Self-Healing Organic-Inorganic Coatings

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Corrosion, Wear and Erosion".

Deadline for manuscript submissions: closed (15 February 2024) | Viewed by 2669

Special Issue Editors


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Guest Editor
Department of Analytical, Physical and Inorganic Chemistry, Universidade Estadual Paulista "Júlio de Mesquita Filho", Sao Paulo, Brazil
Interests: organic–inorganic composites; protective coatings; structural analysis; surface analysis; carbon nanostructures

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Guest Editor
Centre for Functional and Surface Functionalized Glass, Alexander Dubček University of Trenčín, Trencin, Slovakia
Interests: anti-corrosion polymeric coatings; sol–gel; corrosion inhibition; self-healing coatings; bio-based coat-ings; electrochemical analysis

Special Issue Information

Dear Colleagues,

Hybrid coatings provide outstanding metallic protection in extreme environments for combining features of organic and inorganic materials that not only result in a remarkable barrier but also in improved mechanical, thermal, chemical and adhesion properties of coatings. In recent decades, the development of self-healing materials has added the possibility to regenerate hybrid coatings after failure, extending their service life. Self-healing coatings are able to repair or heal themselves by external intervention or autonomously, slowing or even stopping corrosion. When self-healing agents or systems such as corrosion inhibitors, chelation systems, microcapsules, interconnected vascular networks, shape-memory polymers, Diels–Alder or retro-Diels–Alder reactions (just to name a few) are properly integrated, a wide range of applications can be explored. Driven by the current demanding applications of smart materials, the design of self-healing organic–inorganic coatings must maintain the structural integrity of the hybrid matrix without compromising barrier and adhesion properties. In addition, to meet the requirements of a circular economy, eco-friendly materials are particularly sought out to replace the traditional ones. To this end, the unlimited possibilities for the design, synthesis, testing, and applications of high-performance anti-corrosion materials support this Special Issue to host papers in the following scope:

  • Efficient methods to synthesize self-healing coatings
  • Smart ecofriendly coatings for corrosion protection
  • Green materials for effective corrosion inhibition
  • New organic–inorganic hybrid systems for protection of metallic alloys
  • Nanotechnology applied to organic-inorganic coatings
  • Multifunctional polymer coatings
  • Fitting and modeling of electrochemical measurements of self-healing coatings
  • Water uptake calculations, prediction of performance and durability of hybrid coatings in extreme environments
  • Self-healing mechanisms

Prof. Dr. Peter Hammer
Dr. Andressa Trentin
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Coatings is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • anti-corrosion hybrid coatings
  • self-healing coatings
  • corrosion inhibition
  • organic–inorganic coatings
  • hybrid coatings for smart applications
  • design, synthesis, and analysis of hybrid coatings

Published Papers (2 papers)

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Editorial

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5 pages, 222 KiB  
Editorial
Self-Healing Organic-Inorganic Coatings
by Peter Hammer, Mayara Carla Uvida and Andressa Trentin
Coatings 2022, 12(11), 1668; https://doi.org/10.3390/coatings12111668 - 03 Nov 2022
Cited by 3 | Viewed by 1398
Abstract
Nowadays, steel and light alloys, such as aluminum, magnesium, and titanium, represent most of the primary components of metallic structures in many applications [...] Full article
(This article belongs to the Special Issue Self-Healing Organic-Inorganic Coatings)

Research

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22 pages, 6471 KiB  
Article
Improving the Protection Performance of Waterborne Coatings with a Corrosion Inhibitor Encapsulated in Polyaniline-Modified Halloysite Nanotubes
by Xin Liu, Zhiyue Gao, Die Wang, Fengjie Yu, Baoshuai Du and Ivan Gitsov
Coatings 2023, 13(10), 1677; https://doi.org/10.3390/coatings13101677 - 25 Sep 2023
Cited by 4 | Viewed by 850
Abstract
Organic coatings provide an effective way to improve the corrosion resistance of metals. Traditional organic varnishes, however, either contain highly polluting or toxic components or lack self-healing ability. In this article, we report a feasible method of preparing polyaniline-modified halloysite nanotubes (PANI@HNTs). They [...] Read more.
Organic coatings provide an effective way to improve the corrosion resistance of metals. Traditional organic varnishes, however, either contain highly polluting or toxic components or lack self-healing ability. In this article, we report a feasible method of preparing polyaniline-modified halloysite nanotubes (PANI@HNTs). They were loaded with a corrosion inhibitor, benzotriazole (BTA), and were tested as multifunctional anticorrosion additives for environmentally friendly epoxy waterborne coatings. The PANI@HNTs were formed via the in situ polymerization of aniline in the presence of halloysites. The BTA loading was then carried out and reached up to 14.5 wt.%. The BTA retention ability of the PANI@HNTs was significantly improved in comparison to that of pure HNT. Electrochemical impedance spectroscopy (EIS) tests of the coatings immersed in a 3.5 wt.% NaCl solution showed that the barrier and corrosion inhibition effects were enhanced by two to four orders of magnitude with the incorporation of BTA-loaded PANI@HNTs. The salt spray tests on artificially scratched coatings revealed that the surfaces protected by varnishes doped with the BTA-loaded PANI@HNTs exhibited the lowest degree of corrosion compared to the control samples, illustrating the self-healing potential of the modified coatings. Full article
(This article belongs to the Special Issue Self-Healing Organic-Inorganic Coatings)
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