Nanomaterials for Catalysis and Pollution Abatement

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: closed (29 February 2020) | Viewed by 11809

Special Issue Editor


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Guest Editor
Instituto de Tecnología Química, Universidad Politécnica de Valencia, Camino de Vera s.n., 46022 Valencia, Spain
Interests: hierarchical zeolites; nanosized materials; graphene; MOF; VOC; chlorinated VOC; catalytic abatement; catalytic oxidation; selective catalytic reduction; mixed oxide bronze

Special Issue Information

Dear colleagues,

The huge increase in the research on material science has allowed the development of more efficient catalysts for cleaner and more sustainable industrial processes and for the pollution abatement of mobile and fixed sources. Supports such as zeolites, graphene, MOFs, mesoporous materials, and mixed oxides derived from LDHs among others, can have active functions themselves or can be functionalized with noble or non-noble metals in the form of single atoms, clusters and nanoparticles with precise control of the aggregation during reaction and other deactivation processes.

This Special Issue is dedicated to showing the potential of nanomaterials in the field of catalysis and pollution abatement, providing affordable clean energy, clean water, recovering degraded and polluted environments, recycling wastes and caring for the atmosphere of urban areas, all in line with the Sustainable Development Agenda of the United Nations.

Dr. Joaquin Martinez Triguero
Guest Editor

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Keywords

  • Hierarchical zeolites
  • nanosized materials
  • graphene
  • MOF
  • VOC
  • Chlorinated VOC
  • Catalytic abatement
  • catalytic oxidation
  • selective catalytic reduction
  • mixed oxide bronze

Published Papers (4 papers)

