Photoelectrochemical Applications of Quantum Dots and Photofunctional Nanomaterials

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: 25 September 2024 | Viewed by 3530

Special Issue Editors


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Guest Editor
Institute of Functional Nano & Soft Materials, Soochow University, Suzhou 215123, China
Interests: carbon dots; photocatalysis; electrocatalysis; photo-electrocatalysis; heterogeneous catalysis; nanocatalysis

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Guest Editor
Institute of Functional Nano and Soft Materials Laboratory (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China
Interests: nanomaterials; nanocatalysis; enzymatic catalysis; chiral catalysis; carbon dots; carbon-based nanomaterials; carbon-based nanocomposites; photocatalysis; electrocatalysis; photo-electrocatalysis; heterogeneous catalysis; catalysis for energy; CO2 transformation

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Guest Editor
Institute for Energy Research, Jiangsu University, Zhenjiang, China
Interests: carbon-based functional nano materials; nano sensing and catalysis; clean energy and environmental governance

Special Issue Information

Dear Colleagues,

Quantum dots, a nanometer-level material, not only include semiconductors but also carbon materials, silicon materials, or other non-metallic materials. The quantum confinement effect has driven the development and exploration of quantum dots over the past several decades. The excellent photoelectrochemical properties of quantum dots and photofunctional nanomaterials have attracted widespread attention in the fields of optics, photoelectrochemistry, electronics, catalysis, and biology, which stimulate the related research development and promote many novel directions.

With the perspective of quantum dots for our global energy and sustainability challenges in mind, this Special Issue focuses on quantum dots and photofunctional nanomaterials for photoelectrochemical applications, including:

  1. synthesis and photoelectrochemical properties of functional materials;
  2. photoelectrochemical catalysis;
  3. photoelectrochemical energy conversion;
  4. photofunctional nanomaterials for bioapplications;
  5. photoelectrochemical devices;
  6. in situ investigation and analysis of the photoelectrochemical process.

Prof. Dr. Yang Liu
Prof. Dr. Hui Huang
Prof. Dr. Haitao Li
Guest Editors

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Keywords

  • quantum dots
  • photofunctional nanomaterials
  • photoelectrochemical properties
  • photocatalysis
  • electrocatalysis
  • biocatalysis

Published Papers (3 papers)

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Research

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12 pages, 2983 KiB  
Article
A Light-Powered Micropump with Dynamic Collective Behavior for Reparation
by Yunyu Sun, Hao Wang, Jiwei Jiang, Hui Zhang, Limei Liu, Keying Zhang, Bo Song and Bin Dong
Nanomaterials 2024, 14(6), 517; https://doi.org/10.3390/nano14060517 - 14 Mar 2024
Viewed by 686
Abstract
Inspired by the collective behaviors of active systems in nature, the collective behavior of micromotors has attracted more and more attention in recent years. However, little attention has been paid to the collective behavior of the immobilized micromotor, i.e., the micropump. In this [...] Read more.
Inspired by the collective behaviors of active systems in nature, the collective behavior of micromotors has attracted more and more attention in recent years. However, little attention has been paid to the collective behavior of the immobilized micromotor, i.e., the micropump. In this paper, a unique pentacene-based micropump is reported, which demonstrates dynamic collective behavior activated by white light irradiation. The light irradiation may generate the photochemical reactions between pentacene and water, leading to the electroosmotic flow. As a result, this micropump is capable of pumping the surrounding solution inward along the substrate surface based on the electroosmosis mechanism. Intriguingly, the inward pumping causes the agglomeration of the tracer particles on the surface of the micropump. In addition, the aggregation can migrate following the change in the light irradiation position between two adjacent micropumps. Based on the aggregating and migrating behaviors of this pentacene-based micropump, we have achieved the conductivity restoration of the cracked circuit. Full article
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12 pages, 5672 KiB  
Article
Carbon Quantum Dots/Cu2O Photocatalyst for Room Temperature Selective Oxidation of Benzyl Alcohol
by Zhuang Tong, Yunliang Liu, Xin Wu, Yuanyuan Cheng, Jingwen Yu, Xinyue Zhang, Naiyun Liu, Xiang Liu and Haitao Li
Nanomaterials 2024, 14(2), 212; https://doi.org/10.3390/nano14020212 - 18 Jan 2024
Viewed by 900
Abstract
The luminescence properties and excellent carrier transfer ability of carbon quantum dots (CQDs) have attracted much attention in the field of photocatalysis. In this work, we loaded the CQDs on the surface of Cu2O to enhance the visible-light property of Cu [...] Read more.
The luminescence properties and excellent carrier transfer ability of carbon quantum dots (CQDs) have attracted much attention in the field of photocatalysis. In this work, we loaded the CQDs on the surface of Cu2O to enhance the visible-light property of Cu2O. Furthermore, the composite was used for selective oxidation of benzyl alcohol to benzaldehyde. The composite catalyst achieved high selectivity (90%) for benzaldehyde at room temperature, leveraging its visible-light-induced electron transfer properties and its photocatalytic activity for hydrogen peroxide decomposition. ·OH was shown to be the main reactive oxygen species in the selective oxidation reaction of benzyl alcohol. The formation of heterostructures of CQDs/Cu2O promoted charge carrier separation and provided a fast channel for photoinduced electron transfer. This novel material exhibited enhanced levels of activity and stability for selective oxidation of benzyl alcohol. Potential applications of carbon quantum dot composites in conventional alcohol oxidation reactions are shown. Full article
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Review

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26 pages, 8240 KiB  
Review
The Recent Progresses of Electrodes and Electrolysers for Seawater Electrolysis
by Fan Zhang, Junjie Zhou, Xiaofeng Chen, Shengxiao Zhao, Yayun Zhao, Yulong Tang, Ziqi Tian, Qihao Yang, Evelina Slavcheva, Yichao Lin and Qiuju Zhang
Nanomaterials 2024, 14(3), 239; https://doi.org/10.3390/nano14030239 - 23 Jan 2024
Viewed by 1571
Abstract
The utilization of renewable energy for hydrogen production presents a promising pathway towards achieving carbon neutrality in energy consumption. Water electrolysis, utilizing pure water, has proven to be a robust technology for clean hydrogen production. Recently, seawater electrolysis has emerged as an attractive [...] Read more.
The utilization of renewable energy for hydrogen production presents a promising pathway towards achieving carbon neutrality in energy consumption. Water electrolysis, utilizing pure water, has proven to be a robust technology for clean hydrogen production. Recently, seawater electrolysis has emerged as an attractive alternative due to the limitations of deep-sea regions imposed by the transmission capacity of long-distance undersea cables. However, seawater electrolysis faces several challenges, including the slow kinetics of the oxygen evolution reaction (OER), the competing chlorine evolution reaction (CER) processes, electrode degradation caused by chloride ions, and the formation of precipitates on the cathode. The electrode and catalyst materials are corroded by the Cl under long-term operations. Numerous efforts have been made to address these issues arising from impurities in the seawater. This review focuses on recent progress in developing high-performance electrodes and electrolyser designs for efficient seawater electrolysis. Its aim is to provide a systematic and insightful introduction and discussion on seawater electrolysers and electrodes with the hope of promoting the utilization of offshore renewable energy sources through seawater electrolysis. Full article
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