Nanomaterials with High Electrocatalytic Performance

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "2D and Carbon Nanomaterials".

Deadline for manuscript submissions: closed (30 October 2022) | Viewed by 5348

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Guest Editor
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China
Interests: nanomaterials; materials genome; electrocatalysis; hetrogeneous catalysis; energy storage
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Special Issue Information

Dear Colleagues,

The urgent need for sustainable clean energy technology calls for high-performance electrocatalytic materials for key processes such as hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, electrocatalytic reduction of CO2, etc. Nanomaterials demonstrate nanoscale effects such as surface and interface effect, quantum size effect, small size effect, and macroscopic quantum tunneling effect. These special properties endow nanomaterials with broad prospects in the application of electrochemical catalysis. The effective design and accurate construction of nanomaterials with high electrocatalytic performance, and the relevant mechanism are fascinating yet challenging.

This Special Issue welcomes contributions focusing on nanomaterials with high electrocatalytic performance, especially those concerning experimental and computational designs, precise construction and characterization, and mechanism understanding.

Dr. Yutong Gong
Guest Editor

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Keywords

  • nanomaterials
  • energy conversion
  • electrocatalysis
  • mechanism
  • hydrogen evolution reaction
  • CO2 reduction
  • N2 reduction
  • oxygen reduction reaction
  • size effect
  • composites

Published Papers (3 papers)

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Research

13 pages, 3688 KiB  
Article
Molybdenum Diselenide and Tungsten Diselenide Interfacing Cobalt-Porphyrin for Electrocatalytic Hydrogen Evolution in Alkaline and Acidic Media
by Antonia Kagkoura, Christina Stangel, Raul Arenal and Nikos Tagmatarchis
Nanomaterials 2023, 13(1), 35; https://doi.org/10.3390/nano13010035 - 22 Dec 2022
Cited by 1 | Viewed by 1542
Abstract
Easy and effective modification approaches for transition metal dichalcogenides are highly desired in order to make them active toward electrocatalysis. In this manner, we report functionalized molybdenum diselenide (MoSe2) and tungsten diselenide (WSe2) via metal-ligand coordination with pyridine rings [...] Read more.
Easy and effective modification approaches for transition metal dichalcogenides are highly desired in order to make them active toward electrocatalysis. In this manner, we report functionalized molybdenum diselenide (MoSe2) and tungsten diselenide (WSe2) via metal-ligand coordination with pyridine rings for the subsequent covalent grafting of a cobalt-porphyrin. The new hybrid materials were tested towards an electrocatalytic hydrogen evolution reaction in both acidic and alkaline media and showed enhanced activity compared to intact MoSe2 and WSe2. Hybrids exhibited lower overpotential, easier reaction kinetics, higher conductivity, and excellent stability after 10,000 ongoing cycles in acidic and alkaline electrolytes compared to MoSe2 and WSe2. Markedly, MoSe2-based hybrid material showed the best performance and marked a significantly low onset potential of −0.17 V vs RHE for acidic hydrogen evolution reaction. All in all, the ease and fast modification route provides a versatile functionalization procedure, extendable to other transition metal dichalcogenides, and can open new pathways for the realization of functional nanomaterials suitable in electrocatalysis. Full article
(This article belongs to the Special Issue Nanomaterials with High Electrocatalytic Performance)
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12 pages, 3049 KiB  
Article
Corrosion-Engineered Morphology and Crystal Structure Regulation toward Fe-Based Efficient Oxygen Evolution Electrodes
by Ying Wang, Zhengbang Yang, Zhonghua Zhang and Ming He
Nanomaterials 2022, 12(12), 1975; https://doi.org/10.3390/nano12121975 - 08 Jun 2022
Cited by 2 | Viewed by 1621
Abstract
The rational regulation of catalysts with a well-controlled morphology and crystal structure has been demonstrated effective for optimizing the electrochemical performance. Herein, corrosion engineering was employed for the straightforward preparation of FeAl layered double hydroxide (LDH) nanosheets and Fe3O4 nanooctahedrons [...] Read more.
The rational regulation of catalysts with a well-controlled morphology and crystal structure has been demonstrated effective for optimizing the electrochemical performance. Herein, corrosion engineering was employed for the straightforward preparation of FeAl layered double hydroxide (LDH) nanosheets and Fe3O4 nanooctahedrons via the feasible modification of dealloying conditions. The FeAl-LDH nanosheets display an excellent catalytic performance for oxygen evolution reactions in 1 M KOH solution, such as low overpotentials (333 mV on glass carbon electrode and 284 mV on Ni foam at 10 mA cm−2), a small Tafel slope (36 mV dec−1), and excellent durability (24 h endurance without deactivation). The distinguished catalytic features of the FeAl-LDH nanosheets comes from the Al and Fe synergies, oxygen vacancies, and well-defined two-dimensional (2D) layered LDH structure. Full article
(This article belongs to the Special Issue Nanomaterials with High Electrocatalytic Performance)
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12 pages, 4096 KiB  
Article
Chromium-Modified Ultrathin CoFe LDH as High-Efficiency Electrode for Hydrogen Evolution Reaction
by Jun-Jun Zhang, Meng-Yang Li, Xiang Li, Wei-Wei Bao, Chang-Qing Jin, Xiao-Hua Feng, Ge Liu, Chun-Ming Yang and Nan-Nan Zhang
Nanomaterials 2022, 12(7), 1227; https://doi.org/10.3390/nano12071227 - 06 Apr 2022
Cited by 31 | Viewed by 2947
Abstract
Hydrogen evolution reaction (HER) has a dominant function in energy conversion and storage because it supplies a most effective way for converting electricity into sustainable high-purity hydrogen. Layered double hydroxides (LDHs) have shown promising performance in the process of electrochemical water oxidation (a [...] Read more.
Hydrogen evolution reaction (HER) has a dominant function in energy conversion and storage because it supplies a most effective way for converting electricity into sustainable high-purity hydrogen. Layered double hydroxides (LDHs) have shown promising performance in the process of electrochemical water oxidation (a half-reaction for water splitting). Nevertheless, HER properties have not been well released due to the structural characteristics of related materials. Herein, a simple and scalable tactics is developed to synthesize chromium-doped CoFe LDH (CoFeCr LDH). Thanks to oxygen vacancy, optimized electronic structure and interconnected array hierarchical structure, our developed ternary CoFeCr-based layered double hydroxide catalysts can provide 10 mA cm−2 current density at −0.201 V vs. RHE with superior long-term stability in alkaline electrolyte. We anticipate that the simple but feasible polymetallic electronic modulation strategy can strengthen the electrocatalytic property of the layered double hydroxides established in the present study, based on a carbon neutral and hydrogen economy. Full article
(This article belongs to the Special Issue Nanomaterials with High Electrocatalytic Performance)
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