Nanomaterials for Chemical Engineering (Volume III)

A special issue of Nanomaterials (ISSN 2079-4991).

Deadline for manuscript submissions: 31 August 2024 | Viewed by 1814

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Guest Editor
State Key Laboratory of Heavy Oil Processing and Centre for Bioengineering and Biotechnology, College of Chemical Engineering, China University of Petroleum (East China), 66 Changjiang West Road, Qingdao 266580, China
Interests: peptide molecular design; self-assembly of biofunctional materials; pollutant water treatment; solution and interface aggregation behaviors of surfactant molecules; metal corrosion prevention
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Special Issue Information

Dear Colleagues,

The present Special Issue is the third edition of the previous successful Special Issue, titled “Nanomaterials for Chemical Engineering” (https://www.mdpi.com/journal/nanomaterials/special_issues/nano_chemical_engineering), hosted by this editor.

Scientists and engineers have emphasized the study of nanomaterials in recent decades. The superior properties of nanomaterials are helping to greatly improve and even revolutionize the development of various technology- and industry-based sectors. Despite their many advantages, there are various challenges present in the control and design of nanomaterials with specific properties (morphology, size, porosity, conductivity, optical properties, photoelectric properties, chemical activity, etc.) to meet their functional aims. The main applications of nanomaterials in chemical engineering are based on catalysts, coatings, adsorption, sensors, drug delivery, etc., which all represent fascinating yet challenging research topics.

This Special Issue welcomes contributions devoted to the synthesis and application of functional nanomaterials in chemical engineering, which includes the development of novel nanomaterials and synthesis methods, experimental characterization, and computational modeling studies, as well as their exploitation in devices and practical applications.

Prof. Dr. Meiwen Cao
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Nanomaterials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2900 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • chemical engineering
  • nanomaterials
  • function
  • application
  • adsorption
  • catalyst
  • coating
  • pollutant treatment

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Published Papers (3 papers)

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Research

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15 pages, 3372 KiB  
Article
Magnetic Nanoparticle Support with an Ultra-Thin Chitosan Layer Preserves the Catalytic Activity of the Immobilized Glucose Oxidase
by Boris B. Tikhonov, Daniil R. Lisichkin, Alexandrina M. Sulman, Alexander I. Sidorov, Alexey V. Bykov, Yury V. Lugovoy, Alexey Y. Karpenkov, Lyudmila M. Bronstein and Valentina G. Matveeva
Nanomaterials 2024, 14(8), 700; https://doi.org/10.3390/nano14080700 - 17 Apr 2024
Viewed by 348
Abstract
Here, we developed magnetically recoverable biocatalysts based on magnetite nanoparticles coated with an ultra-thin layer (about 0.9 nm) of chitosan (CS) ionically cross-linked by sodium tripolyphosphate (TPP). Excessive CS amounts were removed by multiple washings combined with magnetic separation. Glucose oxidase (GOx) was [...] Read more.
Here, we developed magnetically recoverable biocatalysts based on magnetite nanoparticles coated with an ultra-thin layer (about 0.9 nm) of chitosan (CS) ionically cross-linked by sodium tripolyphosphate (TPP). Excessive CS amounts were removed by multiple washings combined with magnetic separation. Glucose oxidase (GOx) was attached to the magnetic support via the interaction with N-hydroxysuccinimide (NHS) in the presence of carbodiimide (EDC) leading to a covalent amide bond. These steps result in the formation of the biocatalyst for D-glucose oxidation to D-gluconic acid to be used in the preparation of pharmaceuticals due to the benign character of the biocatalyst components. To choose the catalyst with the best catalytic performance, the amounts of CS, TPP, NHS, EDC, and GOx were varied. The optimal biocatalyst allowed for 100% relative catalytic activity. The immobilization of GOx and the magnetic character of the support prevents GOx and biocatalyst loss and allows for repeated use. Full article
(This article belongs to the Special Issue Nanomaterials for Chemical Engineering (Volume III))
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17 pages, 7317 KiB  
Article
Efficient and Selective Removal of Palladium from Simulated High-Level Liquid Waste Using a Silica-Based Adsorbent NTAamide(C8)/SiO2-P
by Jiaxuan Shi, Junli Wang, Wentao Wang, Xuan Wu, Hui Wang and Jianwei Li
Nanomaterials 2024, 14(6), 544; https://doi.org/10.3390/nano14060544 - 20 Mar 2024
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Abstract
In order to realize the effective separation of palladium from high-level liquid waste (HLLW), a ligand-supported adsorbent (NTAamide(C8)/SiO2-P) was prepared by the impregnation method in a vacuum. The SiO2-P carrier was synthesized by in situ polymerization of divinylbenzene and [...] Read more.
In order to realize the effective separation of palladium from high-level liquid waste (HLLW), a ligand-supported adsorbent (NTAamide(C8)/SiO2-P) was prepared by the impregnation method in a vacuum. The SiO2-P carrier was synthesized by in situ polymerization of divinylbenzene and styrene monomers on a macroporous silica skeleton. The NTAamide(C8)/SiO2-P adsorbent was fabricated by impregnating an NTAamide(C8) ligand into the pore of a SiO2-P carrier under a vacuum condition. The adsorption performance of NTAamide(C8)/SiO2-P in nitric acid medium has been systematically studied. In a solution of 0.2 M HNO3, the distribution coefficient of Pd on NTAamide(C8)/SiO2-P was 1848 mL/g with an adsorption percentage of 90.24%. With the concentration of nitric acid increasing, the adsorption capacity of NTAamide(C8)/SiO2-P decreases. Compared to the other 10 potential interfering ions in fission products, NTAamide(C8)/SiO2-P exhibited excellent adsorption selectivity for Pd(II). The separation factor (SFPd/other metals > 77.8) is significantly higher than that of similar materials. The interference of NaNO3 had a negligible effect on the adsorption performance of NTAamide(C8)/SiO2-P, which maintained above 90%. The adsorption kinetics of Pd(II) adsorption on NTAamide(C8)/SiO2-P fits well with the pseudo-second order model. The Sips model is more suitable than the Langmuir and Freundlich model for describing the adsorption behavior. Thermodynamic analysis showed that the adsorption of Pd(II) on NTAamide(C8)/SiO2-P was a spontaneous, endothermic, and rapid process. NTAamide(C8)/SiO2-P also demonstrated good reusability and economic feasibility. Full article
(This article belongs to the Special Issue Nanomaterials for Chemical Engineering (Volume III))
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Review

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16 pages, 2372 KiB  
Review
Bicontinuous Interfacially Jammed Emulsion Gels (Bijels): Preparation, Control Strategies, and Derived Porous Materials
by Xingliang Shen and Meiwen Cao
Nanomaterials 2024, 14(7), 574; https://doi.org/10.3390/nano14070574 - 26 Mar 2024
Viewed by 636
Abstract
Bicontinuous interfacially jammed emulsion gels, also known as Bijels, are a new type of soft condensed matter. Over the last decade, Bijels have attracted considerable attention because of their unique morphology, property, and broad application prospects. In the present review, we summarize the [...] Read more.
Bicontinuous interfacially jammed emulsion gels, also known as Bijels, are a new type of soft condensed matter. Over the last decade, Bijels have attracted considerable attention because of their unique morphology, property, and broad application prospects. In the present review, we summarize the preparation methods and main control strategies of Bijels, focusing on the research progress and application of Bijels as templates for porous materials preparation in recent years. The potential future directions and applications of Bijels are also envisaged. Full article
(This article belongs to the Special Issue Nanomaterials for Chemical Engineering (Volume III))
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