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Inorganic Nanoparticle-Polymer Composites

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Composites".

Deadline for manuscript submissions: closed (20 November 2022) | Viewed by 1818

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Department of Inorganic Chemistry, Complutense University of Madrid, Madrid, Spain
Interests: functional nanomaterials; oxides; electron microscopy; electrical properties
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Special Issue Information

Dear Colleagues,

In recent years, the research and development of inorganic nanoparticles and polymer composites have attracted interest in many technological areas, with the aim of improving the properties of the functional materials. The most commonly used compounds include carbon allotropies or organic polymers, while metallic and semiconducting nanomaterials are usually used as the inorganic counterparts.

One of the most important factors is the fact that they can be easily manipulated using different shaping technologies (e.g., chemical deposition, spin-coating, 3D printing). Other factors include their light weight, low deposition cost at ambient conditions, solution-based manufacturability, excellent adhesion, and easy scalability. In this way, the current possibilities of functional nanomaterials can be expanded with great repercussions at an industrial level in a wide range of sectors including wind energy, electric vehicles, sensors, actuators, catalysis, and optoelectronics applications.

One of the problems preventing the use of nanomaterials is the usage of standard manufacturing processes based on sintering, pressing, and molding, which restricts the possible shapes and ultimately results in limitations in applications. Therefore, the search for new inorganic nanoparticle–polymer composites is a priority area of materials research. A good example of this is represented by semiconductor nanoparticles (SnO, SnO2, TiO2, Ga2O3, Cr2O3, NiO, and Si) used as inorganic counterparts, which are embedded into a conductive polymer (PEDOT:PSS) or graphene.

Moreover, not only the quality of the nanoparticles must be taken into account, but also the interface between the components of the device. It is therefore crucial to control the interface and develop efficient preparation methods without adding any additional costs. In this sense, the polymers can be deposited at room temperature without requiring special surface pre-treatments.

Thus, nanomaterial composites can be prepared with by alternative methods by using the soft chemical route (e.g., sol–gel methods, co-precipitation), which permits control of the dimensionality and particle size, exhaustive chemical composition, and microstructure, thus optimizing the final material properties.

Therefore, I invite all researchers in this field to contribute their latest results, as well as review the articles in the upcoming Special Issue, in order to aid the development of knowledge and application of inorganic nanoparticle–polymer composites in the future.

Prof. Dr. Julio Ramírez-Castellanos
Guest Editor

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Keywords

  • inorganic nanoparticles
  • composites
  • organic polymer
  • synthesis method
  • physical properties

Published Papers (1 paper)

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Research

12 pages, 3004 KiB  
Article
Covalently-Bonded Coating of L-Arginine Modified Magnetic Nanoparticles with Dextran Using Co-Precipitation Method
by Behnam Azadpour, Faezeh Kashanian, Mehran Habibi-Rezaei, Seyyed Ali Seyyed Ebrahimi, Roozbeh Yazdanpanah, Zahra Lalegani and Bejan Hamawandi
Materials 2022, 15(24), 8762; https://doi.org/10.3390/ma15248762 - 8 Dec 2022
Cited by 7 | Viewed by 1566
Abstract
In this study, L-arginine (Arg) modified magnetite (Fe3O4) nanoparticles (RMNPs) were firstly synthesized through a one-step co-precipitation method, and then these aminated nanoparticles (NPs) were, again, coated by pre-oxidized dextran (Dext), in which aldehyde groups (DextCHO) have been introduced [...] Read more.
In this study, L-arginine (Arg) modified magnetite (Fe3O4) nanoparticles (RMNPs) were firstly synthesized through a one-step co-precipitation method, and then these aminated nanoparticles (NPs) were, again, coated by pre-oxidized dextran (Dext), in which aldehyde groups (DextCHO) have been introduced on the polymer chain successfully via a strong chemical linkage. Arg, an amino acid, acts as a mediator to link the Dext to a magnetic core. The as-synthesized Arg-modified and Dext-coated arginine modified Fe3O4 NPs were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transformation infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). Both synthesized samples, XRD pattern and FT-IR spectra proved that the core is magnetite. FT-IR confirmed that the chemical bonds of Arg and Dext both exist in the samples. SEM images showed that the NPs are spherical and have an acceptable distribution size, and the VSM analysis indicated the superparamagnetic behavior of samples. The saturation magnetization was decreased after Dext coating, which confirms successive coating RMNPs with Text. In addition, the TGA analysis demonstrated that the prepared magnetic nanocomposites underwent various weight loss levels, which admitted the modification of magnetic cores with Arg and further coating with Dext. Full article
(This article belongs to the Special Issue Inorganic Nanoparticle-Polymer Composites)
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