formation at the surface of silicone materials, silicone materials must possess antibacterial properties. To achieve this, we prepared copper (Cu)–silicone composite membranes using a simple two-step process of immersion in iodine and copper sulfate solutions. Subsequent scanning electron microscopy revealed Cu nanoparticles (CuNPs) of 10 to 200 nanometers in diameter on the silicone membrane surface, which were identified as copper iodide using energy-dispersive X-ray spectroscopy. The mechanical strength of the material did not change significantly as a result of the two-step immersion treatment and the Cu/silicone membrane showed excellent antibacterial efficacy against Escherichia coli and Staphylococcus aureus, maintaining R > 2 even after a physical impact such as stomacher treatment. Additionally, the Cu ions eluted from the Cu/silicone membrane remained at very low concentrations, suggesting firm immobilization of CuNPs on the silicone membrane. This proposed antimicrobial treatment method does not require special equipment, can be performed at room temperature, and has the potential for use on silicone materials other than membranes. Full article
(This article belongs to the Special Issue Advanced Research on Thin-Film Composite Membranes)
Show Figures

Figure 1

Back to TopTop