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Surface Science of Gas Sensing Materials

A special issue of Sensors (ISSN 1424-8220). This special issue belongs to the section "Sensor Materials".

Deadline for manuscript submissions: closed (31 May 2023) | Viewed by 2203

Special Issue Editor


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Guest Editor
Lomonosov Moscow State University, Moscow 119991, Russia
Interests: materials chemistry; inorganic chemistry; catalysis

Special Issue Information

The Special Issue "Surface Science of Gas Sensing Materials" is aimed at presenting state-of-the-art knowledge of surface phenomena in gas sensors. Gas sensors are attracting increasing interest from scientific and industrial communities. Extensive research has been carried out on the design, synthesis, and investigation of gas sensing materials with improved sensitivity, selectivity, operation temperature, stability, and dynamics. However, designing novel gas sensing materials with predetermined working characteristics is a challenging task, and a basic understanding of the physical and chemical processes at the surface of gas sensors is strongly required. Functioning of gas sensors relies on the gas–solid interactions at the materials surface. Therefore, in this Special Issue we would like to collect the articles reporting on the current understanding of surface chemistry of gas-sensing materials. All types of submissions are welcome, including research articles, reviews, and communications. Authors are encouraged to contribute to the Special Issue with the results of their experimental or theoretical research. The topics to be covered in the Special Issue include—but are not restricted to—the following:

  • First-principles modeling of sensing materials surfaces and gas–solid interactions (adsorption/desorption, redox reactions).
  • The design and synthesis of gas sensing materials with specific surface activity: metal oxides, composites, sulfides, graphene-based materials, etc; surface modification and functionalization.
  • Investigation of surface structure, composition, and defects of sensing materials with the atomic-resolution microscopy, diffraction, and spectroscopy techniques.
  • Evaluation of surface reactivity, active sites of gas sensing materials, adsorption of gases, and redox processes at the gas–solid interface.
  • Revelation of gas-sensing mechanisms by cutting-edge techniques (aside from the sensing tests): first-principles calculations, in situ or operando spectroscopy methods, catalytic measurements.

With respect to the scope of this issue, we discourage the submission of manuscripts in which the sensing mechanisms are proposed in a speculative manner and not confirmed by their own experimental evidences or first-principles studies.

Dr. Artem Marikutsa
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Sensors is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • gas sensor
  • metal oxide sensor
  • surface chemistry
  • sensing mechanism
  • active sites
  • surface science techniques

Published Papers (1 paper)

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Research

18 pages, 2815 KiB  
Article
Synergistic Effect of Surface Acidity and PtOx Catalyst on the Sensitivity of Nanosized Metal–Oxide Semiconductors to Benzene
by Artem Marikutsa, Nikolay Khmelevsky and Marina Rumyantseva
Sensors 2022, 22(17), 6520; https://doi.org/10.3390/s22176520 - 29 Aug 2022
Cited by 2 | Viewed by 1321
Abstract
Benzene is a potentially carcinogenic volatile organic compound (VOC) and its vapor must be strictly monitored in air. Metal–oxide semiconductors (MOS) functionalized by catalytic noble metals are promising materials for sensing VOC, but basic understanding of the relationships of materials composition and sensors [...] Read more.
Benzene is a potentially carcinogenic volatile organic compound (VOC) and its vapor must be strictly monitored in air. Metal–oxide semiconductors (MOS) functionalized by catalytic noble metals are promising materials for sensing VOC, but basic understanding of the relationships of materials composition and sensors behavior should be improved. In this work, the sensitivity to benzene was comparatively studied for nanocrystalline n-type MOS (ZnO, In2O3, SnO2, TiO2, and WO3) in pristine form and modified by catalytic PtOx nanoparticles. Active sites of materials were analyzed by X-ray photoelectron spectroscopy (XPS) and temperature-programmed techniques using probe molecules. The sensing mechanism was studied by in situ diffuse-reflectance infrared (DRIFT) spectroscopy. Distinct trends were observed in the sensitivity to benzene for pristine MOS and nanocomposites MOS/PtOx. The higher sensitivity of pristine SnO2, TiO2, and WO3 was observed. This was attributed to higher total concentrations of oxidation sites and acid sites favoring target molecules’ adsorption and redox conversion at the surface of MOS. The sensitivity of PtOx−modified sensors increased with the surface acidity of MOS and were superior for WO3/PtOx. It was deduced that this was due to stabilization of reduced Pt sites which catalyze deep oxidation of benzene molecules to carbonyl species. Full article
(This article belongs to the Special Issue Surface Science of Gas Sensing Materials)
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