2D Materials for Membrane Distillation

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Membrane Analysis and Characterization".

Deadline for manuscript submissions: closed (30 November 2023) | Viewed by 2061

Special Issue Editors


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Guest Editor
Laboratoire de Physique des Matériaux, Faculté des Sciences de Bizerte, 7021 Jarzouna, Tunisia
Interests: 2D materials; nanostructures; quantum optics; electronic of few-particle states (excitons, electron-phonon, polarons, thermoplasmons) semi-magnetic nanostructures with spin states, entanglement) in quantum dots; quantum optic through organic-inorganic heterostructures and hybrid microcavities

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Guest Editor
Department of Environmental Engineering, University of Calabria, 87036 Rende, CS, Italy
Interests: polymeric membranes; mixed-matrix membranes; nanotechnologies; thermoplasmonics; molecular probes; active coatings; electrospinning; desalination; solar-driven membrane distillation; gradient salinity energy; zero liquid discharge; circular economy
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Special Issue Information

Dear Colleagues,

Membrane Distillation (MD) has emerged as a hybrid thermal/membrane technology having the potential to demineralize saltwater (included natural and anthropic brine) at recovery factors above the value of 50 % typical for Reverse Osmosis (RO).

The recent achievements in MD process optimization have opened the door for the commercialization of MD modules. However, hydrophobic microfiltration (MF) membranes are usually employed in MD applications; thus, there is a lack in terms of membranes specifically optimized for MD. Definitively, the development of membranes exclusively designed for MD characterized -especially characterized by poor wetting and fouling/scaling tendencies- is an imperative.

In recent years, the rapid growth of interest in fundamental studies and engineering of Two-dimensional (2D) materials suggests the realization of high-performance separation and distillation membranes. The unique atomic thickness of 2D materials stimulates the continued search for ultrathin and selective membranes for separation. Many different breakthroughs in recent decades have been accomplished towards the exfoliation and perforation of monolayers implementing pioneering nanosheet membranes for molecular separation. Different 2D materials including graphene, graphene oxide, MXenes, layered transition metal dichalcogenides (TMDs), layered zeolites, 2D metal organic, 2D covalent organic have been embedded into polymeric membranes exploited in MD process. When incorporated in polymeric membranes, 2D materials conferred to the membranes highly desirable properties for MD applications, such as facilitated water transport, enhancement of the salt rejection and long-term stability. Moreover, recent studies have demonstrated the opportunity to exploit 2D materials (i.e. graphene and tungsten disulfide) as photothermal filler in membranes enabling efficient light-to-heat conversion under the solar radiation exploitable to boost the performance and reduce the specific energy consumption of the process paving the way for the advent of photothermal MD. 

This Special Issue entitled “2D Materials for Membrane Distillation" aims to gather the focal points of developments of novel membranes for MD process based on the employment of 2D materials.

Related topics include but are not limited to:

  • Novel 2D materials in membrane preparation;
  • New approaches in the embodiment of 2D materials in membranes;
  • 2D materials in enhancement of the performance of MD process;
  • New areas of application of membranes based on 2D materials.

Prof. Dr. Sihem Jaziri
Dr. Sergio Santoro
Guest Editors

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Published Papers (2 papers)

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Research

18 pages, 3769 KiB  
Article
Environmentally Friendly Photothermal Membranes for Halite Recovery from Reverse Osmosis Brine via Solar-Driven Membrane Crystallization
by Marco Aquino, Sergio Santoro, Antonio Politano, Giuseppe D’Andrea, Alessio Siciliano, Salvatore Straface, Mauro Francesco La Russa and Efrem Curcio
Membranes 2024, 14(4), 87; https://doi.org/10.3390/membranes14040087 - 10 Apr 2024
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Abstract
Modern society and industrial development rely heavily on the availability of freshwater and minerals. Seawater reverse osmosis (SWRO) has been widely adopted for freshwater supply, although many questions have arisen about its environmental sustainability owing to the disposal of hypersaline rejected solutions (brine). [...] Read more.
Modern society and industrial development rely heavily on the availability of freshwater and minerals. Seawater reverse osmosis (SWRO) has been widely adopted for freshwater supply, although many questions have arisen about its environmental sustainability owing to the disposal of hypersaline rejected solutions (brine). This scenario has accelerated significant developments towards the hybridization of SWRO with membrane distillation–crystallization (MD-MCr), which can extract water and minerals from spent brine. Nevertheless, the substantial specific energy consumption associated with MD-MCr remains a significant limitation. In this work, energy harvesting was secured from renewables by hotspots embodied in the membranes, implementing the revolutionary approach of brine mining via photothermal membrane crystallization (PhMCr). This method employs self-heating nanostructured interfaces under solar radiation to enhance water evaporation, creating a carefully controlled supersaturated environment responsible for the extraction of minerals. Photothermal mixed matrix photothermal membranes (MMMs) were developed by incorporating graphene oxide (GO) or carbon black (CB) into polyvinylidene fluoride (PVDF) solubilized in an eco-friendly solvent (i.e., triethyl phosphate (TEP)). MMMs were prepared using non-solvent-induced phase separation (NIPS). The effect of GO or GB on the morphology of MMMs and the photothermal behavior was examined. Light-to-heat conversion was used in PhMCr experiments to facilitate the evaporation of water from the SWRO brine to supersaturation, leading to sodium chloride (NaCl) nucleation and crystallization. Overall, the results indicate exciting perspectives of PhMCr in brine valorization for a sustainable desalination industry. Full article
(This article belongs to the Special Issue 2D Materials for Membrane Distillation)
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15 pages, 5101 KiB  
Article
Wetting-Based Comparison of Ag, Carbon Black, and MoS2 Composite Membranes for Photothermal Membrane Distillation
by Tarik Eljaddi and Corinne Cabassud
Membranes 2023, 13(9), 780; https://doi.org/10.3390/membranes13090780 - 04 Sep 2023
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Abstract
Photothermal membrane distillation is a new-generation desalination process that can take advantage of the ability of specific materials to convert solar energy to heat at the membrane surface and thus to overcome temperature polarization. The development of appropriate photothermal membranes is challenging because [...] Read more.
Photothermal membrane distillation is a new-generation desalination process that can take advantage of the ability of specific materials to convert solar energy to heat at the membrane surface and thus to overcome temperature polarization. The development of appropriate photothermal membranes is challenging because many criteria need to be considered, including light to heat conversion, permeability and low wetting, and fouling, as well as cost. Based on our experience with wetting characterization, this study compares photothermal membranes prepared using different well-known or promising materials, i.e., silver nanoparticles (Ag NPs), carbon black, and molybdenum disulfide (MoS2), in terms of their structural properties, permeability, wettability, and wetting. Accordingly, membranes with different proportions of photothermal NPs are prepared and fully characterized in this study. Wetting is investigated using the detection of dissolved tracer intrusion (DDTI) method following membrane distillation operations with saline solutions. The advantages of MoS2 and carbon black-based photothermal membranes in comparison with polyvinylidene difluoride (PVDF) membranes include both a permeability increase and a less severe wetting mechanism, with lower wetting indicators in the short term. These materials are also much cheaper than Ag NPs, having higher permeabilities and presenting less severe wetting mechanisms. Full article
(This article belongs to the Special Issue 2D Materials for Membrane Distillation)
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