Green Corrosion Inhibitors for Metallic Materials

The protection of ferrous metals in acidic environments is important in many industries. Extending the pH range of organic inhibitors to low pH has been achieved with the addition of iodide ions, which facilitate adsorption. It was of interest to see whether similar outcomes could be achieved with inorganic inhibitors. To this end, this paper examines the influence of potassium iodide addition on the level of corrosion protection provided by Ce(NO₃)₃ in 3.5% NaCl electrolytes over a pH range of 2.5 to 8. Potentiodynamic polarization was used to assess percentage inhibitor efficiency (IE%), and scanning electron microscopy, energy dispersive X-ray spectrometry, and X-ray photoelectron spectroscopy were used to characterize the corrosion product. It was found that KI alone provided only poor corrosion inhibition except at pH 2.5, where nearly 85IE% was achieved. Its addition to the cerium electrolytes was generally in excess of 90% and over 97% for the optimum concentration. The addition of KI seemed to change the mechanism of formation of corrosion products from predominantly Fe₂O₃ to a mixture of FeOOH, Fe₃O₄, and Fe₂O₃, which were more adherent. Corrosion protection was extended to pH 4, but under the conditions explored here, no additional protection was evident at pH 2.5. Full article

In this work, two compounds of isonicotinohydrazide organic class, namely (E)-N′-(1-(4-(dimethylamino)phenyl)ethylidene) isonicotinohydrazide (MAPEI) and (Z)-N′-(2-oxo-2, 3-dihydro-1H-inden-1-ylidene) isonicotinohydrazide (OHEI) were synthesized and evaluated for corrosion protection of N80 steel in a concentrated acidic medium (15 wt.% HCl) at a temperature of 303 K. The weight loss method (gravimetric method) and electrochemical techniques, i.e., electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves (PPC), were used to evaluate the inhibition and adsorption characteristics of tested compounds. Further, surface characterization using a scanning electron microscope (SEM) was used to assess the surface morphology of steel before and after inhibition. Weight loss experiments at 303 K and 363 K showed that tested compounds’ performance decreased with the increase in temperature, particularly at low concentrations of inhibitors whereas they exhibited good stability at higher concentrations. Electrochemical tests showed that MAPEI and OHEI inhibitors were effective at 5 × 10⁻³ mol/L, reaching an inhibition efficiency above 90%. It was also determined that the adsorption of both inhibitors followed the Langmuir adsorption isotherm model. Furthermore, SEM analysis showed that the investigated compounds can form a protective layer against steel corrosion in an acidic environment. On the other hand, the corrosion inhibition mechanism was established from density functional theory (DFT), and the self-consistent-charge density-functional tight-binding (SCC-DFTB) method which revealed that both inhibitors exerted physicochemical interactions by charge transfer between the s- and p-orbitals of tested molecules and the d-orbital of iron. The results of this work are intended to deepen the research on the products of this family to control the problem of corrosion. Full article

In this work some organic natural products were studied, namely tannic acid, gallic acid, mimosa tannin and chestnut tannin, as potential green corrosion inhibitors of the aluminium alloy AA2024-T3. The anodizing treatment was performed in a solution of the referred organic compounds in diluted sulfuric acid. The electrochemical impedance spectroscopy and the potentiodynamic polarization were performed to assess sealing quality and corrosion protection granted by the anodic films. To understand the green inhibitors; interaction with the metal surface, FTIR spectra of anodizing and anodizing and sealed samples of AA2023-T3 were recorded, and the shifts in the position of the major bands confirmed that the green inhibitor interacts with the metal surface. Images of the morphology of the coatings were provided by Scanning Electron Microscopy. From the results obtained through the various techniques that were used to carry out this study it is possible to conclude that the formed anodic films can be a good contribution for the prevention of corrosion in the aluminium alloy AA2024-T3. Full article