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Research

14 pages, 4421 KiB  
Article
A Highly Sensitive SERS and RRS Coupled Di-Mode Method for CO Detection Using Nanogolds as Catalysts and Bifunctional Probes
by Dongmei Yao, Guiqing Wen, Lingbo Gong, Chongning Li, Aihui Liang and Zhiliang Jiang
Nanomaterials 2020, 10(3), 450; https://doi.org/10.3390/nano10030450 - 2 Mar 2020
Cited by 9 | Viewed by 2853
Abstract
Carbon monoxide (CO) is a commonly poisonous gas. It is important to detect CO in daily life. Herein, a new and sensitive surface enhanced Raman scattering (SERS) and resonance Rayleigh scattering (RRS) coupled di-mode method was developed for CO, based on gold nano-enzyme [...] Read more.
Carbon monoxide (CO) is a commonly poisonous gas. It is important to detect CO in daily life. Herein, a new and sensitive surface enhanced Raman scattering (SERS) and resonance Rayleigh scattering (RRS) coupled di-mode method was developed for CO, based on gold nano-enzyme catalysis and gold nanoprobes. CO can react with HAuCl4 to generate gold nanoparticles (AuNPs) in pH 5.2 HAc-NaAc buffer. The generated AuNPs exhibited SERS activity at 1620 cm−1 in the presence of Vitoria blue B (VBB) molecular probes, and an RRS peak at 290 nm. Based on the AuNP bifunctional probes, the increased SERS and RRS intensities respond linearly with the concentration of CO in the range of 100–1500 ng/mL and 30–5230 ng/mL, respectively. To improve the sensitivity, the produced AuNPs were used as nano-enzyme catalysts for the new indicator reaction of HAuCl4-ethanol (En) to amplify the signal. The sensitive SERS method was coupled with the accurate RRS method to develop a sensitive and accurate SERS/RRS di-mode method for determination of 3.0–413 ng/mL CO, based on the AuNP-HAuCl4-En nanocatalytic reaction and its product of AuNPs as SERS and RRS bifunctional probes. Full article
(This article belongs to the Special Issue Nanomaterials for Catalysis and Pollution Abatement)
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18 pages, 8190 KiB  
Article
Synthesis of Diatomite-Based Mesoporous Wool-Ball-Like Microspheres and Their Application for Toluene Total Oxidation Reaction
by Quoc-Chon Le, Chinh Chien Nguyen, Thi Thanh Nhi Le, Thierry Lefèvre, Minh Tuan Nguyen Dinh, Sung Hyun Hong, Soo Young Kim and Quyet Van Le
Nanomaterials 2020, 10(2), 339; https://doi.org/10.3390/nano10020339 - 17 Feb 2020
Cited by 2 | Viewed by 2260
Abstract
Diatomite (DE) has attracted considerable attention owing to its abundance, low cost, and potential for a wide variety of applications. This work reports the development of mesoporous wool-ball-like (WBL) microspheres from natural DE through a simple hydrothermal treatment. We discovered that the presence [...] Read more.
Diatomite (DE) has attracted considerable attention owing to its abundance, low cost, and potential for a wide variety of applications. This work reports the development of mesoporous wool-ball-like (WBL) microspheres from natural DE through a simple hydrothermal treatment. We discovered that the presence of cetyltrimethylammonium bromide is a prerequisite for generating monodispersed WBL microspheres. The mechanism for the transformation of pristine DE into mesoporous microspheres through dissolution–recrystallization was clearly investigated. Interestingly, the microspheres exhibited a specific surface area 25–60 times larger than that of the pristine DE. The application of WBL microsphere DE as an effective support for metallic catalysts in the toluene total oxidation reaction was demonstrated. Full article
(This article belongs to the Special Issue Nanomaterials for Catalysis and Pollution Abatement)
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14 pages, 3337 KiB  
Article
Catalytic Performance of Palladium Supported on Sheaf-Like Ceria in the Lean Methane Combustion
by Shuna Li, Yagang Zhang, Jing Shi, Gang Zhu, Yanxiang Xie, Zhikai Li, Ruiyi Wang and Huaqing Zhu
Nanomaterials 2020, 10(1), 31; https://doi.org/10.3390/nano10010031 - 21 Dec 2019
Cited by 11 | Viewed by 2519
Abstract
Sheaf-like CeO2 (CeO2-S) in microscale was prepared by the hydrothermal method, and then etched with KOH aiming to obtain an imperfect fluorite structure (CeO2-SK) with high content of oxygen vacancies and oxygen mobility. With CeO2-S and [...] Read more.
Sheaf-like CeO2 (CeO2-S) in microscale was prepared by the hydrothermal method, and then etched with KOH aiming to obtain an imperfect fluorite structure (CeO2-SK) with high content of oxygen vacancies and oxygen mobility. With CeO2-S and CeO2-SK as supports respectively, a modified colloidal deposition method was employed to obtain Pd/CeO2 catalysts for being used in lean methane combustion. According to the inductively coupled plasma (ICP), N2 physisorption and scanning electron microscopy (SEM) results, the Pd supported catalysts are very similar in their Pd loading, surface area and morphologies. SEM and transmission electron microscopy (TEM) results revealed various nanorods exposed CeO2 (110) and (100) facets on Pd/CeO2-SK surface after KOH etching. Raman spectra and H2-temperature programmed reduction (H2-TPR) results indicated that Pd/CeO2-SK catalyst has a much higher content of catalytic active PdO species than Pd/CeO2-S catalyst. It was also found that the catalytic performance of Pd/CeO2 in lean methane combustion depends greatly upon the exposing crystal planes and oxygen vacancies content of sheaf-like CeO2, and Pd/CeO2-SK exhibits higher activity than Pd/CeO2-S. The larger amount of CeO2 (110) and (100) planes on Pd/CeO2-SK surface can enhance the formation of oxygen vacancies, active Pd species and migration of lattice oxygen, which all evidently improve the redox ability and catalytic activity of the Pd/CeO2-SK catalysts in lean methane combustion. Full article
(This article belongs to the Special Issue Nanomaterials for Catalysis and Pollution Abatement)
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19 pages, 5507 KiB  
Article
High Catalytic Performance of Mn-Doped Ce-Zr Catalysts for Chlorobenzene Elimination
by Lei Zhu, Xi Li, Zhiying Liu, Lin Yao, Peng Yu, Ping Wei, Yanhua Xu and Xingmao Jiang
Nanomaterials 2019, 9(5), 675; https://doi.org/10.3390/nano9050675 - 1 May 2019
Cited by 16 | Viewed by 3711
Abstract
Mn-Ce-Zr-O catalysts doped with varying Mn content were prepared and assessed for the catalytic combustion of chlorobenzene (CB). Nanosized MCZ-0.67 catalyst with amorphous phase exhibited a high and stable catalytic activity among the studied catalysts, achieving 90% CB conversion at 226 °C and [...] Read more.
Mn-Ce-Zr-O catalysts doped with varying Mn content were prepared and assessed for the catalytic combustion of chlorobenzene (CB). Nanosized MCZ-0.67 catalyst with amorphous phase exhibited a high and stable catalytic activity among the studied catalysts, achieving 90% CB conversion at 226 °C and withstanding stability tests, including time-based stability and the successive influence of various operating conditions. Meanwhile, the MCZ-0.67 catalyst used showed good recyclability by calcination in air. Characterization results suggested that Mn doping played a dominant role in improving the catalytic performance, resulting in larger surface area, better redox properties and greater amounts of surface active oxygen. In addition, the introduction of Zr was also indispensable for maintaining the good catalytic performance of catalysts. Finally, trace amounts of polychlorinated by-products during CB oxidation were monitored and the oxidation process was discussed. Full article
(This article belongs to the Special Issue Nanomaterials for Catalysis and Pollution Abatement)
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